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61.
Ishii K Tsutsui K Endoh Y Tohyama T Kuzushita K Inami T Ohwada K Maekawa S Masui T Tajima S Murakami Y Mizuki J 《Physical review letters》2005,94(18):187002
Mott gap excitations in the optimally doped high-T(c) superconductor YBa(2)Cu(3)O(7-delta) (T(c)=93 K) have been studied by the resonant inelastic x-ray scattering method. Anisotropic spectra in the ab plane are observed in a twin-free crystal. The excitation from the one-dimensional CuO chain is enhanced at 2 eV near the zone boundary of the b* direction, while the excitation from the CuO2 plane is broad at 1.5-4 eV and almost independent of the momentum transfer. Theoretical calculations based on the one-dimensional and two-dimensional Hubbard model reproduces the observed spectra when different values of the on-site Coulomb energy are assumed. The Mott gap of the CuO chain site is found to be much smaller than that of the CuO2 plane site. 相似文献
62.
The kinetics of the phase transition between the (2 x 2) and (p x square root[3])-Bi structures on Au(111) was investigated using electrochemical methods and time-resolved surface X-ray diffraction. The temporal changes in the current value and the diffracted X-ray intensity that originated from the (2 x 2)-Bi overlayer were monitored during the phase transitions at various over-potentials. The phase transition models and kinetics parameters were deduced from each of the current and X-ray intensity transient curves. We also carried out comparative studies of the phase transition from the structural and electrochemical points of view. For the (p x square root[3]) --> (2 x 2) phase transition, the phase transition models determined by the X-ray and electrochemical measurements were a surface-diffusion controlled instantaneous nucleation-growth process and a Langmuir process, respectively. For the reverse transition, the phase transition models determined by X-ray and electrochemical measurements were a Langmuir adsorption process and a surface diffusion controlled nucleation-growth process, respectively. Our results revealed that the current transient curve does not always reflect the phase transition model in both cases and suggest that a structural analysis is fundamental in the phase transition studies. The disagreements between the phase transition models and their mechanisms are discussed. 相似文献
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Masahiro Yoshida Kenji Ishii Ignace Jarrige Tetsu Watanuki Kazutaka Kudo Yoji Koike Ken'ichi Kumagai Nozomu Hiraoka Hirofumi Ishii Ku‐Ding Tsuei Jun'ichiro Mizuki 《Journal of synchrotron radiation》2014,21(1):131-135
A single‐crystal momentum‐resolved resonant inelastic X‐ray scattering (RIXS) experiment under high pressure using an originally designed diamond anvil cell (DAC) is reported. The diamond‐in/diamond‐out geometry was adopted with both the incident and scattered beams passing through a 1 mm‐thick diamond. This enabled us to cover wide momentum space keeping the scattering angle condition near 90°. Elastic and inelastic scattering from the diamond was drastically reduced using a pinhole placed after the DAC. Measurement of the momentum‐resolved RIXS spectra of Sr2.5Ca11.5Cu24O41 at the Cu K‐edge was thus successful. Though the inelastic intensity becomes weaker by two orders than the ambient pressure, RIXS spectra both at the center and the edge of the Brillouin zone were obtained at 3 GPa and low‐energy electronic excitations of the cuprate were found to change with pressure. 相似文献
67.
Nishima W Kanamaru S Arisaka F Kitao A 《Journal of the American Chemical Society》2011,133(34):13571-13576
Bacteriophage T4 penetrates the outer membrane of Escherichia coli using a multifunctional device composed of a gene product 5 (gp5) protein trimer. We report that gp5 sequentially exerts distinct functions along the course of penetration stages induced by screw motion. A triple-stranded β-helix of gp5 acts as a cell-puncturing drill bit to make a hole on the membrane and then send the lipids upward efficiently by strong charge interactions. The gp5 lysozyme domains, which degrade the peptidoglycan layer later, are shown to play novel roles to enlarge the hole and control the release of the β-helix. The lysozyme active site is protected from lipid binding during the penetration and is exposed after the β-helix release. Intrinsic multiple functions of gp5 are shown to be served in turn regulated by gradual change of interdomain interactions, which enables the initial infection process with single protein trimer by continuous screw motion. The results of lysozyme domain should be understood as the case where a single-function protein acquired multiple chemical functions through interplay with other domains in a multidomain protein. 相似文献
68.
Rika Okuma Tomoki Kuwahara Takafumi Yoshikane Mizuki Watanabe Patricia Dranchak James Inglese Satoshi Shuto Yuki Goto Hiroaki Suga 《化学:亚洲杂志》2020,15(17):2631-2636
Here we report the construction of an mRNA‐encoded library of thioether‐closed macrocyclic peptides by using an N‐chloroacetyl‐cyclopropane‐containing exotic initiator whose structure is more constrained than the ordinary N‐chloroacetyl‐α‐amino acid initiators. The use of such an initiator has led to a macrocycle library with significantly suppressed population of lariat‐shaped species compared with the conventional libraries. We previously used a conventional library and identified a small lariat thioether‐macrocycle with a tail peptide with a C‐terminal free Cys whose sidechain plays an essential role in potent inhibitory activity against a parasitic model enzyme, phosphoglycerate mutase. On the other hand, the cyclopropane‐containing macrocycle library has yielded a larger thioether‐macrocycle lacking a free Cys residue, which exhibits potent inhibitory activity to the same enzyme with a different mode of action. This result indicates that such a cyclopropane‐containing macrocycle library would allow us to access mechanistically distinct macrocycles. 相似文献
69.
Y. Murakami Y. Ohkubo D. Fuse Y. Sakamoto T. Ono S. Kitao M. Seto M. Tanigaki T. Saito S. Nasu Y. Kawase 《Hyperfine Interactions》2004,158(1-4):145-149
Hyperfine fields at Fe and Mo layers in polyimide/Fe(10 nm)/[Mo(1.1 nm)/Fe(2.0 nm)]120 and [Mo(1.3 nm) /Fe(2.0 nm)]120 multilayers prepared by the electron-beam evaporation technique were measured at room-temperature by Mössbauer spectroscopy and perturbed-angular-correlation spectroscopy. The hyperfine fields in the Fe layers do not show a clear dependence on the Mo layer thickness. On the other hand, the hyperfine fields in the Mo layers show different magnetic structures in these samples. The difference suggests a variation of electron spin polarization in the Mo layers. 相似文献
70.
We herein propose the multiple Markov transition matrix method (MMMM), an algorithm by which to estimate the stationary probability distribution from independent multiple molecular dynamics simulations with different Hamiltonians. Applications to the potential of mean force calculation in combination with the umbrella sampling method are presented. First, the performance of the MMMM is examined in the case of butane. Compared with the weighted histogram analysis method (WHAM), the MMMM has an advantage with respect to the reasonable evaluation of the stationary probability distribution even from nonequilibrium trajectories. This method is then applied to Met‐enkephalin nonequilibrium simulation. © 2008 Wiley Periodicals, Inc. J Comput Chem, 2009 相似文献