排序方式: 共有186条查询结果,搜索用时 15 毫秒
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Devadoss Karthik Kumar Subramaniam Parameswaran Rajendran 《Tetrahedron letters》2012,53(26):3230-3232
We have developed a novel one pot synthesis of 4-chloroquinolin-2-ylamines via Smiles rearrangement under milder condition. The key transformation involves O-alkylation of 4-chloro-1H-quinolin-2-ones with chloroacetamide followed by Smiles rearrangement. The scope of this methodology is further extended to the synthesis of 4-chloroquinolin-2-ylmethylamines and 2-(4-chloroquinolin-2-ylamino)ethanols. This methodology has furnished good yields of 2-amino-4-chloroquinolines. 相似文献
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Zhang X Bao N Ramasamy K Wang YH Wang Y Lin B Gupta A 《Chemical communications (Cambridge, England)》2012,48(41):4956-4958
Cu(2)FeSnS(4) (CFTS) nanocrystals with tunable crystal phase have been synthesized using a solution-based method. As-synthesized CFTS nanocrystals in the shape of oblate spheroid and triangular plate with band gaps of 1.54 ± 0.04 and 1.46 ± 0.03 eV, respectively, appear attractive as a low-cost substitute for thin film solar cells. 相似文献
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Ramasamy K Mazumdar D Bennett RD Gupta A 《Chemical communications (Cambridge, England)》2012,48(45):5656-5658
The Cr-based tellurides are attractive material systems for fundamental studies and potential applications. Colloidal syntheses of ferromagnetic Cr(2)Te(3) and CuCr(2)Te(4) nanocrystals with uniform morphology and narrow size distribution are reported together with their detailed magnetic characterisation. 相似文献
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Spin locking of the nuclear magnetization of a spin with S=1 such as deuterium in the presence of a radio-frequency field under magic angle spinning (MAS) is described in terms of adiabatic modulations of the energy levels. In a brief initial period, part of the initial density operator nutates about the Hamiltonian and is dephased. The remaining spin-locked state undergoes persistent oscillatory transfer processes between various coherences with a periodicity given by the rotation of the sample. While all crystallites in the powder undergo such periodic transfer processes, the phases of the oscillations depend on the angle gamma of the crystallites. The angle gamma is the azimuthal angle defining the orientation of the unique axis of the quadrupolar interaction tensor in a rotor-fixed frame. The theory is extended to describe cross-polarization between spins S=1 and I=12 under MAS. There are four distinct Hartmann-Hahn matching conditions that correspond to four zero-quantum matching conditions, all of which are shifted and broadened compared to their spin S=12 counterparts. These matching conditions are further split into a family of sideband conditions separated by the spinning frequency. The theory allows the calculation of both shifts and broadening factors of the matching conditions, as verified by simulations and experiments. 相似文献
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Friedel-Crafts acylation is carried out with several aromatic substrates in the presence of an electrochemically active aluminium anode to minimize the inorganic reagents. Only a catalytic amount of AlCl3 (5 mol %) is required to enable the anodic polarization of the aluminium electrode to promote continuous acylation. This process typically gave products in good yields (70-96%). 相似文献
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An Enolate‐Mediated Organocatalytic Azide–Ketone [3+2]‐Cycloaddition Reaction: Regioselective High‐Yielding Synthesis of Fully Decorated 1,2,3‐Triazoles 下载免费PDF全文
Adluri B. Shashank S. Karthik R. Madhavachary Prof. Dr. Dhevalapally B. Ramachary 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(51):16877-16881
An enolate‐mediated organocatalytic azide–ketone [3+2]‐cycloaddition (OrgAKC) reaction of a variety of enolizable arylacetones and deoxybenzoins with aryl azides was developed for the synthesis of fully decorated 1,4‐diaryl‐5‐methyl(alkyl)‐1,2,3‐triazoles in excellent yields with high regioselectivity at 25 °C for 0.5–6 h. This reaction has an excellent outcome with reference to reaction rate, yield, regioselectivity, operation simplicity, and availability of substrates and catalyst. This reaction has advantages over the previously known metal‐mediated reactions. 相似文献
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Dr. Gang He William Torres Delgado Devon J. Schatz Dr. Christian Merten Arash Mohammadpour Lorenz Mayr Michael J. Ferguson Robert McDonald Prof. Dr. Alex Brown Prof. Dr. Karthik Shankar Prof. Dr. Eric Rivard 《Angewandte Chemie (International ed. in English)》2014,53(18):4587-4591
The synthesis of the first examples of tellurophenes exhibiting phosphorescence in the solid state and under ambient conditions (room temperature and in air) is reported. Each of these main‐group‐element‐based emitters feature pinacolboronates (BPin) as ring‐appended side groups. The nature of the luminescence observed was also investigated using computational methods. 相似文献
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