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P. Perros J. P. Morizur J. Kossanyi A. M. Duffield 《Journal of mass spectrometry : JMS》1973,7(3):357-364
Electron-impact-induced loss of a water molecule is an important fragmentation pattern of 1,2,3,4-tetrahydronaphthalene-1,2-diol. From deuterium labelling experiments the hydroxylic hydrogen atoms are shown to participate to over 70% in the water elimination. On the other hand, the C-4 hydrogen atoms are involved to the extent of 18% in this sequence. Statistical distribution, resulting from the randomisation of various hydrogen atoms, has been calculated and compared to the experimental values. 相似文献
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Jean Kossanyi J. P. Morizur Bernard Furth Joseph Wiemann A. M. Duffield Carl Djerassi 《Journal of mass spectrometry : JMS》1968,1(6):777-789
The mass spectra of nineteen aliphatic 1,2-glycols containing a variety of substituents have been recorded and mechanistic rationalizations are presented for the more important degradation processes observed. Fragmentation of the hydroxylated carbon-carbon bond in these compounds occurred to an appreciable degree often accompanied by the transfer of a hydroxylic hydrogen atom. 相似文献
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Jean‐François Morizur Lon J. Mathias 《Journal of polymer science. Part A, Polymer chemistry》2008,46(10):3182-3192
The synthesis of alkyl 2‐(carboethoxyhydroxymethyl)acrylates via the Bayllis‐Hillmann reaction pathway is described. These compounds are found to be poor monomers when involved in free radical polymerizations but present an extremely high reactivity upon Michael addition with primary amines leading to a simple, mild and efficient route to the preparation of new multifunctional heterocycles and polymers with potential applications in biodegradable coatings. Real‐time NMR spectroscopy permitted monitoring the extent of the reaction sequence and determining the conversion profile of reactants and Michael adduct intermediate. Poly(ester amide)s derived from diamine and hexane bis‐2‐(carboethoxyhydroxymethyl)acrylate were synthesized at room temperature by means of a very efficient Michael addition/cyclization polymerization. These polymers display excellent adhesion to metal, glass, and paper substrates and interesting hydrolytic susceptibility. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3182–3192, 2008 相似文献
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The structural and electronic transport properties of La1−x
Ce
x
MnO3 (x=0.0–1.0) have been studied. All the samples exhibit orthorhombic crystal symmetry and the unit cell volume decreases with
Ce doping. They also make a metal-insulator transition (MIT) and transition temperature increases with increase in Ce concentration
up to 50% doping. The system La0.5Ce0.5MnO3 also exhibits MIT instead of charge-ordered state as observed in the hole doped systems of the same composition. 相似文献
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The first total and stereoselective synthesis of (E)-6, 10 dimethyl-9 methylidene undec-5-en-2-one: a constituant of Costus Root oil is reported. It was conducted with an overall yield of 22% from 1-methyl-2-oxo-methylcyclopentane carboxylate (α-methylated Dieckmann-ester) , used as a starting material. 相似文献