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991.
It is not clear whether the mechanism of the SH2′ reaction of allyl chloride is concerted or stepwise. The relative rates of the competitive free radical addition to two different double bonds in (2-chloroallyl)-(2-choromethylallyl) ether have been determined. There are two competitive free radical addition reactions, one is free radical SH2′ reaction and the other is free radical addition reaction. The mechanism of the SH2′ reaction is discussed by comparing free radical SH2′ reaction with free radical addition reaction. 相似文献
992.
993.
The applications of a series piezoelectric sensor for end-point determination in frequencimetric titrations, including neutralization, precipitation, complexation and redox titrations, are reported. The method is based on the fact that a series piezoelectric sensor shows a sensitive and selective frequency response to changes in conductivity of solution and can be applied to sample solutions containing large amounts of unreacted foreign electrolytes. 相似文献
994.
Duan‐Jun Xu Bing‐Yu Zhang Jian‐Rong Su Jing‐Jing Nie 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(12):m622-m624
In the title compound, [Sr(C7H5O3)2(C12H8N2)2(H2O)2], the SrII ion is located on a twofold rotation axis and assumes a distorted square‐antiprism SrN4O4 coordination geometry, formed by two phenanthroline (phen) ligands, two 2‐hydroxybenzoate anions and two water molecules. Within the mononuclear complex molecule, intramolecular π–π stacking is observed between nearly parallel coordinated phen ligands, while normal intermolecular π–π stacking occurs between parallel phen ligands of adjacent complex molecules. Classic O—H...O and weak C—H...O hydrogen bonding helps to stabilize the crystal structure. 相似文献
995.
996.
A new piezoelectric crystal impedance sensor for the determination of sulphur dioxide in aqueous solution is presented. It is realized using a series piezoelectric crystal device which is constructed by connecting an AT-cut piezoelectric crystal to a probe in series. The probe is filled with an internal electrolyte solution that is separated from sample solutions by a gas-permeable membrane. The present sensor exhibits a favourable frequency response to 1 x 10(-7)-1 x 10(-3) M sulphur dioxide. The detection limit is 1 x 10(-8) M. The effects of the sensor preparation are considered. Dynamic range, reproducibility, response time and selectivity of the sensor are also discussed. The proposed sensor has been used successfully for lamp sulphur determinations in petroleum samples. 相似文献
997.
998.
Polymer particles with various shapes and morphologies produced in continuous microfluidic reactors 总被引:8,自引:0,他引:8
Nie Z Xu S Seo M Lewis PC Kumacheva E 《Journal of the American Chemical Society》2005,127(22):8058-8063
We report a novel approach to continuous and scalable production of core-shell droplets and polymer capsules in microfluidic devices. The described method is also useful in the synthesis of polymer particles with nonspherical shapes. We used capillary instability-driven break-up of a liquid jet formed by two immiscible fluids. Precise control of emulsification of each liquid allowed for the production of highly monodisperse core-shell droplets with a predetermined diameter of cores and thickness of shells. We also achieved control over the number of cores per droplet and the location of cores in the droplet. We carried out fast throughput photopolymerization of the monomeric shells and obtained polymer particles with various shapes and morphologies, including spheres, truncated spheres and, hemispheres, and single and multicore capsules. 相似文献
999.
Continuous microfluidic reactors for polymer particles 总被引:4,自引:0,他引:4
Seo M Nie Z Xu S Mok M Lewis PC Graham R Kumacheva E 《Langmuir : the ACS journal of surfaces and colloids》2005,21(25):11614-11622
This article provides an overview of our work in the area of the synthesis of polymer particles in continuous microfluidic reactors. The method includes (a) the generation of highly monodisperse monomer droplets in a microfluidic flow-focusing device and (b) in-situ solidification of these droplets by means of photopolymerization. We discuss the effect of monomer properties on the emulsification process, the effect of the polymerization rate on the production of high-quality particles, the role of the material of the microfluidic device in droplet formation, and the synthesis of particles with different shapes and compositions. We also demonstrate the production of highly ordered arrays of polymer particles achieved by photopolymerization of the dynamic lattices of monomer droplets in microfluidic channels. The article is concluded with a summary of future research directions in the production of polymer colloids in microfluidic reactors. 相似文献
1000.
A new bulk acoustic wave (BAW) sensor modified with a molecularly imprinted polymer (MIP) was fabricated and applied for the determination of pyrimethamine. This sensor exhibited high selectivity and sensitive response to pyrimethamine. Factors such as pH and the amount of coating influencing sensor properties, were investigated in detail and optimized. The calibration curve was linear in the range 6.0x10(-7)-1.0x10(-4) M. The determination limit was 2.0x10(-7) M. In harsh chemical environments such as high temperature, organic solvents, bases, acids, etc., the sensor still exhibited long-term stability. The proposed method has been satisfactorily applied for the determination of pyrimethamine in serum and urine media. 相似文献