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41.
Dai Tsukada Yuta Matsumoto Ryo Sasaki Michitoshi Takeishi Takanobu Saito Noritaka Usami Takashi Suemasu 《Journal of Crystal Growth》2009,311(14):3581-3586
We have prepared (1 1 1)-oriented Si layers on SiO2 (fused silica) substrates from amorphous-Si(a-Si)/Al or Al/a-Si stacked layers using an aluminum-induced crystallization (AIC) method. The X-ray diffraction (XRD) intensity from the (1 1 1) planes of Si was found to depend significantly on growth conditions such as the thicknesses of Si and Al, deposition order (a-Si/Al or Al/a-Si on SiO2), deposition technique (sputtering or vacuum evaporation) and exposure time of the Al layer to air before the deposition of Si. The crystal orientation of the Si layers was confirmed by θ−2θ, 2θ XRD and electron backscatter diffraction (EBSD). The photoresponse properties of semiconducting BaSi2 films formed on the (1 1 1)-oriented Si layers by the AIC method were measured at room temperature. Photocurrents were clearly observed for photon energies greater than 1.25 eV. The external quantum efficiencies of the BaSi2 were also evaluated. 相似文献
42.
Sanji T Yoshiwara A Sakurai H Tanaka M 《Chemical communications (Cambridge, England)》2003,(13):1506-1507
The first example of induced optical activity of oligosilanes within the internal cavity of gamma-cyclodextrins is reported. 相似文献
43.
Masahiro IWAKURA Kazuki OKURA Mika KUBOTA Keiyu SUGAWARA Atsuyoshi KAWAGOSHI Hitomi TAKAHASHI Takanobu SHIOYA 《Physical Therapy Research》2021,24(1):35
Objective: To estimate the minimal clinically important difference (MCID) of quadriceps and inspiratory muscle strength after a home-based pulmonary rehabilitation program (PRP) in chronic obstructive pulmonary disease (COPD). Method: Eighty-five COPD patients were included. Quadriceps maximal voluntary contraction (QMVC) was measured. We measured maximal inspiratory mouth pressure (PImax), the 6-minute walk distance (6MWD), the chronic respiratory questionnaire (CRQ) and the modified Medical Research Council dyspnoea score (mMRC). All measurements were conducted at baseline and at the end of the PRP. The MCID was calculated using anchor-based (using 6MWD, CRQ, and mMRC as possible anchor variables) and distribution-based (half standard deviation and 1.96 standard error of measurement) approaches. Changes in the five variables were compared in patients with and without changes in QMVC or PImax >MCID for each variable. Results: Sixty-nine COPD patients (age 75±6 years) were analysed. QMVC improved by 2.4 (95%CI 1.1-3.7) kgf, PImax by 5.8 (2.7-8.8) cmH2O, 6MWD by 21 (11-32) meters and CRQ by 3.9 (1.6-6.3) points. The MCID of QMVC and PImax was 3.3-7.5 kgf and 17.2-17.6 cmH2O, respectively. The MCID of QMVC (3.3 kgf) could differentiate individuals with significant improvement in 6MWD and PImax from those without. Conclusion: The MCID of QMVC (3.3 kgf) can identify a meaningful change in quadriceps muscle strength after a PRP. The MCID of PImax (17.2 cmH2O) should be used with careful consideration, because the value is estimated using distributionbased method. 相似文献
44.
Suzuki M Kino K Morikawa M Kobayashi T Komori R Miyazawa H 《Molecules (Basel, Switzerland)》2012,17(6):6705-6715
DNA is constantly exposed to endogenous and exogenous oxidative stresses. Damaged DNA can cause mutations, which may increase the risk of developing cancer and other diseases. G:C-C:G transversions are caused by various oxidative stresses. 2,2,4-Triamino-5(2H)-oxazolone (Oz), guanidinohydantoin (Gh)/iminoallantoin (Ia) and spiro-imino-dihydantoin (Sp) are known products of oxidative guanine damage. These damaged bases can base pair with guanine and cause G:C-C:G transversions. In this study, the stabilization energies of these bases paired with guanine were calculated in vacuo and in water. The calculated stabilization energies of the Ia:G base pairs were similar to that of the native C:G base pair, and both bases pairs have three hydrogen bonds. By contrast, the calculated stabilization energies of Gh:G, which form two hydrogen bonds, were lower than the Ia:G base pairs, suggesting that the stabilization energy depends on the number of hydrogen bonds. In addition, the Sp:G base pairs were less stable than the Ia:G base pairs. Furthermore, calculations showed that the Oz:G base pairs were less stable than the Ia:G, Gh:G and Sp:G base pairs, even though experimental results showed that incorporation of guanine opposite Oz is more efficient than that opposite Gh/Ia and Sp. 相似文献
45.
