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51.
Precisely Controlled Multidimensional Covalent Frameworks: Polymerization of Supramolecular Colloids
Dr. Yongguang Li Shanshan Wu Lingling Zhang Xin Xu Yajun Fang Juzhen Yi Dr. Jehan Kim Dr. Bowen Shen Prof. Myongsoo Lee Dr. Liping Huang Liwei Zhang Junhui Bao Prof. Hongbing Ji Prof. Zhegang Huang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(48):21709-21713
Rapid and selective removal of micropollutants from water is important for the reuse of water resources. Despite hollow frameworks with specific functionalized porous walls for the selective adsorption based on a series of interactions, tailoring a stable shape of nanometer- and micrometer-sized architectures for the removal of specific pollutants remains a challenge. Here, exactly controlled sheets, tubes, and spherical frameworks were presented from the crosslinking of supramolecular colloids in polar solvents. The frameworks strongly depended on the architecture of original supramolecular colloids. As the entropy of colloids increased, the initial laminar framework rolled up into hollow tubules, and then further curled into hollow spheres. These shape-persistent frameworks showed unprecedented selectivity as well as specific recognition for the shape of pollutants, thus contributing to efficient pollutant separation. 相似文献
52.
Yongxing Tang Yajun Yu Xinyu Wei Jin Yang Yeting Zhu Yun-Hui Zhao Zilong Tang Zhihua Zhou Xiaofang Li Xianyong Yu 《Tetrahedron letters》2019,60(43):151187
A novel 6-endo-dig cyclization followed by oxidation/elimination of o-alkynylarylaldimines with 4-hydroxybenzylamine was developed for preparation of isoquinolines. The intermediates of this tandem reaction were monitored by mass spectroscopy (MS) to confirm the reaction pathway. This methodology was further applied to the design and synthesis of a novel ratiometric chemosensor for determination of fluoride. 相似文献
53.
A One‐Step Route to CO2‐Based Block Copolymers by Simultaneous ROCOP of CO2/Epoxides and RAFT Polymerization of Vinyl Monomers 下载免费PDF全文
Dr. Yong Wang Yajun Zhao Prof. Dr. Yunsheng Ye Prof. Dr. Haiyan Peng Prof. Dr. Xingping Zhou Prof. Dr. Xiaolin Xie Prof. Dr. Xianhong Wang Prof. Dr. Fosong Wang 《Angewandte Chemie (International ed. in English)》2018,57(14):3593-3597
The one‐step synthesis of well‐defined CO2‐based diblock copolymers was achieved by simultaneous ring‐opening copolymerization (ROCOP) of CO2/epoxides and RAFT polymerization of vinyl monomers using a trithiocarbonate compound bearing a carboxylic group (TTC‐COOH) as the bifunctional chain transfer agent (CTA). The double chain‐transfer effect allows for independent and precise control over the molecular weight of the two blocks and ensures narrow polydispersities of the resultant block copolymers (1.09–1.14). Notably, an unusual axial group exchange reaction between the aluminum porphyrin catalyst and TTC‐COOH impedes the formation of homopolycarbonates. By taking advantage of the RAFT technique, it is able to meet the stringent demand for functionality control to well expand the application scopes of CO2‐based polycarbonates. 相似文献
54.
Prof. Dr. Yuandong Xu Binyang Liu Chaoyang Dong Haoyang Feng Prof. Dr. Yajun Wei Prof. Dr. Xia Zhang 《欧洲无机化学杂志》2023,26(1):e202200569
Three-dimensional (3D) heterostructured molybdenum disulfide (MoS2) is used as base materials for aniline monomer in situ polymerization on its surface. It is found that the aniline addition has a remarkable effect on the energy storage of the final compounds due to the improvement of the conductivity and structure stability combined with the synergistic effect between the two types of species. The optimal compound of PANI@MoS2-150 not only shows a high capacitance value of 801.4 F ⋅ g−1 at a current density of 0.5 A ⋅ g−1 but also provides a high retention rate of 77.4 % after 10,000 cycles. The capacitance fading may be due to the increase of the internal resistance analyzed by EIS. Furthermore, a flexible symmetric supercapacitor based on PANI@MoS2-150 has also been fabricated and the specific capacitance reaches 105 F ⋅ g−1 at a current density of 1 A ⋅ g−1. Impressively, the capacitance retention is larger than 100 % undergoing 10,000 cycles. Besides, the highest energy density of 21 Wh ⋅ kg−1 was obtained. Additionally, the fabricated symmetric supercapacitor demonstrates excellent flexibility. 相似文献
55.
