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961.
Capillary electrochromatographic separation of amino acid enantiomers with molecularly imprinted polymers as chiral recognition agents 总被引:3,自引:0,他引:3
J.-M. Lin Tatsuro Nakagama Xing-Zheng Wu Katsumi Uchiyama Toshiyuki Hobo 《Analytical and bioanalytical chemistry》1997,357(1):130-132
The use of molecularly imprinted polymers polymerized in a capillary for the separation of amino acid enantiomers by electrochromatography
is described. The substrate-selective polymers were prepared by using l-phenylalanine anilide as print molecule and methacrylic acid as the functional monomer. The treatment of the inside surface
of the capillary, the composition of the polymer and the electrochromatographic running conditions were investigated. This
preliminary report demonstrated a novel and simple method for capillary electrochromatographic separations of amino acid enantiomers
using molecularly imprinted polymers.
Received: 9 April 1996 / Revised: 8 August 1996 / Accepted: 8 August 1996 相似文献
962.
用高效液相色谱跟踪2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷(MMTN)与丙烯腈(AN),丙烯酸甲酯(MA)的共聚合反应。根据Lowry-Meyer共聚积分方程式,采用插值法进行数据拟合测定单体的竞聚率。对于体系MMTN(M_1)-AN(M_2),r_1=0.048;r_2=0.213;MMTN(M_1)-MA(M_2)r_1=0.025,r_2=0.764。说明两组共聚体系均有较强的交替共聚趋势。 相似文献
963.
Toshiyuki Kobayashi 《Inventiones Mathematicae》1994,117(1):181-205
Summary LetGG be real reductive Lie groups and q a -stable parabolic subalgebra of Lie (G) . This paper offers a sufficient condition on (G, G, q) that the irreducible unitary representation
ofG with non-zero continuous cohomology splits into a discrete sum of irreducible unitary representations of a subgroupG, each of finite multiplicity. As an application to purely analytic problems, new results on discrete series are also obtained for some pseudo-Riemannian (non-symmetric) spherical homogeneous spaces, which fit nicely into this framework. Some explicit examples of a decomposition formula are also found in the cases whereA
q is not necessarily a highest weight module.Oblatum 3-IV-1993The author is supported by the NSF grant DMS-9100383. 相似文献
964.
Toshiaki Ito Toshiyuki Morii Morimitsu Tanimoto 《Zeitschrift fur Physik C Particles and Fields》1993,59(1):57-61
We have studied the heavy flavored hadron spectroscopy, which is motivated by the heavy quark effective theory. TheQ \(\bar q\) ,Qqq andQQq hadrons have been investigated systematically. Regarding thes-quark as a member of heavy quarks, the predicted mass levels of both theQqq andQQq baryons are quite consistent with experimental ones. 相似文献
965.
966.
The Baker's yeast reduction of 1-(1,3-dithian-2-yl)-1,2-propanedione gave highly enantio-and diastereoselectively (S)-(+)-(1-1,3-dithian-2-yl)-2-hydroxy-1-propanone or (1S,23-(+)-(1)-(1,3-dithian-2-yl-1,2-propanediol, depending on the reaction time. The hydroxy ketone was reduced with diisobutylaluminum hydride to give (1R,2S)-1-(1,3-dithian-2-yl)-1,2-propanediol with high diastereoselectivity. The former (1S,2S)-diol was converted into L-digitoxose. 相似文献
967.
Toshiyuki Kodaira Miyuki Okumura Michio Urushisaki Kimio Isa 《Journal of polymer science. Part A, Polymer chemistry》1993,31(1):169-176
The effect of bulky N-substitutents of N-t-butyl- and N-phenyl-N-allylmethacrylamides (BAMA and PAMA, respectively) on their cyclopolymerizability was investigated. BAMA yielded an almost completely cyclized polymer while the degree of cyclization of poly (PAMA) was about 95%. The latter value indicates that the effect of phenyl group is comparable with that of methyl group, since N-methyl-N-allylmethacrylamide was reported to give a polymer with a degree of cyclization of 93%. Structural investigation on telomerization products of BAMA and PAMA permitted the assignment of the repeating cyclic units of these polymers to that of a five-membered ring. This structural characteristic was also supported by the observation of five-membered cyclized radicals on ESR measurements of these monomers. Rotation around amide C? N bonds of these monomers and related compounds studied by 13C-NMR was found to be strongly dependent on N-substitutents. The mechanism of the cyclization was discussed in terms of the structure of the ring formed and rotation around amide C? N bonds of these monomers. The reactivity of the methacryloyl and allyl groups involved in these monomers were compared based on the information obtained by structural investigation of polymers and telomerization products and by ESR studies. © 1993 John Wiley & Sons, Inc. 相似文献
968.
Synthesis of optically active 2,3-dihydrofuran derivatives has been accomplished through a combination strategy of ferric ion-catalyzed cycloaddition of styrene derivatives with quinones and following lipase-catalyzed enantioselective acylation. 相似文献
969.
Chirality induction of π-conjugated polyanilines through chiral complexation with the chiral palladium(II) complexes was demonstrated to afford the chiral conjugated polymer complexes. Complexation of the emeraldine base of poly(o-toluidine) (POT) with the chiral palladium(II) complex bearing one labile coordination site led to the formation of the chiral conjugated polymer complex, which exhibited an induced circular dichroism (ICD) based on the chirality induction into a π-conjugated backbone. The mirror image of the CD signal was observed with the chiral conjugated polymer complex, which was obtained from the chiral palladium(II) complex possessing the opposite configuration. The chirality of the podand ligand moieties of the palladium complex is considered to induce a propeller twist of the π-conjugated molecular backbone. The crystal structure of the chiral conjugated complex of N-bis(4′-dimethylaminophenyl)-1,4-benzoquinonediimine (L3) as a model compound of the polyaniline revealed a chiral propeller twist conformation of the π-conjugated backbone. Furthermore, chiral complexation with the cationic palladium(II) complexes provided the ionic chiral conjugated complexes. 相似文献
970.
Amphiphilic poly(gamma-glutamic acid) (gamma-PGA) was prepared by the introduction of L-phenylalanine ethylester (L-PAE) as a side chain. This gamma-PGA-graft-L-PAE formed monodispersed nanoparticles in water. The particle size of the gamma-PGA nanoparticles could be controlled by the degree of L-PAE grafting. The hydrolytic degradation and enzymatic degradation by gamma-glutamyl transpeptidase (gamma-GTP) of these gamma-PGA nanoparticles was studied by gel permeation chromatography (GPC) and scanning electron microscopy (SEM). The hydrolysis ratio of gamma-PGA was found to decrease upon increasing the hydrophilicity of the gamma-PGA. The degradation of the gamma-PGA backbone by gamma-GTP resulted in a dramatic change in nanoparticle morphology. With increasing time, the gamma-PGA nanoparticles reduced in size and finally disappeared completely.Time-course of the changes in the morphology of the gamma-PGA nanoparticles following incubation with gamma-glutamyl transpeptidase. 相似文献