全文获取类型
收费全文 | 124篇 |
免费 | 2篇 |
专业分类
化学 | 76篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 20篇 |
物理学 | 26篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 6篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 8篇 |
2015年 | 2篇 |
2014年 | 5篇 |
2013年 | 16篇 |
2012年 | 9篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 9篇 |
2008年 | 4篇 |
2007年 | 3篇 |
2006年 | 7篇 |
2005年 | 6篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1994年 | 1篇 |
1990年 | 1篇 |
排序方式: 共有126条查询结果,搜索用时 15 毫秒
31.
Hikmet Aĝirbaş Selahattin Güner 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):257-263
Abstract 4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2.3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yielded 4-substituted-2.3-1 H-benzthiazine-1-ones. 相似文献
32.
33.
Serbetçi T Demirci B Güzel CB Kültür S Ergüven M Başer KH 《Natural product communications》2010,5(9):1369-1374
The chemical compositions of the water-distilled essential oil of Stachys cretica ssp. lesbiaca Rech. fil. and S. cretica ssp. trapezuntica Rech. fil. were determined by GC and GC-MS. Altogether 63 compounds were identified. The sesquiterpene hydrocarbon, germacrene D (20.3% and 12.9% respectively) was the main component identified in both oils. Furthermore, ethanol, light petroleum, dichloromethane, ethyl acetate and n-butanol extracts prepared from the aerial parts of the plants were tested for their antimicrobial activities against six bacterial strains and the yeast Candida albicans. The extracts exhibited no antibacterial activity, but the light petroleum and n-butanolic fractions showed low antifungal activities. Crude ethanolic extracts of the two subspecies were tested for their ability to inhibit the growth of HL-60 and Ishikawa human tumor cell lines. The IC50 values were 100 microg/mL for the HL-60 cell line and 200 microg/mL for the Ishikawa cell line. 相似文献
34.
New vic-dioxime ligands and their CuII, CoIII, NiII and VOIV complexes have been prepared and characterized by elemental analyses, i.r. and u.v. spectra, magnetic moments and molar conductance data. The CoIII complexes are diamagnetic. The 1H- and 13C-n.m.r. and g.c./m.s. spectra of the vic-dioxime ligands and their CoIII complexes were recorded. The compounds are all non-electrolytes. 相似文献
35.
Tümer Mehmet Köksal Hüseyin Serin Selahattin Dig¯rak Metin 《Transition Metal Chemistry》1999,24(1):13-17
Mixed-ligand complexes of copper(II) with 1,10-phenanthroline and various Schiff bases have been prepared and characterized by elemental analysis, electronic and i.r. spectra, magnetic moment and molar conductance data. The Schiff base behave as bidentate ligands, and the mixed-ligand copper(II) complexes of the ligands HL1, HL2 and HL4 are binuclear. The conductivity data for all the complexes are consistent with those expected for an electrolyte. Antimicrobial activities of some of the ligands and complexes have been tested against Bacillus megaterium and Candida tropicalis. 1H and 13C n.m.r. spectra have been recorded in order to solve the solution structure of the ligands. Thermal properties of all complexes have been studied by the d.t.a. and t.g.a. techniques. 相似文献
36.
In this paper, firstly we present a connection between determinants of tridiagonal matrices and the Lucas sequence. Secondly, we obtain the complex factorization of Lucas sequence by considering how the Lucas sequence can be connected to Chebyshev polynomials by determinants of a sequence of matrices. 相似文献
37.
Supports of turbomachineries can be designed as base frames, which are constructions of steel-plates. One of the most important design requirements of the turbomachinery system is to avoid of natural frequencies in the operating speed range. Thus, a rotor dynamics analysis (see e.g. [1]), which is usually carried out using transfer matrix methods or finite element methods has to take the dynamic stiffness of the base frame into account. However, there are several problems to identify this complex and frequency dependent parameter, for example the localization of excitation or measurement responses and the difficulty of the support of base frames, e.g jack screws. In this article the support of a test base frames is analyzed by modal analysis experimentally. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
38.
A New and Convenient Synthesis of Amino‐phthalimide (1H‐Isoindole‐1,3(2H)‐dione) Derivatives and Their Photoluminescent Properties
下载免费PDF全文
![点击此处可从《Helvetica chimica acta》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A new and convenient synthesis for amino‐phthalimide (1H‐isoindole‐1,3(2H)‐dione) derivatives has been developed starting from an α,β‐unsaturated ketone. The ketones were reacted with amines to give aromatic amine products. This is the first time that substituted amine groups have been incorporated in aromatic rings. The mechanism of the product formation is rationalized by the 1,2‐addition of amines to ketones. All aromatic compounds exhibited high fluorescence properties at the blue‐green region. 相似文献
39.
B. Altintas C. Parlak C. Bozkurt R. Eryiğit 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,79(3):301-312
Although graphite and hexagonal form of BN (h-BN) are isoelectronic and have very similar lattice structures, it has been
very difficult to
intercalate h-BN while there are hundreds of intercalation compounds
of graphite. We have done a comparative first principles investigation of lithium intercalation of graphite and hexagonal
boron nitride to provide clues for the difficulty of h-BN intercalation. In
particular lattice structure, cohesive energy, formation enthalpy,
charge transfer and electronic structure of both intercalation
compounds are calculated in the density functional theory framework
with local density approximation to the
exchange-correlation energy. The calculated formation enthalpy
of the considered forms of Li intercalated h-BN is found to be positive which rules out h-BN intercalation without externally
supplied energy. Also, the Li(BN)3 form of Li-intercalated
h-BN is found to have a large electronic density of states at the Fermi level and an interlayer state that crosses Fermi level
at the zone center; these properties make it an interesting material to investigate the role of interlayer states in the superconductivity
of alkali intercalated layered structures. The most pronounced change in the charge distribution of the intercalated compounds
is found to be charge transfer from the planar σ states to the π states. 相似文献
40.
Irfan Gustian Sevim Ünügür Çelik Wawang Suratno Ayhan Bozkurt 《Journal of Physics and Chemistry of Solids》2011,72(11):1377-1380
Polymer electrolyte composite membranes based on poly(1-vinyl-1,2,4-triazole) (PVTRI) and nitrilotri(methyl triphosphonic acid) (TPA) were investigated. PVTRI was produced by free radical polymerization of 1-vinyl-1,2,4-triazole. The polymer PVTRI was doped with TPA at various molar ratios x=0.125, x=0.25, and x=0.5. The proton transfer from TPA to the triazole rings was proved with Fourier-transform infrared spectroscopy (FT-IR). Thermogravimetry (TG) analysis showed that the samples are thermally stable up to approximately 250 °C. DSC results illustrated the homogeneity of the materials as well as the softening effect of the dopant. Cyclic voltammetry results illustrated that the electrochemical stability domain of the dopant extends over 1.5 V. The maximum proton conductivity has been measured for PVTRITPA-0.25 as 8.5×10−4 S cm−1 at 150 °C. 相似文献