Erratum： Silver-Doping Induced Lattice Distortion in TiO2 Nanoparticles [Chin. Phys. Lett. 26（2009）077809]

We found an error in our previous report [Chin. Phys. Lett. 26（2009）077809] concerning the JCPDS data which was used to compare with our data. It should read as JCPDS No 21-1272 （α = 3.7850A, c = 9.5140A, c/α = 2.5140, and V = 136.30A^3）,     

强激光辐照下预载柱壳热屈曲失效的数值分析

 采用有限元方法（ANSYS7.0）和简易的热力耦合本构关系,较系统地数值研究了预载柱壳受激光辐照时的热力响应和热屈曲失效行为,分析了几种壳体在不同预载条件下（轴压或内压）的屈曲模态和屈曲特征值,给出了屈曲模态和热屈曲失效与激光强度、辐照时间、预载条件和壳体几何尺度及形状间的定量或定性关系。计算结果表明：（1）屈曲失效行为主要集中在激光辐照区内且以径向屈曲为主。（2）在一定范围内,屈曲特征值与光斑中心点温度近似有线性关系。（3）激光辐照区内高温引起的材料软化和预载径向变形的耦合作用是柱壳发生热屈曲失效的根本原因,有效提高结构刚度,可使屈曲特征值提高。（4）壳体形状的改变对内压柱壳有更为明显的影响,其中圆柱形壳体屈曲特征值最大,因此具有较高的安全性。     

气相色谱-质谱法检测沉积物中自由态与束缚态多溴联苯醚和四溴双酚-A

建立了一种同时测定沉积物中不同赋存形态的多溴联苯醚(PBDEs)和四溴双酚A(TBBPA)的分析方法.样品由等体积的丙酮和正己烷混合溶剂抽提得到自由态目标物,再通过碱性水解反应释放束缚态目标化合物.通过调节酸度(pH值)实现PBDEs和TBBPA的分离和提取.PBDEs由复合硅胶柱净化,运用气相色谱-质谱(负离子化学源)-分时段选择离子监测技术测定;TBBPA经重氮甲烷衍生化反应后由酸性硅胶柱预纯化,运用气相色谱-质谱(电子轰击源)-分时段选择离子监测技术测定.8种低溴联苯醚(BDE28,-47,-66,-100,-99,-154,-153,-183),十溴联苯醚(BDE209)和TBBPA的检出限分别为0.6～12.5 pg/g,172 pg/g,4 2 pg/g.方法具有良好的准确度和精确度,回收率均在74%～106%之间,RSD≤10%.对东江沉积物样品的分析表明,本方法能够实现不同形态的PBDEs 和TBBPA的有效检测.     

超高效液相色谱-四极杆-飞行时间质谱对混合光合作用糖脂的分析

采用电喷雾电离源(ESI),分别在正离子模式下对混合单半乳糖甘油二酯、双半乳糖甘油二酯和在负离子模式下对混合硫代异鼠李糖甘油二酯进行超高效液相色谱-四极杆-飞行时间质谱的定性定量研究.结果表明,采用梯度洗脱,各组分在BEH C18柱上可得到良好分离,根据各特征碎片离子可以确定糖脂的种类和酰基组成,根据特征碎片离子信号强度之间的关系,可进一步确定各酰基的位置;采用等梯度洗脱可确定各组分占总组分的百分组成,从而测定出各组分在混合脂中的绝对含量.     

