Breakdown voltage improvement of LDMOSs by charge balancing: An inserted P-layer in trench oxide (IPT-LDMOS)

For the first time, the novel inserted P-layer in trench oxide of LDMOS structure (IPT-LDMOS) is proposed in which a trench oxide with inserted P-layer is considered in the drift region to improve the breakdown voltage. Our simulation with two dimensional ALTAS simulator shows that by determining the optimum doping concentration of the P-layer, the charges of the N-drift and P-layer regions would be balanced. Therefore, complete depletion at the breakdown voltage in the drift region happens. Also, electric field in the IPT-LDMOS is modified by producing additional peaks which decrease the common peaks near the drain and source junctions.     

Essential normality for certain finite linear combinations of linear-fractional composition operators on the Hardy space H 2

In 1999 Nina Zorboska and in 2003 P. S.Bourdon, D. Levi, S.K.Narayan and J.H. Shapiro investigated the essentially normal composition operator ${C_\varphi }$ , when φ is a linear-fractional self-map of D. In this paper first, we investigate the essential normality problem for the operator T _w ${C_\varphi }$ on the Hardy space H ², where w is a bounded measurable function on ?D which is continuous at each point of F(φ), φ ∈ S(2), and T _w is the Toeplitz operator with symbol w. Then we use these results and characterize the essentially normal finite linear combinations of certain linear-fractional composition operators on H ².     

An efficient one‐pot synthesis of a new heterocyclic system with high‐fluorescent properties

Nucleophilic substitution of hydrogen in nitro derivative of imidazo[1,2‐a]pyridine has been used as a key step in the one‐pot synthesis of a new highly fluorescent heterocyclic system pyrido [1″,2″:1′,2′]imidazo[4′,5′:5,6]pyrido[2,3‐b]indole. J. Heterocyclic Chem., (2012).     

Design and synthesis of a magnetic hierarchical porous organic polymer: A new platform in heterogeneous phase‐transfer catalysis

Recyclable phase transfer catalysts containing magnetic nanoparticles (MNPs) have been known as a major trend towards sustainable catalysts. In this study, a novel class of magnetic porous polymer on the basis of calix[4]resorcinarene was synthesized starting from silica‐coated Fe₃O₄ core‐shell nanoparticles. This compound was found as an efficient phase transfer catalyst to the conversion of benzyl halides into benzyl azides and cyanides in good yields. The catalyst could be used at least for five consecutive cycles without appreciable loss in the catalytic activity.     

Naturally occurring organic acids for organocatalytic synthesis of pyrroles via Paal–Knorr reaction

Research on Chemical Intermediates - In this study, common naturally occurring organic acids, namely oxalic, malonic, succinic, tartaric and citric acid (as safe, inexpensive, and biodegradable...     

Optimization of the decentralized cash management problem

This paper treats the problem of determining optimal level of transaction balances in a decentralized firm. In conformity with the practices of such firms, cash generated at dispersed location is concentrated at central locations prior to short-term investment and borrowing. Under deterministic assumptions, an optimal transfer/investment is derived and a simple procedure for determining optimal parameters is described.     

Practical and efficient synthesis of tetrahydrobenzo[<Emphasis Type="Italic">b</Emphasis>]pyran using caffeine supported on silica as an ionic liquid solid acid catalyst

The new catalyst silica-caffeine hydrogen sulfate [SiO₂-caff.]HSO₄ was conveniently prepared from commercially available 3-chloropropyltriethoxysilane via immobilization on silica followed by reaction with caffeine. The catalyst prepared was then characterized by the FT-IR spectroscopy, TGA, EDX, and SEM techniques. It was found that this heterogeneous catalyst was a highly efficient one for the synthesis of tetrahydrobenzo[b]pyrans in good-to-high yields, and could be recovered by a simple filtration of the reaction solution and reused for five consecutive runs. The attractive features of this method are simple procedure, clean reaction, easy work-up, use of a reusable catalyst, and performing a multi-component reaction.     

Discrimination of Shirazi thyme from thymus species and antioxidant activity prediction using chemometrics and FT-IR spectroscopy

Local names are not reliable sources for identification of plants, because they differ significantly from one region to another. Apart from confusing nomenclature, the similar appearance and fragrance of Shirazi thyme and Thymus species cause misidentification. In order to prevent the adverse events in relation to the use of improper herbal products, easy-to-use quality control (QC) methodology was developed to classify these culinary plants. Fourier transform infrared (FT-IR) fingerprinting technique was applied for classification of these plants on the basis of their biochemical compositions. Powerful PLS-DA classification model with classification accuracy of 100% was obtained. For the first time in the present study, it was revealed that Shirazi thyme samples have higher antioxidant activity [average IC₅₀ of 37.03 (µg/ml)] compared to different Thymus species [average IC₅₀ of 148.35 (µg/ml)]. FT-IR fingerprint profiles were also used to construct a predictive model for antioxidant activity of the plants based on a reliable PLSR model. The developed PLSR model revealed that IR wavenumbers of 1000–1200, 1700, and 3200–3500 cm^?1 are important for antioxidant activity prediction of the analyzed plants. The applied approach has the potential for being used in QC programs not only for fraud mitigation and detection, but also for estimation of antioxidant activity of the culinary plants.