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801.
We consider a class of second order quasilinear differential equations with singular ninlinearities. Our main purpose is to investigate in detail the asymptotic behavior of their solutions defined on a positive half-line. The set of all possible positive solutions is classified into five types according to their asymptotic behavior near infinity, and sharp conditions are established for the existence of solutions belonging to each of the classified types. 相似文献
802.
803.
804.
Keiichiro Sugimoto Midori Amako Hiroaki Takeuchi Kazuya Nakagawa Morio Yoshimura Yoshiaki Amakura Tomoyuki Fujita Shigeo Takenaka Hiroshi Inui 《Molecules (Basel, Switzerland)》2022,27(1)
Inhibition of fructose absorption may suppress adiposity and adiposity-related diseases caused by fructose ingestion. Eucalyptus leaf extract (ELE) inhibits intestinal fructose absorption (but not glucose absorption); however, its active compound has not yet been identified. Therefore, we evaluated the inhibitory activity of ELE obtained from Eucalyptus globulus using an intestinal fructose permeation assay with the human intestinal epithelial cell line Caco-2. The luminal sides of a cell monolayer model cultured on membrane filters were exposed to fructose with or without the ELE. Cellular fructose permeation was evaluated by measuring the fructose concentration in the medium on the basolateral side. ELE inhibited 65% of fructose absorption at a final concentration of 1 mg/mL. Oenothein B isolated from the ELE strongly inhibited fructose absorption; the inhibition rate was 63% at a final concentration of 5 μg/mL. Oenothein B did not affect glucose absorption. In contrast, the other major constituents (i.e., gallic acid and ellagic acid) showed little fructose-inhibitory activity. To our knowledge, this is the first report that oenothein B in ELE strongly inhibits fructose absorption in vitro. ELE containing oenothein B can prevent and ameliorate obesity and other diseases caused by dietary fructose consumption. 相似文献
805.
Synthesis of Poly(L‐lactide) with One Terminal D‐Glucose Residue and Wettability of Its Film Surface
To develop the new‐type poly(L ‐lactide)‐based biomedical material having a wettable surface, the synthesis of poly(L ‐lactide) with one terminal D ‐glucose residue was investigated. After the hydroxyl group at 1‐C of α‐tetrabenzyl glucose, α‐Glc(Bzl)4, was converted to the corresponding potassium alkoxide by using potassium tert‐butoxide, L ‐lactide (L ‐LA) was polymerized in the presence of α‐Glc(Bzl)4‐OK as an initiator in tetrahydrofuran at room temperature to prepare α‐Glc(Bzl)4‐polyLA. Subsequently, the removal of O‐protecting benzyl groups in the terminal α‐Glc(Bzl)4 residue was carried out by hydrogenolysis with Pd/C to obtain the objective D ‐glucose‐end‐capped polyLA, α‐Glc‐polyLA. The wettability of surface of the α‐Glc‐polyLA material is discussed using the difference of the dynamic contact angle between a α‐Glc‐polyLA/homopolyLA blend film and a film of the polyLA homopolymer. 相似文献
806.
Fumio Toda Koichi Tanaka Tomoyuki Tamashima Masako Kato 《Angewandte Chemie (International ed. in English)》1998,37(19):2724-2727
A conrotatory [2+2] cyclization is the second step in the solid-state thermal reaction of s-trans-tetraaryldibromohexatetraenes 1 to cyclobutenes 4 . Prior to the cyclization 1 rearranges into the cis conformer 3 . Surprisingly the thermal rearrangement and the stereoselective cyclization occur readily in spite of the required motion of the sterically bulky substituents. R=Ph, p-MeC6H4. 相似文献
807.
Kenzo Inoue Hidehito Miyamoto Tomoyuki Itaya 《Journal of polymer science. Part A, Polymer chemistry》1997,35(9):1839-1847
Novel multiarmed polymers with ethylene oxide units, [( CH2CH2O)n : 7, n = 3; 8, n= 7.2; 9, n = 11.8, and 12, n = 11.8] were prepared from the reaction of polyethylene glycol monomethyl ethers with acid chlorides of hexakis(3,5-dicarboxyphenoxy)-( 6 ) and hexakis(4-carboxyphenoxy)cyclotriphosphazenes ( 11 ) and conductivities of their Li+ salt complexes were investigated. The glass transition temperatures of the salt-free polymers are in the temperature range −59 to −54°C, indicative of a high degree of reorientational mobility of the arms. When LiClO4 was added to the multiarmed polymers, the Tg values raised monotonically. The extent of Tg elevation was affected by the length of arms and the number of oxygen atoms around cyclotriphosphazene core and increased in the order 7 > 8 > 12 > 9 . The conductivities increased in the order 9 > 8 = 12 > 7 and the maximum conductivities of 4.0 × 10−5 S/cm at 30°C and 6.0 × 10−4 S/cm at 90°C have been achieved for the 9 -Li+ complex with Li+/O = 0.03. Interestingly, the conductivity of 9 -Li+ complexes at constant reduced temperatures increased in the whole concentrations of LiClO4 examined (Li+/O = 0.01–0.2), although the degree of increase in conductivity above Li+/O = 0.06 became small. From the behaviors of Tg and the conductivity of multiarmed polymer–LiClO4 complexes, it appears that the conductivity is governed by relative concentrations of inter- and intramolecular complexes in the polymer matrix. The influence of structural change of the comb-shaped to multiarmed polymers on the conductivity is described. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35 : 1839–1847, 1997 相似文献
808.
