COPPER-CATALYSED REARRANGEMENT OF 4-SUBSTITUTED-2,3-1H-BENZOXAZINE-1-THIONES |
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Authors: | Hikmet Aĝirbaş Selahattin Güner |
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Institution: | Department of Chemistry , Kocaeli University , 41300, Izmit, Turkey |
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Abstract: | Abstract 4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2.3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yielded 4-substituted-2.3-1 H-benzthiazine-1-ones. |
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Keywords: | 2 3-1H-Benzoxazine-1-one 2 3-1H-benzoxazine-1-thione 2 3-1H-benzthiazine-1-one |
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