Katsufumi Tanaka Takanobu Hira Ryuichi Fukui Nozomi Nakagawa Ryuichi Akiyama Masami Nakano Keisuke Yoshida Teppei Tsujita 《Colloid and polymer science》2011,289(7):855-862
An attempt has been made to develop a candidate for electro-rheological (ER) nano-suspensions based on anatase titanium dioxide
with a particle diameter around 300 nm. The micro-gap flow behavior and microstructure were evaluated for a suspension with
a particle volume fraction of 8.8 vol.%. The ER effect was investigated for the nano-suspension. The effect of shearing time
on the ER responses was also investigated. The ER effect was discussed in comparison to the effect previously reported for
the nano-suspension based on rutile titanium dioxide with a particle diameter around 15 nm. 相似文献
46.
Takanobu Kawamura Kenji Urayama Shinzo Kohjiya 《Journal of Polymer Science.Polymer Physics》2002,40(24):2780-2790
Strain‐energy density functions (W) of end‐linked polydimethylsiloxane (PDMS) networks with different entanglement densities were estimated as a function of the first and second invariants I1 and I2 of Green's deformation tensor on the basis of the quasi‐equilibrium biaxial stress‐strain data. Entanglement densities in the PDMS networks were controlled by varying the precursor PDMS concentration (?0) in end‐linking. The deduced functional form of W [W = C10(I1 ? 3) + C01(I2 ? 3) + C11(I1 ? 3)(I2 ? 3) + C20(I1 ? 3)2 + C02(I2 ? 3)2] is independent of the degree of dilution at network preparation. The contribution of each term in I1 and I2 to total energy depends on whether the precursor PDMS solution before end‐linking belongs to the concentrated regime ?0 > ?c where many entanglement couplings of precursor chains exist or the moderately concentrated regime ?0 < ?c where pronounced entanglement couplings of precursor chains are absent. These results suggest that the rubber elasticity of the end‐linked networks is significantly influenced by the entangled state of precursor chains before end‐linking, and the extra terms in the estimated W that are absent in the prediction of the classical rubber elasticity theories [W = C (I1 ? 3)] mainly originate from the effect of trapped entanglements. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2780–2790, 2002 相似文献
47.
48.
Masao Fukushima Mounir Haddou Hien Van Nguyen Jean-Jacques Strodiot Takanobu Sugimoto Eiki Yamakawa 《Computational Optimization and Applications》1996,5(1):5-37
In this paper, we propose a parallel decomposition algorithm for solving a class of convex optimization problems, which is broad enough to contain ordinary convex programming problems with a strongly convex objective function. The algorithm is a variant of the trust region method applied to the Fenchel dual of the given problem. We prove global convergence of the algorithm and report some computational experience with the proposed algorithm on the Connection Machine Model CM-5. 相似文献
49.
50.
Numerical simulations of flame propagation and DDT in obstructed channels filled with hydrogen–air mixture 总被引:2,自引:0,他引:2
Vadim N. Gamezo Takanobu Ogawa Elaine S. Oran 《Proceedings of the Combustion Institute》2007,31(2):2463-2471
We study flame acceleration and deflagration-to-detonation transition (DDT) in channels with obstacles using 2D and 3D reactive Navier–Stokes numerical simulations. The energy release rate for the stoichiometric H2–air mixture is modeled by a one-step Arrhenius kinetics. Computations show that at initial stages, the flame and flow acceleration is caused by thermal expansion of hot combustion products. At later stages, shock–flame interactions, Rayleigh–Taylor, Richtmyer–Meshkov, and Kelvin–Helmholtz instabilities, and flame–vortex interactions in obstacle wakes become responsible for the increase of the flame surface area, the energy-release rate, and, eventually, the shock strength. Computations performed for different channel widths d with the distance between obstacles d and the constant blockage ratio 0.5 reproduce the main regimes observed in experiments: choking flames, quasi-detonations, and detonations. For quasi-detonations, both the initial DDT and succeeding detonation reignitions occur when the Mach stem, created by the reflection of the leading shock from the bottom wall, collides with an obstacle. As the size of the system increases, the time to DDT and the distance to DDT increase linearly with d2. We also observe an intermediate regime of fast flame propagation in which local detonations periodically appear behind the leading shock, but do not reach it. 相似文献