全文获取类型
收费全文 | 1199篇 |
免费 | 60篇 |
国内免费 | 3篇 |
专业分类
化学 | 1001篇 |
晶体学 | 7篇 |
力学 | 23篇 |
数学 | 100篇 |
物理学 | 131篇 |
出版年
2023年 | 7篇 |
2022年 | 9篇 |
2021年 | 49篇 |
2020年 | 41篇 |
2019年 | 46篇 |
2018年 | 46篇 |
2017年 | 35篇 |
2016年 | 59篇 |
2015年 | 57篇 |
2014年 | 38篇 |
2013年 | 85篇 |
2012年 | 81篇 |
2011年 | 103篇 |
2010年 | 57篇 |
2009年 | 51篇 |
2008年 | 79篇 |
2007年 | 84篇 |
2006年 | 60篇 |
2005年 | 67篇 |
2004年 | 55篇 |
2003年 | 34篇 |
2002年 | 30篇 |
2001年 | 20篇 |
2000年 | 14篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 4篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有1262条查询结果,搜索用时 15 毫秒
101.
Gloria Brusotti Tatiana Adrienne Ngueyem Raffaela Biesuz Gabriele Caccialanza 《Journal of separation science》2010,33(11):1692-1697
Euphorbiaceae barks are known to contain an appreciable amount of polyphenolic compounds responsible for several biological activities. Preliminary extraction from Bridelia grandis stem bark afforded high content of polyphenols, determined by spectrophotometric methods such as Folin–Ciocalteu (for total phenols, TP) and n‐butanol‐HCl (for condensed tannins, CT). A preliminary Plackett–Burman screening design was used to identify the key factors that influence the TP and CT extraction. Between all the variables known to influence the extraction from vegetable matrixes, six were selected; maceration was chosen as traditional extraction methodology. To investigate the effect of solvents and extraction method, methanol, acetone 70% (v/v in water), centrifugation and ultrasound were chosen. A full factorial design 23 was applied to optimize the extraction procedure. The responses were obtained analyzing the extracts for their TP and CT contents determined by the above‐mentioned spectrophotometric methods. The results confirm that, within the explored domain, the optimum solvent is methanol and the optimum method is one‐cycle centrifugation. Finally, it was also compared with the effect of maceration on the considered responses. It has never given results better than centrifugation, whereas in the case of CT it represents an advantage to employ a three‐cycle centrifugation instead of one. 相似文献
102.
Tatiana Sodero 《Bulletin of the Brazilian Mathematical Society》2011,42(3):439-454
A sectional-Anosov flow is a flow for which the maximal invariant set is sectional-hyperbolic. A generalized 3-handlebody
is a compact manifold which is built from a 3-disc attaching 0, 1, 2 and 3-handles at its boundary, one at a time, by attaching
maps. We prove that there exist a class of orientable generalized 3-handlebodies supporting sectional-Anosov flows, moreover
this class of manifolds is strictly large than the previous one studied in [14]. 相似文献
103.
Emilio L. Cano Javier M. Moguerza Tatiana Ermolieva Yuri Ermoliev 《Computational Management Science》2014,11(1-2):25-44
Due to deregulations of the energy sector and the setting of targets such as the 20/20/20 in the EU, operators of public buildings are now more exposed to instantaneous (short-term) market conditions. On the other hand, they have gained the opportunity to play a more active role in securing long-term supply, managing demand, and hedging against risk while improving existing buildings’ infrastructures. Therefore, there are incentives for the operators to develop and use a Decision Support System to manage their energy sub-systems in a more robust energy-efficient and cost-effective manner. In this paper, a two-stage stochastic model is proposed, where some decisions (so-called first-stage decisions) regarding investments in new energy technologies have to be taken before uncertainties are resolved, and some others (so-called second-stage decisions) on how to use the installed technologies will be taken once values for uncertain parameters become known, thereby providing a trade-off between long- and short-term decisions. 相似文献
104.
105.
