首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9139篇
  免费   1433篇
  国内免费   777篇
化学   6383篇
晶体学   92篇
力学   544篇
综合类   50篇
数学   1078篇
物理学   3202篇
  2024年   14篇
  2023年   203篇
  2022年   227篇
  2021年   311篇
  2020年   440篇
  2019年   365篇
  2018年   319篇
  2017年   298篇
  2016年   458篇
  2015年   452篇
  2014年   513篇
  2013年   652篇
  2012年   846篇
  2011年   817篇
  2010年   566篇
  2009年   535篇
  2008年   588篇
  2007年   449篇
  2006年   486篇
  2005年   364篇
  2004年   270篇
  2003年   229篇
  2002年   188篇
  2001年   145篇
  2000年   154篇
  1999年   189篇
  1998年   163篇
  1997年   132篇
  1996年   139篇
  1995年   120篇
  1994年   99篇
  1993年   83篇
  1992年   79篇
  1991年   78篇
  1990年   44篇
  1989年   40篇
  1988年   41篇
  1987年   34篇
  1986年   29篇
  1985年   24篇
  1984年   20篇
  1983年   23篇
  1982年   9篇
  1981年   14篇
  1980年   9篇
  1977年   6篇
  1976年   10篇
  1975年   9篇
  1973年   8篇
  1972年   6篇
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
61.
Operator Matrix Forms of Positive Operators   总被引:2,自引:0,他引:2  
If a 3-tuple (A:H1→H1,B:H2→H1,C:H2→H2)of operators on Hibert spaces is given,we proved that the operator ~↑A:=(↑A ↓B^*↑B ↓C) on H=H1 H2 is ≥0 is and only if A≥0,R(B)∪→R(A^1/2) and C≥B^* A^ b,where A^ is the generalized inverse of A.In general,A^ is a closed operator,but since R(B)∪→R(A^1/2,B^* A^ B is bounded yet.  相似文献   
62.
铸膜液的溶剂体系(溶剂和非溶剂)对不对称膜形态的形成有重要作用。为了探索溶剂和透气性间的关系,本文考虑到了制备BCA梯度密度不对称膜的各种溶剂的一系列物理参数,得到了一些定性结果,并指出了更全面、明确、解释两者关系的研究方向。  相似文献   
63.
For improved mechanical and water‐swelling properties of chitosan films, a series of transparent films were prepared with dialdehyde starch as a crosslinking agent. Fourier transform infrared and X‐ray analysis results demonstrated that the formation of Schiff's base disturbed the crystallization of chitosan. The mechanical properties and water‐swelling properties of the films were significantly improved. The best values of the tensile strength and breaking elongation were 113.1 MPa and 27.0%, respectively, when the dialdehyde starch content was 5%. All the crosslinked films still retained obvious antimicrobial effects toward S. aureus and E. coli, and they showed potential for biomedical applications. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 993–997, 2003  相似文献   
64.
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate.  相似文献   
65.
In this paper we develop a numerical method for computing higher order local approximations of center manifolds near steady states in Hamiltonian systems. The underlying system is assumed to be large in the sense that a large sparse Jacobian at the equilibrium occurs, for which only a linear solver and a low-dimensional invariant subspace is available. Our method combines this restriction from linear algebra with the requirement that the center manifold is parametrized by a symplectic mapping and that the reduced equation preserves the Hamiltonian form. Our approach can be considered as a special adaptation of a general method from Numer. Math. 80 (1998) 1-38 to the Hamiltonian case such that approximations of the reduced Hamiltonian are obtained simultaneously. As an application we treat a finite difference system for an elliptic problem on an infinite strip.  相似文献   
66.
论文系统地阐述了从原子、原子核到基本粒子内部结构研究的历史及现状,讨论了微观物理理论和实验研究的前景和展望.论文还阐述了微观物理与宏观物理(宇宙论和天体物理等)的结合与交叉,以无可争辨的实验事实阐明了微观世界和宏观世界的无限性.  相似文献   
67.
微观世界探索(续)   总被引:1,自引:1,他引:0  
论文系统地阐述了从原子、原子核到基本粒子内部结构研究的历史及现状,讨论了微观物理理论和实验研究的前景和展望.论文还阐述了微观物理与宏观物理(宇宙论和天体物理等)的结合与交叉,以无可争辨的实验事实阐明了微观世界和宏观世界的无限性.  相似文献   
68.
A diffusive predator-prey model in heterogeneous environment   总被引:1,自引:0,他引:1  
In this paper, we demonstrate some special behavior of steady-state solutions to a predator-prey model due to the introduction of spatial heterogeneity. We show that positive steady-state solutions with certain prescribed spatial patterns can be obtained when the spatial environment is designed suitably. Moreover, we observe some essential differences of the behavior of our model from that of the classical Lotka-Volterra model that seem to arise only in the heterogeneous case.  相似文献   
69.
Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied.  相似文献   
70.
An exfoliated poly(4,4-oxybis(benzene)disulfide) (POBDS)/vermiculite (VMT) nanocomposite was prepared by using cyclo(4,4-oxybis(benzene)disulfide) (COBDS) oligomers and cetyltrimethyl ammonium bromide exchanged VMT. The POBDS/VMT nanocomposites were fabricated in two steps. First, the COBDS oligomers were used to swell and exfoliate organo VMT to afford COBDS-VMT nanocomposite precursor. Subsequently, the exfoliated POBDS-VMT nanocomposite can be made via in situ and instant melt ring-opening polymerization of the COBDS-VMT nanocomposite precursor. High molecular weight POBDS polymer can be formed in a few minutes. The nano scale dispersion of VMT layers within POBDS polymer was confirmed by both the X-ray diffraction patterns and TEM examinations. This methodology provides a potential approach to synthesize high performance polymer nanocomposite.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号