全文获取类型
收费全文 | 56261篇 |
免费 | 9356篇 |
国内免费 | 6239篇 |
专业分类
化学 | 40008篇 |
晶体学 | 681篇 |
力学 | 3288篇 |
综合类 | 368篇 |
数学 | 6584篇 |
物理学 | 20927篇 |
出版年
2024年 | 54篇 |
2023年 | 1169篇 |
2022年 | 1381篇 |
2021年 | 2022篇 |
2020年 | 2440篇 |
2019年 | 2255篇 |
2018年 | 1900篇 |
2017年 | 1868篇 |
2016年 | 2731篇 |
2015年 | 2743篇 |
2014年 | 3274篇 |
2013年 | 4152篇 |
2012年 | 5187篇 |
2011年 | 5269篇 |
2010年 | 3676篇 |
2009年 | 3440篇 |
2008年 | 3659篇 |
2007年 | 3293篇 |
2006年 | 2948篇 |
2005年 | 2547篇 |
2004年 | 1947篇 |
2003年 | 1529篇 |
2002年 | 1436篇 |
2001年 | 1137篇 |
2000年 | 1012篇 |
1999年 | 1180篇 |
1998年 | 971篇 |
1997年 | 901篇 |
1996年 | 850篇 |
1995年 | 784篇 |
1994年 | 688篇 |
1993年 | 574篇 |
1992年 | 479篇 |
1991年 | 439篇 |
1990年 | 363篇 |
1989年 | 291篇 |
1988年 | 212篇 |
1987年 | 196篇 |
1986年 | 175篇 |
1985年 | 152篇 |
1984年 | 95篇 |
1983年 | 101篇 |
1982年 | 56篇 |
1981年 | 46篇 |
1980年 | 31篇 |
1979年 | 19篇 |
1976年 | 20篇 |
1975年 | 21篇 |
1972年 | 19篇 |
1957年 | 18篇 |
排序方式: 共有10000条查询结果,搜索用时 312 毫秒
71.
72.
Sajeesh Kumar Madhurakkat Perikamana Sang Min Lee Jinkyu Lee Taufiq Ahmad Min Suk Lee Hee Seok Yang Heungsoo Shin 《Macromolecular bioscience》2019,19(4)
Plant derived flavonoids have not been well explored in tissue engineering applications due to difficulties in efficient formulations with biomaterials for controlled presentation. Here, the authors report that surface coating of epigallocatechin gallate (EGCG) on polymeric substrates including poly (L‐lactic acid) (PLLA) nanofibers can be performed via oxidative polymerization of EGCG in the presence of cations, enabling regulation of biological functions of multiple cell types implicated in bone regeneration. EGCG coating on the PLLA nanofiber promotes osteogenic differentiation of adipose‐derived stem cells (ADSCs) and is potent to suppress adipogenesis of ADSCs while significantly reduces osteoclastic maturation of murine macrophages. Moreover, EGCG coating serves as a protective layer for ADSCs against oxidative stress caused by hydrogen peroxide. Finally, the in vivo implantation of EGCG‐coated nanofibers into a mouse calvarial defect model significantly promotes the bone regeneration (61.52 ± 28.10%) as compared to defect (17.48 ± 11.07%). Collectively, the results suggest that EGCG coating is a simple bioinspired surface modification of polymeric biomaterials and importantly can thus serve as a promising interface for tuning activities of multiple cell types associated with bone fracture healing. 相似文献
73.
Jiatian Chen Le Yang Ying Li Qinghua Hou Lanlan Li Peng Jin 《International journal of quantum chemistry》2019,119(16):e25961
Inorganic planar ring-shape molecules with 4n + 2 π electrons are always the focus of experimental synthesis and theoretical research due to their potential aromaticity and stability. In this work, the whole series of five-membered heterocycle monoanions X nY5-n− (X, Y = group 15 elements; n = 1-4) were thoroughly investigated by means of density functional theory calculations. They all have large formation energies and HOMO-LUMO gap energies, suggesting the potential thermodynamic and kinetic stability. Their aromaticities are comparable to that of typical aromatic hydrocarbons. Their thermal stabilities were firmly established by the ab initio molecular dynamics simulations. As most of them are predicted for the first time, their various spectra were simulated for experimental characterization. Furthermore, we demonstrate that these five-membered cyclic anions can be employed as η5-ligand to construct novel all-inorganic metallocenes, which may serve as the building blocks of low-dimensional nanomaterials. 相似文献
74.