Mikhail Elyashberg Kirill Blinov Yegor Smurnyy Tatiana Churanova Antony Williams 《Magnetic resonance in chemistry : MRC》2010,48(3):219-229
The accuracy of 13C chemical shift prediction by both DFT GIAO quantum‐mechanical (QM) and empirical methods was compared using 205 structures for which experimental and QM‐calculated chemical shifts were published in the literature. For these structures, 13C chemical shifts were calculated using HOSE code and neural network (NN) algorithms developed within our laboratory. In total, 2531 chemical shifts were analyzed and statistically processed. It has been shown that, in general, QM methods are capable of providing similar but inferior accuracy to the empirical approaches, but quite frequently they give larger mean average error values. For the structural set examined in this work, the following mean absolute errors (MAEs) were found: MAE(HOSE) = 1.58 ppm, MAE(NN) = 1.91 ppm and MAE(QM) = 3.29 ppm. A strategy of combined application of both the empirical and DFT GIAO approaches is suggested. The strategy could provide a synergistic effect if the advantages intrinsic to each method are exploited. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
106.
Robson Miranda da Gama Tatiana Santana Balogh Simone França Tânia Cristina Sá Dias Valcinir Bedin André Rolim Baby Jivaldo do Rosário Matos Maria Valéria Robles Velasco 《Journal of Thermal Analysis and Calorimetry》2011,106(2):399-405
This research aimed the effect on Caucasian hair tresses treated with oxidative hair dye, either incorporated or not with
conditioners agents, analyzed by Differential Scanning Calorimetry (DSC) and Thermogravimetric analysis (TG). The formulations
of hair dyes were emulsions oil-in-water with light blond color containing or not the conditioners agents: silanetriol and
panthenol; PEG-12 dimethicone; hydrolyzed silk, hydrolyzed milk protein, and lactose. Each dye (1.5 g) was applied in the
hair tress (2.0 g/20.0 cm of length of Caucasian light-brown), previously treated, more 1.5 g of hydrogen peroxide 20 vol
during 40 min. Evaluation of mass loss of the different hair sample demonstrates that these chemical hair treatments impair
the hair fibers, reduced their moisture content with respect to the untreated hair. The incorporation of conditioners agents
(silanetriol and panthenol; PEG-12 dimethicone; hydrolyzed silk, hydrolyzed milk protein, and lactose) in oxidative hair dyes
types did not decrease the damage caused on the tresses by the coloring process quantified by TG/DTG. However, the DSC curves
demonstrated those conditioners agents (silanetriol and panthenol; PEG-12 dimethicone) dislocated the beginning of the third
event in 20 °C and they inhibited the presence of the fourth event, having characterized thermal protection to the hair. 相似文献
107.
108.
109.
Motivated by Bonahon’s result for hyperbolic surfaces, we construct an analogue of the Patterson–Sullivan–Bowen–Margulis map
from the Culler–Vogtmann outer space CV (F
k
) into the space of projectivized geodesic currents on a free group. We prove that this map is a continuous embedding and
thus obtain a new compactification of the outer space. We also prove that for every k ≥ 2 the minimum of the volume entropy of the universal covers of finite connected volume-one metric graphs with fundamental
group of rank k and without degree-one vertices is equal to (3k − 3) log 2 and that this minimum is realized by trivalent graphs with all edges of equal lengths, and only by such graphs.
Received: December 2005, Accepted: March 2006 相似文献
110.
Parthasarathy R Bykhovski A Gelmont B Globus T Swami N Woolard D 《Physical review letters》2007,98(15):153906
In this work, a theoretical study of the coupling of TM polarized subterahertz (THz) radiation with periodic semiconductor rectangular slot arrays was conducted, using InSb as an example. Simulation results showed that the structure with 4-12 microm thickness provides over a 20-30-fold increase in the electric field at slot edges in a nanosize region ( approximately 500 nm). The enhancement of the THz electromagnetic field extends across the slots and reaches peak values at the edges due to discontinuity effects. Because of the strong local electromagnetic field enhancement, the structure can potentially be used for the development of novel biophotonic sensors, leading to improved detection sensitivity. 相似文献