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101.
A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam 总被引:1,自引:0,他引:1
JiaXingHUANG XiaoMeiLIANG DaoQuanWANG 《中国化学快报》2004,15(2):169-170
12-Oxo-1,15-pentadecanlactam 7 was synthesized from cyclododecanone with a totalyield of 36% in a seven-step reaction. The azide 5 to 12-nitro-1,15-pentadecanlactam 6 is the key step featured by direct ring expansion. 相似文献
102.
废旧电池中的重金属对人体的危害 总被引:7,自引:0,他引:7
讨论了废旧电池对环境的致毒作用和对人体健康的危害,介绍了废旧电池中重金属在生物体中的吸收、转化、分布、作用部位及毒性,指出人类社会的可持续性发展与自然生态循环的协调一致要求从源头上制止污染,而不是在术端治理污染,即从根本上改变人类的物质生活方式,重新回到生态系统的框架之内。 相似文献
103.
104.
CHU Yongbao GAO Baoyu YUE Qinyan WANG Yan & WANG Shuguang . School of Environmental Science Engineering Shandong University Jinan China . College of Material Environment Qingdao University of Science Technology Qingdao China 《中国科学B辑(英文版)》2006,(4)
Polyaluminum chloride (PAC) coagulant has been developed and widely used in water and wastewater treatment industry since the 1980s[1]. PAC is normally made by partial hydrolysis of acid aluminum chloride solution using slow alkaline titration method. However, this method would result in many different Al species. Among these Al species, it seems that tridecamer (Al13O4(OH) 724 , often denoted by Al13) is the most effective and stable polymeric Al species for water and wastewater treatme… 相似文献
105.
ShiGuoSUN XiaoJunPENG MingWenFAN YongQianXU LeiSHI LiChengSU 《中国化学快报》2004,15(8):965-968
Two novel rhenium(I) 2, 2′-bipyridyl complexes, [(4,4′-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4′-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4′-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN. 相似文献
106.
The reaction of 3-(1-hydropolyfluoroalkenyl)-1-oxo-2,4,1-benzoxazines 1 with some dinucleophiles was inves-tigated.7-Fluoroalkyl-2,3-dihydro-1,4-diazepine[1,2-d]quinazolin-11-ones 2,2-fluoroalkylisoxazolo[3,2-b]quin-azolin-9-ones 3 and 2-fluoroalkylbenzoimidazoles 4 were obtained from the reaction of 1 with 1,2-diaminoethane,hydroxylamine hydrochloride and 1,2-diaminobenzene respectively. 相似文献
107.
HongBingJI DuGuiHE JunSONG YuQIAN 《中国化学快报》2004,15(10):1241-1244
Clean liquid oxidation of aldehydes can be accomplished using solid catalyst in the presence of molecular oxygen at room temperature, which is a valuable alternative to traditional counterparts. 相似文献
108.
Introduction Tremendous advances have been witnessed during the last decade in the syntheses and application of Group 4 metal complexes because of the motivity which comes from both academic and industrial field. Among them, studies have been dominated by the complexes supported by bis or mono cyclopentadienyl ligands, such as Cp2MX2 or half sandwich amide (CGC) com-plexes.1-6 At that time chemists paid a little attention to the non-cyclopentadienyl complexes, but in recent years, many chem… 相似文献
109.
Li Qiu WANG Xiao Jun PENG* Rong ZHANG Guo Quan XU Jing Nan CUI State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian 《中国化学快报》2003,(1)
Indocyanine dyes as fluorescent labeling reagents have been used in bioanalysis1,2. Arylsulfonate indocyanine dyes 1d and 1e developed by Waggoner A. S. et al.3,4 have excellent fluorescent properties combined with good aqueous solubility, are a new generation of fluorescent label compounds for proteins, oligonucleotides and other compounds containing hydroxyl, mercaptol or primary amine groups5. However, photostability of these dyes has been a problem. Z. G. YAO et al.6 reported that p… 相似文献
110.
ZENG ChunHua WANG Hua & HU JianHang Faculty of Science Kunming University of Science Technology Kunming China Province Engineering Research Center of Industrial Energy Conservation New Technology 《中国科学:物理学 力学 天文学(英文版)》2011,(8)
In this paper, we investigate the escape of Brownian particles and stochastic resonance (SR) with low-temperatures quantum fluctuations by using the quantum Smoluchowski equations at low-temperature. Two specific examples have been considered: one is the example of bistable system, and the other is the example of metastable system. The explicit expressions of the mean-first passage time (MFPT) and signal-to-noise ratio (SNR) for both specific examples are obtained, respectively. Based on the numerical compu... 相似文献