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101.
Alexander Raith Philipp Altmann Mirza Cokoja Wolfgang A. Herrmann Fritz E. Kühn 《Coordination chemistry reviews》2010,254(5-6):608-634
An overview of η5,η1-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a η1-bridging σ-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described. 相似文献
102.
Schröter MK Khodeir L van den Berg MW Hikov T Cokoja M Miao S Grünert W Muhler M Fischer RA 《Chemical communications (Cambridge, England)》2006,(23):2498-2500
Free-standing, ZnO surface decorated Cu nanoparticles of 1-3 nm size were obtained by sequential co-pyrolysis of [Cu(OCHMeCH2NMe2)2] and ZnEt2 in squalane in the absence of additional surfactants and proved to be highly active quasi homogeneous catalysts for methanol synthesis from CO and H2. 相似文献
103.
H. Yücel A. N. Solmaz E. Köse D. Bor 《Journal of Radioanalytical and Nuclear Chemistry》2010,283(2):305-312
In this paper, a semi-empirical method is proposed to determine true coincidence-summing (TCS) correction factors for high
resolution γ-ray spectrometry. It needs the knowledge of both full energy peak (FEP) efficiency and total-to-peak (TTP) efficiency
curves. The TTP efficiency curve is established from the measurements with a set of coincidence-free point sources. Whereas
for a volume source, the coincidence-free FEP efficiency curve is obtained iteratively by using the peaks from almost the
coincidence-free nuclides and those from the coincident nuclides in the mixed standard sources. Then the fitting parameters
obtained for both TTP and FEP efficiency curves are combined in a freely-available TCS calculation program called TrueCoinc, which yields the TCS correction factors required for any nuclide. As an application, the TCS correction factors were determined
for the particular peaks of 238U, 226Ra and 232Th in the reference materials, measured in the case of a close-in detection geometry using a well-type Ge detector. The present
TCS correction method can be applied without difficulty to all Ge detectors for any coincident nuclide. 相似文献
104.
Nadira Ibri?imovi? Mirza Ibri?imovi? Margit Barth Ulrich Bohrn 《Monatshefte für Chemie / Chemical Monthly》2010,205(2):125-130
Abstract
Spoilage of products can mainly be attributed to microorganisms which “live on the product”, i.e. which are able to utilize and/or metabolize components and/or molecules of the product. The objective of this work was to develop and optimize sensor prototypes indicating the quality of a product “in real time”, i.e. at the time the consumer is looking at the product. The design of the presented sensors relates to optical phenomena, for example anomalous absorption and remission of light. The crucial point of the sensor prototypes is a layer sensitive to the analyte, a polymer degradable by enzymes produced by the respective microorganisms. After incubation of the sensor setup with contaminated products, the lytic enzymes released from decaying cell material change the thickness of the polymer layer and generate a colour change visible by the naked eye. Production of the sensor prototypes is very simple and inexpensive and they might be successfully integrated into product packaging. 相似文献105.
106.
Co‐administration of HMG‐CoA reductase with antidiabetic drugs is most common since antidiabetic drugs are mostly prescribed for long term therapy. In the present paper, we describe the simultaneous determination of antidiabetic (pioglitazone hydrochloride and gliquidone) in presence of statins (rosvastatin and simvastatin) in formulations and in human serum using RP‐HPLC technique. The serum samples were subjected to protein precipitation with acetonitrile prior to an HPLC analysis. At a flow rate of 1 mL·min−1 isocratic elution was employed, using mobile phase consisting of methanol/water (90:10, V:V), pH 3.50 with phosphoric acid and absorbance was recorded at 235 nm. The assay was reproducible, linear (concentration range of 5–50 μg·mL−1) and accurate. The LOD and LOQ values were 1.32, 0.28, 0.05 and 0.57 μg·mL−1 and 4.39, 0.93, 0.16 and 1.90 μg·mL−1 for pioglitazone hydrochloride, gliquidone, rosvastatin and simvastatin, respectively. There were no interfering peaks due to the excipients present in the pharmaceutical tablet and serum. Thus, the proposed method is simple and suitable for the analysis of active ingredient in tablet form and human serum. 相似文献
107.
