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COPPER-CATALYSED REARRANGEMENT OF 4-SUBSTITUTED-2,3-1H-BENZOXAZINE-1-THIONES
Authors:Hikmet Aĝirbaş  Selahattin Güner
Institution:Department of Chemistry , Kocaeli University , 41300, Izmit, Turkey
Abstract:Abstract

4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2.3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yielded 4-substituted-2.3-1 H-benzthiazine-1-ones.
Keywords:2  3-1H-Benzoxazine-1-one  2  3-1H-benzoxazine-1-thione  2  3-1H-benzthiazine-1-one
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