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71.
Daniel P. Silva Tomáš Brányik Giuliano Dragone António A. Vicente José A. Teixeira João B. Almeida e Silva 《Chemical Papers》2008,62(1):34-41
This study deals with two innovative brewing processes, high gravity batch and complete continuous beer fermentation systems.
The results show a significant influence of the variables such as concentration and temperature on the yield factor of the
substrate into ethanol and consequently on the productivity of the high gravity batch process. The technological feasibility
of continuous production of beer based on yeast immobilization on cheap alternative carriers was also demonstrated. The influence
of process parameters on fermentation performance and quality of the obtained beers was studied by sensorial analysis. No
significant difference in the degree of acceptance between the obtained products and some traditional market brands was found.
Presented at the 34th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 21–25 May
2007. 相似文献
72.
R. Serna C. N. Afonso F. Catalina N. Teixeira M. F. da Silva J. C. Soares 《Applied Physics A: Materials Science & Processing》1992,54(6):538-542
Thin films consisting of 3 or 4 Sb and Ge alternating layers are irradiated with single nanosecond laser pulses (12 ns, 193 nm). Real time reflectivity (RTR) measurements are performed during irradiation, and Rutherford backscattering spectrometry (RBS) is used to obtain the concentration depth profiles before and after irradiation. Interdiffusion of the elements takes place at the layer interfaces within the liquid phase. The reflectivity transients allow to determine the laser energy thresholds both to induce and to saturate the process being both thresholds dependent on the multilayer configuration. It is found that the energy threshold to initiate the process is lower when Sb is at the surface while the saturation is reached at lower energy densities in those configurations with thinner layers. 相似文献
73.
Each alternative for a repair contract implies a specific responsetime and related cost. The response time is associated withthe commitment of repair time, based on the contract. A decisionmaker chooses the best alternative taking into account the systemperformance and the cost of the contract. This problem has beenanalysed through a multicriteria decision model. This decisionmodel supports decision makers in the determination of the bestcombination of contracting conditions. The decision model proposedallows the decision maker to quantify the consequences of anaction taking into account two basic criteria: the cost of thecontract and the system performance. Two different decisionmodels have been built to support decision makers. These decisionmodels are based on different multicriteria approaches. Thefirst, reported in a previous paper, is based on the multiattributeutility theory (MAUT). The model presented in this paper isbased on the ELECTRE I method combined with utility functions.The paper presents the main theoretical aspects related to bothapproaches and practical implications related to model building.A numerical application is presented in order to illustratethe use of the decision model. 相似文献
74.
M. Melo O. Frazão A.L.J. Teixeira L.A. Gomes J.R. Ferreira da Rocha H.M. Salgado 《Applied physics. B, Lasers and optics》2003,77(1):139-142
In this paper, we present a continuous-wave tunable fibre ring laser operating in the L-band. A bi-directional pumped L-band erbium-doped fibre amplifier provides gain to the loop. Tunability is achieved by bending a single-mode fibre taper using a micrometer drive, controlling in this way the spectral cavity losses. Laser emission is achieved between 1587 and 1606 nm, and low variation of the output laser power is observed over all the tuning range. PACS 42.55.Wd; 42.60.Da 相似文献
75.
76.
Jaume Llibre Paulo R. da Silva Marco A. Teixeira 《Journal of Dynamics and Differential Equations》2007,19(2):309-331
Singular perturbations problems in dimension three which are approximations of discontinuous vector fields are studied in
this paper. The main result states that the regularization process developed by Sotomayor and Teixeira produces a singular
problem for which the discontinuous set is a center manifold. Moreover, the definition of sliding vector field coincides with
the reduced problem of the corresponding singular problem for a class of vector fields.
相似文献
77.
78.