Nonlinear Dynamics - Global dynamics of a flexible asymmetrical rotor resting on vibrating supports is investigated. Hamilton’s principle is used to derive the partial differential governing... 相似文献
75.
76.
Two new homosecoiridoids, named loniaceticiridoside (1) and lonimalondialiridoside (2), were isolated from an aqueous extract of the flower buds of Lonicera japonica. Their structures including the absolute configuration were determined by extensive spectroscopic studies, especially by 2D NMR and CD data analysis. A proposed biosynthetic pathway and preliminary investigations of the biological activity of compounds 1 and 2 are also discussed. 相似文献
77.
裂纹前端的断裂过程区是引起岩石非线性断裂及尺寸效应的主要原因。利用数字图像相关技术对砂岩开展了三点弯曲梁实验,获得观测区域高精度的全场位移和应变数据,根据断裂韧带区域水平位移和水平应变的分布特征,结合裂尖岩石颗粒变化的微观分析,提出采用裂纹尖端水平位移波动性和水平应变突变性所得到的波动系数和水平应变突变值,确定断裂过程区形状和临界尺寸的方法。结果表明:砂岩断裂过程区的形状为不规则的狭长带状区域,断裂过程区的临界长度为11~13mm,临界宽度为1.58~2.36mm。断裂过程区区域内形变在趋向裂尖时呈指数增加,但其单位区域内的形变增量呈波动状态。该方法能够更加准确判断岩石断裂过程区的范围,有助于分析岩石的非线性断裂特性。 相似文献
78.
Yu Wang Xin-jing Zhao Rong-Jing Wei Gui-jie Liang Kang Wang Yuan-zhi Tan Ye Yang 《化学物理学报(中文版)》2021,34(5):591-597
The intermolecular interaction determines the photophysical properties of the organic aggregates, which are critical to the performance of organic photovoltaics. Here, excitonic coupling, an important intermolecular interaction in organic aggregates, between the π-stacking graphene quantum dots is studied by using transient absorption spectroscopy. We find that the spectral evolution of the ground state bleach arises from the dynamic variation of the excitonic coupling in the excited π-stacks. According to the spectral simulations, we demonstrate that the kinetics of the vibronic peak can be exploited as a probe to measure the dynamics of excitonic coupling in the excited π-stacks. 相似文献
79.
Ortiz Adolfo Yang Jianhua Coccolo Mattia Seoane Jesús M. Sanjuán Miguel A. F. 《Nonlinear dynamics》2020,102(4):2323-2337
Nonlinear Dynamics - The main purpose of this paper is to study both the underdamped and the overdamped dynamics of the nonlinear Helmholtz oscillator with a fractional-order damping. For that... 相似文献
80.
Dr. Man-Bo Li Daniels Posevins Dr. Karl P. J. Gustafson Dr. Cheuk-Wai Tai Dr. Andrey Shchukarev Dr. Youai Qiu Dr. Jan-E. Bäckvall 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(1):210-215
A highly selective and efficient oxidative carbocyclization/borylation of enallenols catalyzed by palladium immobilized on amino-functionalized siliceous mesocellular foam (Pd-AmP-MCF) was developed for diastereoselective cyclobutenol synthesis. The heterogeneous palladium catalyst can be recovered and recycled without any observed loss of activity or selectivity. The high diastereoselectivity of the reaction is proposed to originate from a directing effect of the enallenol hydroxyl group. Optically pure cyclobutenol synthesis was achieved by the heterogeneous strategy by using chiral enallenol obtained from kinetic resolution. 相似文献