Synthesis of Discrete Alkyl‐Silica Hybrid Nanowires and Their Assembly into Nanostructured Superhydrophobic Membranes 下载免费PDF全文
Dr. Deliang Yi Chenglong Xu Ruidie Tang Assoc. Prof. Xuehua Zhang Prof. Frank Caruso Prof. Yajun Wang 《Angewandte Chemie (International ed. in English)》2016,55(29):8375-8380
We report the synthesis of highly flexible and mechanically robust hybrid silica nanowires (NWs) which can be used as novel building blocks to construct superhydrophobic functional materials with three‐dimensional macroporous networks. The hybrid silica NWs, with an average diameter of 80 nm and tunable length of up to 12 μm, are prepared by anisotropic deposition of the hydrolyzed tetraethylorthosilicate in water/n‐pentanol emulsions. A mechanistic investigation reveals that the trimethoxy(octadecyl)silane introduced to the water‐oil interface in the synthesis plays key roles in stabilizing the water droplets to sub‐100 nm and also growing a layer of octadecyl groups on the NW surface. This work opens a solution‐based route for the one‐pot preparation of monodisperse, hydrophobic silica NWs and represents an important step toward the bottom‐up construction of 3D superhydrophobic materials and macroporous membranes. 相似文献
56.
梯度法是求解无约束最优化的一类重要方法.步长选取的好坏与梯度法的数值表现息息相关.注意到BB步长隐含了目标函数的二阶信息,本文将BB法与信赖域方法相结合,利用BB步长的倒数去近似目标函数的Hesse矩阵,同时利用信赖域子问题更加灵活地选取梯度法的步长,给出求解无约束最优化问题的单调和非单调信赖域BB法.在适当的假设条件下,证明了算法的全局收敛性.数值试验表明,与已有的求解无约束优化问题的BB类型的方法相比,非单调信赖域BB法中e_k=‖x_k-x~*‖的下降呈现更明显的阶梯状和单调性,因此收敛速度更快. 相似文献
57.
Wang Y Shen Z Li B Zhang Y Zhang Y 《Chemical communications (Cambridge, England)》2007,(12):1284-1286
The dynamic kinetic resolution of 2-oxo-3-arylsuccinates was achieved vial-proline-catalyzed addition of acetone in acetonitrile at room temperature, providing the desired adduct in good yield with up to 87 : 13 dr and high ee up to 99%. 相似文献
58.
59.
光纤频带宽、线径细、抗电磁干扰、抗腐蚀。近年来它在高能粒子物理、聚变研究、核爆和核动力学诊断等不利环境中的应用,引起了人们极大的关注。本文将扼要介绍采用光纤传输的快脉冲辐射诊断系统,并以核爆诊断为例说明这类系统的特点及与以往同轴电缆传输系统相比的优越性。 相似文献
60.
GAO Biao LUO Yajun MIAO Changxi YUE Yinghong YANG Weimin HUA Weiming GAO Zi 《高等学校化学研究》2018,34(4):609-615
A series of Cr-SiO2 catalysts with a Cr content(mass fraction) ranging from 0.5% to 9% was prepared by a sol-gel method. The catalysts were characterized by XRD, N2 adsorption, EDX elemental mapping, Raman spectroscopy, UV-Vis spectroscopy, XPS and H2-TPR, and their catalytic behavior in the dehydrogenation of 1-butene to 1,3-butadiene(BD) using CO2 as a soft oxidant was studied. The initial BD yield is well correlated with the amount of Cr6+ in the fresh catalysts. The highest BD yield of ca. 34% is achieved on the catalysts with 5%-9% Cr at 600℃ and weight hourly space velocity(WHSV) of 4.5 g·gcat-1·h-1. The promoting effect of CO2 on the BD yield was observed, which can be attributed to the reaction coupling between a simple dehydrogenation of 1-butene and the reverse water-gas shift reaction as well as regaining the oxidation state(lattice oxygen) of reduced Cr3+ species due to the mild oxidation ability of CO2. The Cr-SiO2 catalyst exhibits higher BD yield than the Cr catalyst supported on SBA-15, which is attributed to the higher amount of Cr6+ present on the former catalyst. 相似文献