丙烯酰胺-丙烯酸钠共聚物的键结构和光散射研究

用溶液聚合方法制备了一组单体含量相同、分子量不同的丙烯酰胺-丙烯酸钠(AM-AA)共聚物样品,用¹³CNMR和常规光散射方法进行了表征。该组样品的化学组成是均一的(AA摩尔含量16.9±1.1%),AA单体在大分子链中的序列分布为孤立、无规的,聚电解质在盐水体系中的光散射理论适用于共聚物在0.12mol/LNaCl水溶液体系。用恒化学位下的折光指数增量代替恒盐组成的折光指数增量,可从一次常规光散射实验分别求得共聚物样品的真实、第二维利系数A₂和均方旋转半径〈R²〉_z,其关系为:A₂=0.0619M_w^-0.21,〈R²〉_z^1/2=0.0210M_w^0.54.     

几种无定型聚芳醚砜(酮)的成环解聚及产物的开环聚合

几种线性高分子量的无定型聚芳醚砜(酮)在非质子极性溶剂二甲基乙酰胺(DMAc)和二甲基甲酰胺(DMF)中,以氟化铯(CsF)为催化剂进行解聚成环,所得环状低聚物由凝胶渗透色谱(GPC)、高效液相色谱(HPLC)和激光质谱(MALDI-TOF-MS)确认,其中酚酞聚醚砜(PES-C)和酚酞聚醚酮(PEK-C)的解聚成环率分别高达86．3％和87．9％．讨论了影响成环率的各种因素．环状产物又在阴离子引发剂联苯双酚钾的作用下进行开环聚合重新得到高分子量的线性产物．     

Assembly of (l+d)-Tryptophan Derivatives Containing an Imidazole Group Selectively Forms a Rare Purple Ni2+-Hydrogel

Design of metal-selective hydrogels is attractive due to potential applications in materials and biological sciences. Although much progress has been made, assembly of both l - and d -amino acid derivatives was less explored for design of metallohydrogels. In this study, we synthesized a facile and small tryptophan derivative containing an imidazole ligand with both l - and d - configurations (denoted as l/d -ImW). Intriguingly, the assembly of (l+d) -ImW gelators was found to selectively form a Ni²⁺-hydrogel in aqueous medium at room temperature, which shows a rare purple color and exhibits excellent multi-responsiveness. In addition to insights into the gelation mechanism, this study provides a novel approach to the design of metallohydrogels, by the assembly of (l+d) -amino acid derivatives containing both aromatic rings and multiple metal coordination sites.     

讲台与实验台互跨式研究生双语教学模式探索与实践

研究生双语教学是研究生教育国际化进程的必然要求。针对目前研究生双语教学中存在的问题,本文提出了一种新的研究生双语教学模式,即讲台与实验台互跨式研究生双语教学。以生物无机化学研究生双语课程为例,我们探索了讲台与实验台互跨式双语教学的实施方法。实践表明,讲台与实验台互跨式研究生双语教学模式解决了研究生培养中理论与实践相脱节的问题,不但可以全面提高研究生科研素质,而且可以提升教师科研水平。     

Ionic liquid functionalized polymer composite nanotubes toward dye decomposition

Poly(ionic liquid) functionalized composite nanotubes are achieved by ATRP grafting ionic liquid monomers for example Vi Et Im+Bràfrom the poly(DVB-co-VBC) nanotubes surface. PW12O403àanion is introduced through anion exchange. The PW12O403àbased composite nanotubes can synchronously absorb and decompose water soluble dyes for example methyl orange(MO). The cooperative interplay is promising in highly efficient decomposition of dyes.     

