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31.
32.
GUY BOUCHITTÉ IRENE FONSECA GIOVANNI LEONI LUÍSA MASCARENHAS 《Archive for Rational Mechanics and Analysis》2002,165(3):187-242
An integral representation formula for a class of functionals defined on and in (the space of special functions of bounded variation) is obtained without requiring the regularity conditions usually imposed
in the literature. The approach is based on the general results of [10] and on a Poincaré-Wirtinger type inequality introduced
by DE GIORGI, CARRIERO & LEACI [25]. Applications to relaxation problems and dimension-reduction problems in brittle thin
films are presented.
(Accepted May 8, 2002) Published online October 18, 2002
Communicated by L. Ambrosio 相似文献
33.
用酶促聚合和原子转移自由基聚合相结合的"一锅法"合成了聚甲基丙烯酸正丁酯嵌段聚10-羟基癸酸[PBMA-b-P(10-HD)],通过核磁共振(1H NMR)、傅里叶红外光谱(FTIR)和凝胶渗透色谱(GPC)对其结构以及分子量与其分子量分布进行了表征,并通过动态光散射仪(DLS)和原子力显微镜(AFM)对聚合物在水溶液中的性质进行了研究.所得嵌段聚合物纳米粒子呈球形结构,平均直径为135 nm左右. 相似文献
34.
Rare earth element substituted bismuth ferrites (BiFeO3) are of enormous importance as magnetoelectric materials. The polycrystalline samples of Bi
x
La1−x
FeO3 (x=0, 0.2, 0.4, 0.6, 0.8) were prepared by solid-state reaction using standard ceramic method. The single-phase formation of
these compounds was confirmed by X-ray diffraction (XRD) studies. The samples with x=0, 0.2, 0.4, 0.6 are found to be orthorhombic while the sample with x=0.8 is triclinic. The dielectric constant (ε′) and dissipation factor (tan δ) were measured in the frequency range 100 Hz
to 1 MHz at room temperature and as a function of temperature at certain fixed frequencies (1 kHz, 10 kHz, 100 kHz, 1 MHz).
All the samples showed dielectric dispersion. The dielectric constant with temperature shows a broad peak; the peak temperature
shifts with frequency which reflects the relaxor-type behavior. The peak above 600 K in the measured temperature range corresponds
to antiferromagnetic ordering temperature (Néel temperature). The broadness of the peak changes with composition. The ac conductivity
as well as ε′ are found to be maximum for the sample x=0.2 at room temperature. 相似文献
35.
CoFe2O4-BaTiO3 composites were prepared using conventional ceramic double sintering process with various compositions. Presence of two phases
in the composites was confirmed using X-ray diffraction. The dc resistivity and thermoemf as a function of temperature in
the temperature range 300 K to 600 K were measured. Variation of dielectric constant (ɛ′) with frequency in the range 100 Hz to 1 MHz and also with temperature at a fixed frequency of 1 kHz was studied. The ac
conductivity was derived from dielectric constant (ɛ′) and loss tangent (tan δ). The nature of conduction is discussed on the basis of small polaron hopping model. The static value of magnetoelectric
conversion factor has been studied as a function of magnetic field. 相似文献
36.
Building upon our earlier results on the chemistry of nido-1,2-[(Cp*RuH)2B3H7] (Cp*=ɳ5-C5Me5) (nido- 1 ) with different transition metal carbonyls, we continued to investigate the reactivity with group 7 metal carbonyls under photolytic condition. Photolysis of nido- 1 with [Mn2(CO)10] led to the isolation of a trimetallic [(Cp*Ru)2{Mn(CO)3}(μ-H)(μ-CO)3(μ3-BH)] ( 2 ) cluster with a triply bridging borylene moiety. Cluster 2 is a rare example of a tetrahedral cluster having hydrido(hydroborylene) moiety. In an attempt to synthesize the Re analogue of 2 , a similar reaction was carried out with [Re2(CO)10] that yielded the trimetallic [(Cp*Ru)2{Re(CO)3}(μ-H)(μ-CO)3(μ3-BH)] ( 3 ) cluster having a triply bridging borylene unit. Along with 3 , a trimetallic square pyramid cluster [(Cp*Ru)2{Re(CO)3}(μ-H)2(μ-CO)(μ3,ɳ2-B2H5)] ( 4 ), and heterotrimetallic hydride clusters [{Cp*Ru(CO)2}-{Re(CO)4}2(μ-H)] ( 5 ) and [{Cp*Ru(CO)}{Re(CO)4}2(μ-H)3] ( 6 ) were isolated. Cluster 4 is a unique example of a M2M′B2 cluster having diboron capped Ru2Re-triangle. The hydride clusters 5 and 6 have triangular RuRe2 frameworks with one and three μ-Hs respectively. All the clusters have been characterized by using mass spectrometry, 1H, 11B{1H}, 13C{1H} NMR and IR spectroscopies analyses and the structures of clusters 2 – 6 have been unambiguously established by XRD analyses. Furthermore, to understand the electronic, structural, and bonding features of the synthesized metal-rich clusters, DFT calculations have been performed. 相似文献
37.
利用全量子理论的方法,研究了存在相位退相干时多光子T-C模型中两个二能级原子与二项式光场相互作用系统中两原子的布居数反转。讨论了相位退相干系数、二项式光场系数、最大光子数、跃迁光子数对原子布居数反转的影响。结果表明:相位退相干减少了原子布居数反转的振幅、破坏了原子的量子特性。改变跃迁光子数,可以改变原子间布居数反转演化周期及演化强度。当二项式光场的最大光子数增大时,原子布居差的崩塌-回复现象就会逐渐消失。相位退相干因子不变时, 二项式光场从相干态过渡到数态过程中,原子布居的振荡频率由大变小,周期性的崩塌与回复现象逐渐消失。 相似文献
38.
We investigate the thermoelectric properties of GaN with p-and n-type doping by the first principles calculation and the semi-classical Boltzmann theory. We find that the power factors (S2σof p-type GaN (-3500 W/mK2) is about twice that of the n-type (-1750 W/mK2), which indicates the thermoelectric properties of p-type GaN would be better. Thermal conductivity of GaN crystal decreases rapidly as the temperature increases, but it is still too large for thermoelectric applications. The figure of merit (ZT) estimated at 1500 K is 0.134 for p-type GaN crystal and 0.062 for the n-type. 相似文献
39.
Yu-Ming ZHENG Hong-Min LIU Ben-Hao SA Zhong-Dao LU Zhong-Qi WANG Xiao-Ze ZHANG 《理论物理通讯》1993,19(1):71-74
A simple Monte Carlo simulation and even a partition method can be used to reproduce quite well the power law behavior between the factorial moment and the charge interval of fragment charge distributions from the multifragmentation of 197Au nucleus bombarding emulsion at~1 GeV/nucleon. This indicates that the above power law seems not to be a unique precursor of the intermittent behavior in nuclear multifragmentations. 相似文献
40.
The charge dispersion of fragments in high energy p+Cu,Kr and Xe reactions are calculated by statistical model and Monte Carlo technique.The corresponding data are reproduced quite well.It is shown that the charge dispersions are all nearly gaussian.The mass dependence of the most probable fragment charge reflects the rest target memory effect. 相似文献