Diethyl 1-(p-fluoro­phenyl)-5-oxo-3-(2-thienyl)­pyrrolidine-2,2-di­carboxyl­ate

In the title compound, C₂₀H₂₀FNO₅S, the pyrrolidine ring adopts an envelope conformation. The fluoro­phenyl and thio­phene rings are individually planar. The molecular and crystal structures are stabilized by intra- and intermolecular C—H⋯O interactions.     

Secondary flow about a magnetized sphere rotating in viscous conducting fluid

The problem of secondary motion induced by the steady rotation of a magnetized sphere in an infinite incompressible viscous conducting fluid is considered. It is found that the secondary flow adds nothing to the couple required tomaintain the motion and the effect of the magnetic field is to damp the secondary velocity field.     

Effect of polarization on two-dimensional carrier distribution in nitride quantum wells

Wide band-gap group-III nitrides are important for the design of optical devices in the blue and blue–green region. Owing to their wurtzite structure, these materials have a strong inherent polarization field that affects carrier distribution, exciton stability and hence influences the optical properties of the devices. So far, carriers have been assumed to have a sheet-like character. In this paper a non sheet-like distribution function for these quasi two-dimensional carriers is proposed that incorporates the effect of the polarization field. Here GaN/InGaN/GaN and AlGaN/GaN/AlGaN quantum wells have been studied. The polarization field causes the electron and hole wave functions to separate out, thus causing decrease of emission strength and strong reduction of exciton binding energy. This treatment explains well the qualitative nature of carrier distribution in the well. The polarization field changes with GaN mole fraction present in the tertiary nitride layer. The effect of mole fraction on carrier distribution has also been studied. It is found that, inside the well, the hole distribution changes a little more with change in mole fraction than the electron distribution, but for all practical purposes the net change in the distribution pattern is negligible.     

ROLE OF MEROCYANINE DYE AS A PROTON PUMP IN PHOTOVOLTAGE GENERATION

A novel photoelectrochemical cell using a proton pump mechanism in the aggregated planar structure of oxidised cholesterol incorporating merocyanine dyes is reported. Lipid dye binding, as verified from spectral studies and photoisomerisation of the dye, is responsible for this photovoltage generation whose magnitude and storage duration are related to the equilibrium constant of dye-lipid binding through an empirical formula.     

Fragment angular momenta in low and medium energy fission of242Pu

Independent isomeric yield ratios of¹²⁸Sb were determined radiochemically in the thermal neutron induced fission of²⁴¹Pu and 34 MeV alpha particle induced fission of²³⁸U, both involving the same compound nucleus (²⁴²Pu). Fragment angular momenta estimated from the measured isomer ratios using the statistical model analysis showed significantly larger fragment angular momenta in the medium energy fissioning system compared to the low energy fissioning system. This has been attributed to the effect of higher excitation energy and angular momentum in the entrance channel leading to increased fragment temperature, moments of inertia and angular velocity. An attempt was made to calculate the fragment angular momentum in the medium energy fission using the Fermi gas model for the fissioning nucleus, taking into account the multichance fission, saddle shapes of the fissioning nuclei and the angular velocity components of the fissioning nuclei both along and orthogonal to the fission axis. The calculated angular momenta agree well with the experimental results.     

Zero-Sets of Quaternionic and Octonionic Analytic Functions with Central Coefficients

We prove that the zero set of any quaternionic (or octonionic)analytic function f with central (that is, real) coefficientsis the disjoint union of codimension two spheres in R⁴ or R⁸(respectively) and certain purely real points. In particular,for polynomials with real coefficients, the complete root-setis geometrically characterisable from the lay-out of the rootsin the complex plane. The root-set becomes the union of a finitenumber of codimension 2 Euclidean spheres together with a finitenumber of real points. We also find the preimages f^–1for any quaternion (or octonion) A. We demonstrate that this surprising phenomenon of complete spheresbeing part of the solution set is very markedly a special ‘real’phenomenon. For example, the quaternionic or octonionic Nthroots of any non-real quaternion (respectively octonion) turnout to be precisely N distinct points. All this allows us todo some interesting topology for self-maps of spheres.     

Quantumchromodynamic corrections for ΔF=2 processes in the presence of a heavy top quark

We calculate the QCD corrections to the ΔS=2 and ΔB=2 transition amplitudes for the casem _t ?m _w and extrapolate the results tom _t ?m _w , where they join smoothly with the low mass calculations,m _t ?m _w . We present explicit formulas for the corrections with numerical results summarized in tables and figures and compare them with earlier calculations. We arrive at a QCD corrected effective Hamiltonian which must hold for all ranges ofm _t .     

Die langsame Strömung einer einfachen viskoelastischen Flüssigkeit durch einen endlich breiten Spalt

Zusammenfassung Es wird die zweidimensionale schleichende Strömung einer einfachen viskoelastischen Flüssigkeit durch einen endlich breiten Spalt mit Hilfe einer Störungsrechnung untersucht. Dabei wird vorausgesetzt, daß die Relaxationslänge klein gegen die Spaltbreite ist.Für einige Werte der Strömungsparameter werden Ergebnisse für die Geschwindigkeitsverteilung im Spalt, den Stromlinienverlauf und die Reibungsspannungen graphisch dargestellt und diskutiert. Obwohl wegen der Beschränkung der Lösungsmethode die bei Experimenten beobachteten Zirkulationsströmungen nicht beschrieben werden können, zeigen die Ergebnisse, daß die Tendenz der Abweichung vom newtonschen Verhalten in die gleiche Richtung geht.

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Summary The two-dimensional creeping flow of a simple viscoelastic fluid through a finite gap located in an infinitely wide plate is analysed by using a perturbation method.Solutions for the streamline pattern, the velocity distribution in the gap and the stress components are derived and discussed. Because of the restrictions of the perturbation method no circular flow, as observed in some experiments, is predicted, but the results indicate at least some tendencies into this direction.

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Mit 8 Abbildungen     

Controlled buckling and crumpling of nanoparticle-coated droplets

We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the continuous phase. By adding a fixed amount of unsaturated continuous phase, the volume of the droplets can be controllably reduced, causing them to buckle or crumple, thereby becoming nonspherical. The resultant morphologies depend both on the extent of volume reduction and the average droplet size. The buckling and crumpling behavior implies that the droplet surfaces are solid.