Eishun Tsuchida Teruyuki Komatsu Yasuko Mastukawa Tomoyuki Okada 《Macromolecular Symposia》2002,186(1):1-6
Incorporation of different structured synthetic hemes, 5,10,15,20-tetraphenylporphyrinatoiron(II) derivetives with a covalently linked proximal base [FeP( 1 ) to FeP( 7 )], into human serum albumin (HSA), provides seven types of albumin-heme hybrids (HSA-FeP) with different O2-binding abilities. An HSA host absorbs a maximum of eight FeP molecules in each case. The obtained all HSA-FePs can reversibly bind and release O2 under physiological conditions (in aqueous media, pH 7.3, 37°C) as similar as hemoglobin and myoglobin. The difference in the fence structures did not affect the O2-binding parameters, however the axial histidine coordination significantly increased the O2-binding affinity, which is ascribed to the low O2-dissociation rate constants. The most remarkable effect of the heme structure appeared in the half-lifetime (τ1/2) of the O2-adduct complex. The dioxygenated rHSA-FeP( 4 ) showed an unusually long lifetime (τ1/2: 25 hr at 37°C) which is ca. 13-fold longer than that of rHSA-FeP( 1 ). 相似文献
809.
5-(4-Trimethylsilyethynylphenyl)-10,15,20-triphenylplatinumporphyrin was synthesized and copolymerized with trimethylsilylpropyne to give a new high-molecular-weight porphyrin polymer. The polymer formed a smooth and tough coating on many types of surfaces. The coating showed a strong blue luminescence from the platinumporphyrin residue which was quenched in the presence of oxygen. The relationship of the luminescence intensity vs oxygen pressure displayed a remarkably high pressure sensitivity in the low oxygen pressure area, which was ascribed to the high oxygen permeability of the polymer. 相似文献
810.
Jun Manabe Nagisa Sako Mizuki Ito Dr. Masaru Fujibayashi Dr. Chisato Kato Dr. Goulven Cosquer Prof. Katsuya Inoue Dr. Kiyonori Takahashi Prof. Takayoshi Nakamura Prof. Tomoyuki Akutagawa Dr. Seiya Shimono Dr. Hiroki Ishibashi Prof. Yoshiki Kubota Prof. Sadafumi Nishihara 《欧洲无机化学杂志》2023,26(34):e202300449
Materials exhibiting irreversible phase transitions, leading to changes in their properties, have a potential for novel application in electronic components such as a non-rewritable high-security memory. Here, we focused on the two salts, [(9-triptycylammonium)([18]crown-6)][Ni(dmit)2] ( 1 ) and [(9-triptycylammonium)([15]crown-5)][Ni(dmit)2] ( 2 ), which featured 2D sheet structures with alternately stacked cation and anion layers. Both salts exhibit similar cation arrangements, however, their anion arrangements differ significantly. The temperature-dependent magnetic susceptibilities of 1 and 2 were well reproduced by the alternating chain model (JAC1/kB=−306(8), JAC2/kB=−239(3) K) and the Curie-Weiss model (θ=−3.9(1) K), respectively. 1 experience a reversible phase transition around 40–60 K, causing anomalies in magnetic behavior. Moreover, an irreversible single-crystal-to-single-crystal phase transition to 1′ undergo at ~381 K, inducing a rearrangement of [Ni(dmit)2]− anions and a resistivity decrease from 6.5×106 to 6.5×102 Ω cm. The susceptibility curve of 1′ was reproduced by a combination of the Curie-Weiss and dimer models (Jdimer/kB=−407(5), θ=−26.7(5) K). The irreversible transition of 1 is the first example for such supramolecule and [Ni(dmit)2]− system to our knowledge, in opening potential new-type materials. 相似文献