Room-Temperature,Metal-Free,and One-Pot Preparation of 2H-Indazoles through a Mills Reaction and Cyclization Sequence

The Mills reaction and cyclization of readily available 2-aminobenzyl alcohols and nitrosobenzenes using thionyl bromide provided 2H-indazoles in up to 88 % yields. In the metal-free process, acetic acid played a crucial role for the both Mills reaction and cyclization. A brominated 2H-indazole could also be obtained through the one-pot sequence.     

Measurement of Residual Dipolar Couplings of Organic Molecules in Multiple Solvent Systems Using a Liquid-Crystalline-Based Medium

Residual dipolar coupling (RDC), a robust anisotropic NMR parameter for structural elucidation of organic molecules, is only accessible in an anisotropic environment. Herein, we introduce a novel alignment medium based on the molecular self-assembly of oligopeptide amphiphile (OPA). This medium is compatible with different intermediate and polar solvent systems, such as CD₃OD, [D₆]DMSO, and D₂O. The preparation of the OPA-based medium is simple and rapid, while only very weak background signals were observed from OPAs. Furthermore, we show that the purity of OPA has only a minor influence on the quality of the RDC data. These advantages allow RDC measurements of organic molecules with different polarities and solubilities with high efficiency and accuracy.     

岸基光电探测系统

论述两类岸基光电探测系统；岸基光电跟踪仪和岸基红外监视系统。阐述其典型实例、特点及发展方向。     

匀速运动的电偶极子的电场和磁场分布

本文通过对电偶极子电磁势的分析和相对论下电磁场在不同惯性系中的协变分布，计算了作匀速直线运动的电偶极子的电场和磁场的空间分布．     

量子位Heisenberg XX开链中边界量子位之间的纠缠

Heisenberg 开链对研究量子态在自旋链上的传递有重要的意义.本文研究了五量子位Heisenberg XX 开链中边界量子位之间的纠缠，在该系统中引入了磁杂质和系统杂质且它们之间满足线性关系时，该系统可以精确求解，此时边界量子位之间存在纠缠.选择合适的杂质参数和磁场参数，该边界纠缠的最大值可达到0.5. 关键词： Heisenberg XX开链 边界纠缠 杂质     

Ce3+对Er3+/Yb3+共掺氟磷酸盐玻璃光谱性质的影响

研究了能量接受离子Ce3+对Er3+上转换发光强度以及Er3+在1.5 μm附近波段发光性能参数的影响,并从能量匹配及能级结构角度出发对Er3+/Ce3+间的能量转移机制进行了分析.分析认为,4 I11/2能级的Er3+通过无辐射能量转移把能量传递给2F5/2能级的Ce3+激发其跃迁至2F7/2能级,而4I11/2能级上的Er3+则无辐射弛豫至4I13/2能级,从而有效降低氟磷酸盐玻璃中Er3+的上转换发光.当Er3+浓度为1.11×1020 cm-3时,Ce3+的最佳掺杂浓度为2.22×1020 cm-3,此时Ce3+的引入不仅可以降低上转换发光,而且有助于提高Er3+在1.5 μm附近波段的荧光强度、发射截面以及4I13/2能级荧光寿命.     

Reissner-Nordstr(o)m de Sitter黑洞的量子隧穿效应

运用Parikh的量子隧穿模型,研究了Reissner-Nordstr(o)m de Sitter黑洞的量子隧穿效应.结果表明,在能量守恒的条件下,黑洞外视界和宇宙视界处的粒子出射率与Bekenstein-Hawking熵有关,辐射谱不再是严格的纯热谱.     

Timing and detuning studies of a synchronously pumped mode-locked dye laser

The timing relationship between a synchronously pumped mode-locked dye laser and its pump laser is explored experimentally and theoretically. The experimental data is in quantitative agreement with numerical solutions of a semiclassical model that includes no free parameters. The data also agrees qualitatively with an approximate, analytic distillation of this model which is presented here for the first time. Our study has a direct bearing on the jitter and the long term stability of these important ultrashort pulse lasers.