同时测量扭转角度和扭转方向的侧漏光子晶体光纤扭转传感器

基于所研制的侧漏型光子晶体光纤,提出并构建了出一种同时检测扭转角度 和扭转方向的高灵敏度Sagnac干涉仪型光纤扭转传感器.顺时针扭转时, 传感器传输谱向短波长方向偏移;逆时针扭转,向长波长方向偏移. 对传感器扭转特性的实验研究结果表明,构成Sagnac干涉仪的侧漏型光子晶体光纤的长度, 对扭转敏感系数和扭转角度测量范围起着决定性作用.当光纤长度较短时, 扭转传感器具有较大的扭转灵敏度,但扭转角度测量范围较小;光纤长度增加时,扭转灵敏度减小, 扭转角度测量范围增大.当构成Sagnac干涉仪的侧漏型光子晶体光纤长度为14.85 cm时, 传感器的扭转敏感系数可达到0.9354 nm/(°),扭转角度测量范围为-90°—90°; 光纤长度为32 cm时,最大扭转敏感系数降为0.2132 nm/(°), 扭转角度测量范围扩展至-180°—180°. 采用二维测量矩阵法可以有效排除温度对扭转角度的测量的影响. 关键词： 光纤传感器 侧漏型光子晶体光纤 扭转传感器 Sagnac干涉仪     

High-Flexible Single-Polarization Single-Mode Photonic-Crystal Fibre

We propose a new type of high flexible single-polarization single-mode (SPSM) photonic crystal fibre (PCF). Numerical analysis indicates that the SPSM PCF proposed guides only one polarization mode over a wavelength band broader than the conventional SPSM fibres. The position and the bandwidth of the single polarization mode region depend flexibly on the structure parameters such as the hole diameters d₁ and d₂ and the hole pitch Λ of the SPSM PCFs. A 200-nm SPSM region can be obtained for the SPSM PCF with Λ=2.55μm, d₁/Λ=0.3 and d₂/Λ=0.833 and the modal birefringence at the wavelength 1.31μm can reach 1.8×10^-3.     

二甲基亚砜防冻机理的拉曼光谱分析

采用拉曼光谱对不同体积比的二甲基亚砜(DMSO)水溶液进行测量, 并利用Origin 7.5对水的光谱带进行分峰, 求得拉曼光谱峰面积比值. 应用混合模型对实验结果进行了分析, 分析结果表明, 防冻剂二甲基亚砜与水混合时, 其SO基团与水分子的OH基团形成氢键(SO…H—O), 有效地阻止了四面体结构冰的生成, 并证实了二甲基亚砜与水的体积比为1∶1时, 防冻效果最佳.     

Submicron Ion-Exchange Fibers of Polystyrene and Styrene-Butadiene-Styrene Copolymer Blends

In the present study, submicron ion-exchange fibers (IEFs) of polystyrene (PS) and its blends with styrene-butadiene-styrene block copolymer (SBS) were prepared by electrospinning and postsulfonating modification. Scanning electron microscopy (SEM) images showed that the diameters of the fibers enlarged significantly after treatment and the surfaces become rougher. Mechanical properties analysis showed that the electrospun fibers (EF) and the IEFs from PS/SBS blend fabrics possessed better mechanical performances than those from pure PS. The ion-exchange capacity (IEC) of 4.35 mmol/g and and copper ions (Cu²⁺) adsorption value of 3.08 mmol/g for IEFs from PS/SBS blends were both higher than that of IEFs from pure PS and the conventional IEFs produced by coating or grafting fibrous substrates with functionalized resins or monomers. Dynamic adsorption experiments were made to test the behavior of adsorption for Cu²⁺. The results of dynamic adsorption experiments with Cu²⁺ showed that the IEFs from PS/SBS would quickly purify 3000 ml waste water containing Cu²⁺ (100 mg/L), and the removal rate for Cu²⁺ reached 96.5% even at the flow rate of 12 ml/min. The study provided an absorbent with a high dynamic adsorption capacity for removing Cu²⁺ from waste water.     

Difference in effect of temperature on absorption and Raman spectra between all-trans-β-carotene and all-trans-retinol

<正>Temperature dependencies(81℃-18℃) of visible absorption and Raman spectra of all-trans-β-carotene and all-trans-retinol extremely diluted in dimethyl sulfoxide are investigated in order to clarify temperature effects on different polyenes.Their absorption spectra are identified to be redshifted with temperature decreasing.Moreover, all-trans-β-carotene is more sensitive to temperature due to the presence of a longer length of conjugated system.The characteristic energy responsible for the conformational changes in all-trans-β-carotene is smaller than that in all-transretinol. Both of the Raman scattering cross sections increase with temperature decreasing.The results are explained with electron-phonon coupling theory and coherent weakly damped electron-lattice vibrations model.