Sm（0.5）Sr（0.5）Co（0.4）M（0.6）O3（M=Co,Mn,Fe）作为IT-SOFCs阴极的结构与性能

通过X射线衍射(XRD)、热重、热膨胀、电导率以及交流阻抗等测试方法,研究了Sm0.5Sr0.5Co0.4M0.6O3(M=Co,Mn,Fe;分别简写为SSCC,SSCM,SSCF)作为中低温固体氧化物燃料电池(IT-SOFCs)阴极的结构与性能.研究表明,同相法合成的Sm0.5Sr0.5Co0.4M0.6O3均为正交钙钛矿型结构,材料的结构参数和性能都与M元素半径及M-O的键能有关.晶胞参数随着Co、Mn、Fe的顺序增大.材料的氧空位浓度、热膨胀系数、电导率、电极催化活性随着Co、Fe、Mn的顺序降低.同时由于SSCM较低的氧空位浓度,使得电极反应受到氧在电极内的扩散过程控制,具有较差的电极催化性能,而SSCC和SSCF较高的氧空位浓度,电极反应同时受到电极表面氧还原反应和氧离子在电极中的扩散过程混合控制.由于SSCF具有较高的氧扩散系数,使得700 ℃以上SSCF电极表面氧还原电阻(ASR)也低于SSCC的,因而出现了SSCF的总电极催化活性高于SSCC的现象.     

SiO2∶Sm粉体：溶胶-凝胶法制备及特殊荧光性能

采用溶胶-凝胶法制备SiO2:Sm粉体,通过TG-DSC、FTIR、MAS-NMR、PL对材料的结构和性能进行测试表征.FTIR分析显示样品位于960 cm-1的吸收峰归属于Si-O-Sm键的变形振动,29Si MAS-NMR证实Sm3+进入SiO2网络结构.在380 nm入射光激发下样品产生除Sm3+特征发光以外的蓝绿荧光,对不同Sm3+掺量样品荧光性能进行对比分析,结果表明这种特殊的荧光发射与Si-O-Sm键的形成有关.     

Attacks and Improvement of Quantum Sealed-Bid Auction with EPR Pairs

Recently, an experimentally feasible three-party quantum sealed-bid auction protocol based on EPR pairs [Z.Y. Wang, Commun. Theor. Phys. 54 （2010） 997] was proposed. However, this study points out Wang＇s protocol cannot resist some internal bidders＇ attacks, such as the Twiee-CNOT attack, the collusion attack. A malicious bidder can launch the Twice-CNOT attack to obtain the other＇s bid, or the dishonest auctioneer may collude with one bidder and help him/her win the action by changing his/her bid. For preventing against these attacks, a simple solution by using the QKD-based message encryption and a post-confirmation mechanism by adopting the hash function are proposed.     

Coherent beam combination of adaptive fiber laser array with tilt-tip and phase-locking control

We present an experimental study on tilt-tip(TT) and phase-locking(PL) control in a coherent beam combination(CBC) system of adaptive fiber laser array.The TT control is performed using the adaptive fiber-optics collimator(AFOC),and the PL control is realized by the phase modulator(PM).Cascaded and simultaneous controls of TT and PL using stochastic parallel gradient descent(SPGD) algorithm are investigated in this paper.Two-fiber-laser-,four-fiber-laser-,and six-fiber-laser-arrays are employed to study the TT and PL control.In the cascaded control system,only one high-speed CMOS camera is used to collect beam data and a computer is used as the controller.In a simultaneous control system one high-speed CMOS camera and one photonic detector(PD) are employed,and a computer and a control circuit based on field programmable gate array(FPGA) are used as the controllers.Experimental results reveal that both cascaded and simultaneous controls of TT using AFOC and PL using PM in fiber laser array are feasible and effective.Cascaded control is more effective in static control situation and simultaneous control can be applied to the dynamic control system directly.The control signals of simultaneous PL and TT disturb each other obviously and TT and PL control may compete with each other,so the control effect is limited.     

Performance of the muon detector A under TIBET Ⅲ array

In order to observe gamma rays in the 100 TeV energy region, the 4500 m² underground muon detector array using water Cherenkov technique is constructed, forming the TIBET Ⅲ+MD hybrid array. Because the showers induced by primary gamma rays contain much fewer muons than those induced by primary hadrons, significant improvement of the gamma ray sensitivity for TIBET Ⅲ+MD array is expected. In this paper, the design and performance of the MD-A detector with large Tyvek bag is reported.