燃煤过程痕量元素动力学机理的研究进展

由于痕量元素在煤中的含量低微、检测困难,加之其原子量一般较大,可能的反应途径多,使得相关的反应机理研究难度极大。本文结合作者的研究成果,介绍了煤燃烧过程中痕量元素化学反应动力学的国内外研究进展,包括痕量元素化学动力学机理的建立;相关的典型实验、计算模拟及其实验验证、动力学机理模型的简化;痕量元素反应动力学机理的完善和发展,包括采用简单碰撞理论、活化络合物理论(亦称过渡态理论,或绝对反应速率理论)对痕量元素化学反应动力学机理的修正;最后指出煤燃烧过程中痕量元素动力学研究的若干方向是: (1)痕量元素反应动力学模型数据库的建立;(2)煤燃烧过程中,主量元素和次量元素的动力学机理的完善; (3)各痕量元素之间动力学研究的开展; (4)实际燃烧过程中痕量元素动力学行为的研究。     

The negative gradient flow for the <Emphasis Type="Italic">L</Emphasis><Superscript>2</Superscript>-integral of Ricci curvature

 In this paper, the negative gradient flow for the L ²-integral of Ricci curvature on a 3-manifold is considered. It is not known whether the solution to this fourth order geometric evolution equation exists, and whether it will develop singularities in finite time. Based on the trick of De Turck and the idea of Hamilton on the flow of Ricci curvature, the local existence on any compact Riemannian manifold is obtained. In addition, the conditions for the occurences of singularities in finite time during the evolution and the asymptotic behavior of the flow on a 3-manifold are discussed. Received: 22 April 2002 / Revised version: 5 January 2003 Published online: 24 April 2003 This work is partially supported by the Foundations of NNSF of China, the Foundation for University Key Teacher by MEC and Shanghai Priority Academic Discipline.     

Dynamics of energy release in a low-voltage pulsed arc in air

The influence of the discharge conditions on the dynamics of energy release is considered for pulsed arcs in air at initial pressures from 10⁵ to 8×10⁵ Pa and a low-voltage capacitor voltage of up to 400 V. A novel method for determining the resistance of the discharge channel in the final stage of a spark discharge is proposed. The method is applied to estimating the discharge channel parameters.     

Holographic screen to project a 3D image by the method of point-focused aspects

A holographic screen that makes it possible to display 3D images by the method of point-focused aspects (of a scene to be displayed) or by projecting narrow line holograms is suggested and implemented. The image thus formed reconstructs only horizontal parallax, which allows one to cut the body of information necessary for 3D imaging. Projection through the screen and a way of recording the screen are considered.     

Photo-induced effect in the layered perovskite manganite La<Subscript>1.2</Subscript>Sr<Subscript>1.8</Subscript>Mn<Subscript>1.8</Subscript>Co<Subscript>0.2</Subscript>O<Subscript>7</Subscript>

It is helpful to study the photo-induced effect in the perovskite manganites not only for elucidating the mechanism of colossal magnetoresistance (CMR) effect but also for potential applications in technology. The laser-induced effect in the Co doping layered perovskite manganites La_1.2Sr_1.8Mn_1.8Co_0.2O₇, is studied in this paper and the obtained results are also compared with that gained in the Nd-doping manganites with cubic perovskite structure.     

Magnetic field penetration into half-space for type-II superconductors of the second kind

Equations that simulate the magnetic induction and current density distributions in half-space in view of the power I-V characteristic are derived. The magnetization front velocity is determined for a given mean rate of external magnetic field variation at the boundary of the sample. An integral condition for the electrical resistance (nonlinearly depending on the magnetic field) under which the magnetic flux penetrates into the sample with a finite rate is found. An analytical solution that simulates the power variation of the magnetic field at the boundary is given. The Bean generalized model describing the current density distribution near the critical current is considered. It is shown that solutions like shock waves may arise beyond the applicability domain of the Bean model.     

Search for the emission of π<Superscript>0</Superscript> mesons from the neutron-induced fission of <Superscript>235</Superscript>U nuclei

A nuclear-reactor experiment on the search for the emission of neutral pions from the neutron-induced fission of ²³⁵U nuclei has been carried out. To this end, an experimental setup for searching for the emission of π⁰ mesons with high sensitivity to this process has been designed and produced. This setup consisted of two Cherenkov total-absorption spectrometers for the detection and measurements of the energy of two gamma-ray photons from π ⁰-meson decay. The spectrometers were placed at the exits of two coaxial horizontal experimental channels. To protect the detectors from low-energy β and γ rays and neutron fluxes, 3.5-m-long water filters were situated in the channels. To reject the cosmic background, large-area scintillation counters operating in the anticoincidence mode were placed over each spectrometer. The energy and time resolution of the spectrometers, as well as the efficiency of detecting charged particles by scintillation counters, were tested on the secondary electron beam of the Tomsk electron synchrotron Sirius. Runs of measurements of the effect on the operating reactor (duration of 805 h) were alternated with runs of measurements of background on the stopped reactor (duration of 403 h). Statistical processing of the experimental results yields an upper limit of ≤5.3×10 ^?12 with a 90% confidence level for the probability of the emission of neutral pions from the neutron-induced fission of ²³⁵U nuclei. This result and results of other works carried out with sources of spontaneously fissioning ²⁵²Cf nuclei show that the probabilities of the emission of π⁰ mesons from spontaneous fission and fission induced by fission-spectrum neutrons are equal to each other.     

直流电弧等离子体炬的特性研究

介绍了局部热力学平衡下描述直流电弧等离子体炬的磁流体力学模型，采用数值模拟方法研 究了等离子体炬内等离子体的传热和流动特性、湍流对等离子体炬内等离子体特性的影响， 以及等离子体炬运行参数对等离子体特性的影响.将数值模拟结果与已有的实验结果进行了 比较. 关键词： 等离子体炬 磁流体力学 数值模拟