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排序方式: 共有266条查询结果,搜索用时 15 毫秒
41.
Liang Li Ningning Yuan Ping Wang Yiqun Wu Yinglin Song Zhimin Chen Chunying He 《Journal of Physical Organic Chemistry》2012,25(10):872-877
Three‐photon absorption (3PA) properties of symmetric‐type carbazole derivatives show great potential for application in light‐activated therapy and optical limiting. A novel symmetrical carbazole derivative (abbreviated as POCP) with end‐groups of 1,10‐phenanthroline rings as the donor moieties, chained via carbon–nitrogen (C = N) double bond, has been synthetized and its three photon absorption properties has been also determined by using a Q‐switched Nd: YAG laser pumped with 30 ps pulses at 1064 nm in dimethylformamide. The measurement of 3PA cross‐section of this compound is performed by open aperture Z‐scan and σ3PA is 481 × 10–78 cm6 ? s2/photon2 for the transition S0 → S1. The influence of the molecular structure of this compound on three‐photon absorption cross‐sections is discussed micromechanically by Austin model 1 and Zerner's Intermediate Neglect of Differential Overlap/S method. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
42.
Jiecai Han Huaixin Guo Mingfu Zhang Ningning Song Chenghai Xu 《Crystal Research and Technology》2012,47(5):485-490
Nd3+‐doped Y3Al5O12 single crystals have been grown by the horizontal directional solidification (HDS) method in different thermal zone. The Grashof (Gr), Prandtl (Pr), Marangoni (Ma) and Rayleigh (Ra) numbers of melt in HDS system have been discussed for our experimental system to understand the mechanism of melt flow patterns and concentration gradient of dopant. The concentration gradient of Nd3+ ions was explained with melt flow processes during crystal growth in different thermal zone, and results indicated that high growth temperature will be helpful for uniformity of dopant in HDS‐grown single crystal. The main microscopic growth defects such as bubbles and irregular inclusions in HDS‐grown Nd:YAG crystals were observed, and the causes were discussed as well. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
43.
以HZSM-5(SiO2/Al2O3=38)为载体,偏钨酸铵为钨源制备了双功能催化剂WC/HZSM-5,考察了其催化正己烷芳构化反应性能,并采用X射线衍射、扫描电子显微镜、X射线能量散射谱和程序升温氨脱附等手段对催化剂进行了表征,探讨了制备方法和WC含量对WC/HZSM-5催化剂性能的影响.结果表明,采用原位还原碳化法制备的WC/HZSM-5(RC)催化剂上正己烷芳构化反应性能优于浸渍法制备的WC/HZSM-5(IP).5%WC/HZSM-5(RC)样品在反应初始阶段芳烃选择性为10.28%,而HZSM-5上的仅为2.56%.WC/HZSM-5(RC)催化剂上反应产物中轻质芳烃(苯、甲苯和二甲苯)含量增加,重质芳烃C9+含量降低,其催化性能优于Pt/HZSM-5催化剂.产物分布的变化可能是由于WC与分子筛间的协同作用所致. 相似文献
44.
45.
Ningning Yan 《Advances in Computational Mathematics》2001,15(1-4):333-361
In this paper, we present a posteriori error estimates of gradient recovery type for elliptic obstacle problems. The a posteriori error estimates provide both lower and upper error bounds. It is shown to be equivalent to the discretization error in an energy type norm for general meshes. Furthermore, when the solution is smooth and the mesh is uniform, it is shown to be asymptotically exact. Some numerical results which demonstrate the theoretical results are also reported in this paper. 相似文献
46.
In this paper, we derive gradient recovery type a posteriori error estimate for the finite element approximation of elliptic equations. We show that a posteriori error estimate provide both upper and lower bounds for the discretization error on the non-uniform meshes. Moreover, it is proved that a posteriori error estimate is also asymptotically exact on the uniform meshes if the solution is smooth enough. The numerical results demonstrating the theoretical results are also presented in this paper. 相似文献
47.
48.
Dr. Yangxin Wang Ningning Zhang En Zhang Yunhu Han Prof. Zhenhui Qi Prof. Dr. Marion B. Ansorge-Schumacher Prof. Dr. Yan Ge Prof. Dr. Changzhu Wu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1716-1721
In cooperative catalysis, the combination of chemo- and biocatalysts to perform one-pot reactions is a powerful tool for the improvement of chemical synthesis. Herein, UiO-66-NH2 was employed to stepwise immobilize Pd nanoparticles (NPs) and Candida antarctica lipase B (CalB) for the fabrication of biohybrid catalysts for cascade reactions. Distinct from traditional materials, UiO-66-NH2 has a robust but tunable structure that can be utilized with a ligand exchange approach to adjust its hydrophobicity, resulting in excellent catalyst dispersity in diverse reaction media. These attractive properties contribute to the formation of MOF-based biohybrid catalysts with high activity and selectivity in the synthesis of benzyl hexanoate from benzaldehyde and ethyl hexanoate. With this proof-of-concept, we reasonably expect that future tailor-made MOFs can combine other catalysts, ranging from chemical to biological catalysts for applications in industry. 相似文献
49.
We study a special case of Shigesada–Kawasaki–Teramoto (SKT) model for two competing species with the Dirichlet boundary conditions. In our case, one of the species is not influenced by self‐diffusion or cross‐diffusion. We specify the explicit range of parameters by contradiction such that there are no coexisting steady‐state solutions to the model. 相似文献
50.
In this paper, capillary zone electrophoresis with amperometric detection (CZE-AD) was applied to determine the compositions of hetero-polysaccharides from Chinese herbs, Angelica sinensis and flax by analyzing their hydrolyzed monosaccharides: fucose, galactose, glucose, arabinose, rhamnose and xylose. Under the selected optimum conditions, the six monosaccharides could be perfectly separated within 25 min and showed significant current responses at copper electrodes. The linear ranges of the six monosaccharides were all from 5.0 x 10(-6) to 2.0 x 10(-4) mol L(-1) and their detection limits were lower or near 1.0 x 10(-6) mol L(-1) (S/N = 3). Experiments showed that the Angelica sinensis polysaccharide was composed of fucose, galactose, glucose, arabinose, rhamnose and xylose (mole ratio 1.0:13.6:15.0:8.7:21.3:3.7), and the flax polysaccharide was composed of galactose, glucose and arabinose (mole ratio 1.0:4.98:1.1). The purity of these polysaccharides leached by the introduced leaching method was 98.3 and 97.6%, respectively. Analyzing polysaccharides by this method has some merits of speed, simple instrumentation and operation, high sensitivity and high reproducibility. 相似文献