Synthesis and Characterization of Pressure and Temperature Dual‐Responsive Polystyrene Microbeads

A facile approach to the synthesis of pressure and temperature dual‐responsive polystyrene (PS) microbeads with controlled sizes via dispersion polymerization is described. Three different luminophors are selected and directly introduced into the reaction system and thus incorporated into the resultant PS microbeads during polymerization. By manipulating the reaction conditions, including concentrations of the initiator and monomer, polarity of the reaction medium, and injection rate for the monomer, uniform PS microbeads with sizes ranging from 1 to 5 μm are obtained. When a light source centered at 365 nm is used to excite all the luminophors in the PS beads, three distinct and resolvable emission peaks corresponding well with the luminophors are observed. By taking advantage of their sensitive responses to both pressure and temperature, the PS beads can be utilized for quantitative measurements of these two stimulations simultaneously. The PS beads loaded with multiple luminophors have the ability to serve as building blocks for the fabrication of novel sensing and imaging devices and therefore provide a promising strategy for the study of aerodynamics.     

Ex situ FTIR spectroscopy study of LiVPO4F as cathode material for lithium-ion batteries

The LiVPO₄F as cathode material for lithium-ion batteries was synthesized through two steps of solid-state reactions and investigated by ex situ Fourier transform infrared (FTIR) spectroscopy for the initial charge and discharge cycle. The characterization of the effect on the structure of the LiVPO₄F in the process of lithium-ion insertion/extraction at a molecular level by ex situ FTIR spectroscopy is helpful for the mechanism research for lithium-ion insertion/extraction and the improvement of the performance of lithium-ion batteries. In the process of the initial cycle, new bands of VPO₄F appear in the charge and the featured bands of LiVPO₄F reappear in the discharge. In this paper, ex situ FTIR spectra indicates that the structure of the LiVPO₄F in the process of lithium-ion insertion/extraction is almost not affected, which clearly states that the LiVPO₄F possesses stable structure as cathode material. Consequently, the LiVPO₄F might be expected as a potential cathode replacement for commercial lithium-ion batteries.     

一种电流型超导储能脉冲变压器的放电模式

本文针对高温超导电感储能脉冲变压器(HTSPPT)提出了一种振荡放电模式.该模式中HTSPPT的原边绕组电感与电容器组成振荡回路,放电时原边电流通过该振荡回路使电流变化量增加,使得副边绕组感应出更大的电流脉冲.在放电过程中,电容器作为能量转换器件可实现开关的零电压关断,避免了断路开关出现过电压的问题.本文对振荡放电模式的工作原理进行了理论分析,利用一个小型HTSPPT搭建了小型实验系统,成功实现了从电流100A到3.78kA的放大,证明了的该放电模式的可行性.     

Scholte波与含泥沙两相流介质属性关系的分析及仿真验证

基于四种超声悬浮液模型Urick, Urick-Ament, HT, Mcclements分析了Scholte波在两相流体与多孔介质固体界面处的传播特性. 结合各模型的复波数表达式建立含泥沙流体-多孔介质固体界面波特征方程, 分析了Scholte波速与两相流体积含量、粒径等介质属性的关系. 通过仿真实验获得界面波信号, 运用时延估计获得Scholte波速与泥沙含量、粒径的关系, 发现所得的波速与Urick-Ament和HT理论有相对好的一致性. 关键词： Scholte波 两相流体 多孔介质 泥沙含量     

Effect of Cu doping on the magnetic and electrical properties of n=2 Ruddlesden-Popper manganates

A series of polycrystalline Cu-doped n=2 Ruddlesden-Popper manganates La1.2Sr1.8CuzMn（2-x）O7 （x=0, 0.04, 0.13） were synthesized by the solid state reaction method. The effect of Cu doping on the magnetic and transport properties has been studied. It is found that Cu substitution for Mn greatly affects the magnetic and electrical properties of the parent phase La1.2Sr1.8Mn2O7. With the increase of Cu content, the system undergoes a transition from longrange ferromagnetic order to the spin glass state and further to an antiferromagnetic order. A little of Cu dopant can lead to the samples showing semiconductor or insulator behaviour in the whole observed temperature range while the parent phase has a metal-insulator transition. These samples show colossal magnetoresistance at low temperatures and the value of it decreases with increasing Cu content.     

基于Eclipse平台的本体图形编辑器的设计与实现

文章通过对Eclipse平台和GEF框架的介绍,分析了Eclipse平台在图形编辑方面的优越性.结合本体编辑,设计并实现了基于Eclipse平台下的本体编辑器,对编辑器的系统结构做了详细地分析.编辑器由模型、视图、控制以及文件四大部分组成,由于采用基于MVC模式的GEF框架,使得软件结构清晰,明显缩短了软件的开发周期,提高了软件的可维护性和代码的重用性.     

一种测量凹透镜焦距的方法

介绍了一种新的测量凹透镜焦距的方法：复合成象法。该方法通过凹透镜的两次成象过程中透镜位移的测量，再利用贝塞尔公式将凹透镜的焦距值间接测量出来，此方法的测量精度高，相对误差约为１％左右。     

含水玻璃夹层状硅酸盐的合成与XRD表征

120℃时膨润土、高岭土分别用水玻璃固化，固化物晶形仍以蒙脱石、高岭石结构为主，且蒙脱石可包含更多的水玻璃成分，其固化机理为水玻璃加强了这些硅酸盐的层间作用力，讨论了新型夹层物质形成的可能。     

一种新的测定一维同核全相关的NMR技术

提出一种新的基于MDY混合脉冲的可测定一维同核全相关的核磁共振技术.称为一维自旋回波MDY相干转移(lD-SEMDY)实验.结果表明.它具有下列突出优点:一是不用Z-滤波技术就可以得到纯吸收型的一维全相关谱(lD-TOCSY).与同类技术相比,操作简便.可节省测定时间.应用范围较广;二是所测定亚谱中的信号归属通过改变混合时间和延迟时间可以得到确定;三是相干转移非常有效.远程磁化转移信号的灵敏度比较高,对弱偶合的自旋体系也可进行测定.以甙类化合物为例讨论了它在谱峰高度重叠的有机结构测定中的应用.