Lucimara Mendonça CostaEmerson Schwingel Ribeiro Mariana Gava SegatelliDanielle Raphael do Nascimento Fernanda Midori de OliveiraCésar Ricardo Teixeira Tarley 《Spectrochimica Acta Part B: Atomic Spectroscopy》2011,66(5):329-337
The present study describes the adsorption characteristic of Cd(II) onto Nb2O5/Al2O3 mixed oxide dispersed on silica matrix. The characterization of the adsorbent has been carried out by infrared spectroscopy (IR), scanning electronic microscopy (SEM), energy dispersive spectroscopy (EDS), energy dispersive X-ray fluorescence analysis (EDXRF) and specific surface area (SBET). From batch experiments, adsorption kinetic of Cd(II) was described by a pseudo-second-order kinetic model. The Langmuir linear isotherm fitted to the experimental adsorption isotherm very well, and the maximum adsorption capacity was found to be 17.88 mg g−1. Using the effective material, a method for Cd(II) preconcentration at trace level was developed. The method was based on on-line adsorption of Cd(II) onto SiO2/Al2O3/Nb2O5 at pH 8.64, in which the quantitative desorption occurs with 1.0 mol L−1 hydrochloric acid towards FAAS detector. The experimental parameters related to the system were studied by means of multivariate analysis, using 24 full factorial design and Doehlert matrix. The effect of SO42−, Cu2+, Zn2+ and Ni2+ foreign ions showed no interference at 1:100 analyte:interferent proportion. Under the most favorable experimental conditions, the preconcentration system provided a preconcentration factor of 18.4 times, consumption index of 1.08 mL, sample throughput of 14 h−1, concentration efficiency of 4.35 min−1, linear range from 5.0 up to 35.0 μg L−1 and limits of detection and quantification of 0.19 and 0.65 μg L−1 respectively. The feasibility of the proposed method for Cd(II) determination was assessed by analysis of water samples, cigarette sample and certified reference materials TORT-2 (Lobster hepatopancreas) and DOLT-4 (Dogfish liver). 相似文献
79.
Teixeira C Gomes JR Couesnon T Gomes P 《Journal of computer-aided molecular design》2011,25(8):763-775
Comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA) based on three-dimensional
quantitative structure–activity relationship (3D-QSAR) studies were conducted on a series (39 molecules) of peptidyl vinyl
sulfone derivatives as potential Plasmodium Falciparum cysteine proteases inhibitors. Two different methods of alignment were employed: (i) a receptor-docked alignment derived
from the structure-based docking algorithm GOLD and (ii) a ligand-based alignment using the structure of one of the ligands
derived from a crystal structure from the PDB databank. The best predictions were obtained for the receptor-docked alignment
with a CoMFA standard model (q
2 = 0.696 and r
2 = 0.980) and with CoMSIA combined electrostatic, and hydrophobic fields (q
2 = 0.711 and r
2 = 0.992). Both models were validated by a test set of nine compounds and gave satisfactory predictive r
2
pred values of 0.76 and 0.74, respectively. CoMFA and CoMSIA contour maps were used to identify critical regions where any change
in the steric, electrostatic, and hydrophobic fields may affect the inhibitory activity, and to highlight the key structural
features required for biological activity. Moreover, the results obtained from 3D-QSAR analyses were superimposed on the Plasmodium Falciparum cysteine proteases active site and the main interactions were studied. The present work provides extremely useful guidelines
for future structural modifications of this class of compounds towards the development of superior antimalarials. 相似文献
80.
Ferreres F Taveira M Gil-Izquierdo A Oliveira L Teixeira T Valentão P Simões N Andrade PB 《Rapid communications in mass spectrometry : RCM》2011,25(14):1972-1980
High-performance liquid chromatography-diode array detection-electrospray ionization multi-stage mass spectrometry (HPLC-DAD-ESI-MS(n)) is considered to be a very valuable tool for the characterization of compounds found in trace amounts in natural matrices, as their previous isolation and clean-up steps can be avoided. Micro-scale separation increases the potential of this analytical technique, allowing the determination of compounds in reduced samples. Spodoptera littoralis represents a major challenge to Solanaceae plants, as it is one of the most deleterious pests. The S. littoralis/Lycopersicon esculentum system was studied for the first time concerning glycoalkaloids and phenolics. Using HPLC-DAD-ESI-MS(n) we were able to characterize 15 phenolic compounds in L. esculentum leaves. Nine of them are reported for the first time. Some differences were found between leaves of cerasiforme and 'Bull's heart' varieties. However, in the materials of S. littoralis (larvae, adults, exuviae and excrements) reared in both L. esculentum leaves no phenolics were identified. α-Tomatine was the main glycoalkaloid in the host plant. The glycoalkaloid composition of the different S. littoralis materials was distinct, with α-tomatine and dehydrotomatine being the main detected compounds in larvae and excrements. These results add knowledge to the ecological interaction in this insect/plant duo, for which it is hard to obtain considerable sample amounts. 相似文献