Babur M. Mirza Adnan Saeed Safeer Sadiq 《International Journal of Theoretical Physics》2009,48(10):2938-2943
We investigate the effects of magnetic field on the background spacetime of a spherically symmetric relativistic star. Using
the general relativistic Maxwell equations coupled to the Einstein field equations for the gravitational field, it is shown
that not only the backreaction of the spacetime modifies the magnetic field of the star, but also the magnetic field of the
star molds the spacetime in its vicinity. The part played by the poloidal as well as the toroidal components of the magnetic
field on the exterior spacetime are investigated. 相似文献
108.
Steinke T Gemel C Cokoja M Winter M Fischer RA 《Dalton transactions (Cambridge, England : 2003)》2005,(1):55-62
The reaction of 6 equivalents of GaCp*(Cp*= pentamethylcyclopentadienyl) with [{Cp*RhCl2}2] yields the complex [Cp*Rh(GaCp*)3(Cl)2] (1) exhibting a cage-like intermetallic RhGa3 center with Ga-Cl-Ga bridges. Treatment of this complex with GaCl3 gives the Lewis acid-base adduct [Cp*Rh(GaCp*)2(GaCl3)]. (2) Reaction of [{Cp*RhCl2}2] with understoichiometric amounts of E(I)Cp*(E = Al, Ga, In) leads to a variety of products strongly dependent on the molecular ratio of the reactants. Thus, the reduction of [{Cp*RhCl2}2] with one equivalent of E(I)Cp*(E = Al, Ga, In) gives the RhII dimer [{Cp*RhCl}2]. The insertion of 3 equivalents of InCp* into the Rh-Cl bonds of [{Cp*RhCl2}2] yields the salt [Cp*2Rh]+[Cp*Rh(InCp*){In2Cl4(mu2-Cp*)}]- (3), the anion exhibiting an intermetallic RhIn(3) center with an intramolecularly bridging Cp* ring. The reaction of [{Cp*RhCl}2] with Cp*Ga yields various insertion products. In trace amount the "all hydrocarbon" cluster complex [(RhCp*)2(GaCp*)3] (6) is obtained. The corresponding ethylene containing cluster complex [{RhCp(GaCp*)(C2H4)}2] (7) can be prepared by treatment of [RhCp*(CH3CN)(C2H4)] with GaCp*. 相似文献
109.
Claisen rearrangement of allyl phenyl ether and its sulfur and selenium analogues on electron impact
Prabhakar S Mirza SP Kundu A Roy S Vairamani M 《Rapid communications in mass spectrometry : RCM》2000,14(13):1116-1122
The electron impact (EI) mass spectrum of allyl phenyl ether (1) includes an ion at m/z 106 that is formed mainly by the loss of CO from the molecular ion, as supported by high resolution and MS/MS data. The formation of the [M - CO](+) ion from 1 can be explained in terms of the Claisen rearrangement of 1 after ionization in the ion source of the mass spectrometer. Similarly, allyl phenyl sulfide (2) and allyl phenyl selenide (3) showed characteristic ions corresponding to [M - CH(3)](+), [M - XH](+) (X = S or Se) and [M - C(2)H(4)](+.), and the formation of these ions are explained via Claisen rearrangement of 2 and 3 in the ion source of the mass spectrometer resulting in a mixture of rearrangement products. The formation of molecular ions of 2-allyl thiophenol and 2-allyl selenophenol as intermediates, that cannot be isolated as the neutrals from the solution phase Claisen rearrangement of 2 and 3, respectively, is clearly indicated in the gas phase. The mass spectra of the rearrangement products obtained from the solution phase reaction were also consistent with the proposal of formation of these products in the ion source of the mass spectrometer. The formation of characteristic fragment ions attributed to the Claisen rearrangement products are also evident in the collision induced dissociation spectra of the corresponding molecular ions. Copyright 2000 John Wiley & Sons, Ltd. 相似文献
110.
B. Mirza M. Zamani-Nasab 《理论物理通讯》2006,46(12)
In order to study the effect of large scale cosmological expansion on small systems, we assume a FriedmannRobertson-Walker type coordinate system in presence of a nonzero cosmological constant and derive a non-static Reissner-Nrdstr(o)m metric. It is an analytic function of r for all values except at r = 0, which is singular. By determining the equation of motion in this metric we can estimate how expansion of the universe may affect Pioneer‘smotion. Because the metric does not have any event horizon and so high potential regions are accessible, this may help us in better understanding AGN phenomenon. 相似文献