Tandem silylation—desilylation reaction in the synthesis of N-methyl carboxamides

Russian Chemical Bulletin - The N-methylation of primary carboxamides is based on two consecutive reactions. The silylation of the corresponding carboxamides with chloro(chloromethyl)dimethylsilane...     

Electron Backscattered Diffraction for the Study of Matrices for Immobilization of Actinides Composed of the Murataite-Type Phases

Crystallography Reports - Electron backscattered diffraction (EBSD) has been used to analyze structures of natural minerals and artificial compounds for almost three decades. In recent years, it is...     

Dispersive correction for the second- and the third-order nonlinear terms of the electrical energy density for a light-dielectric system

Optical and Quantum Electronics - Classification of hyperspectral image (HSI) is widely used for the study of remotely sensed images. Convolutional Neural Networks (CNNs) are one of the most...     

Effect of External Factors on the Ferromagnetic Resonance Line Width in Exchange-Biased Structures

Physics of the Solid State - The external factors which influence the ferromagnetic resonance (FMR) line width in bilayer (ferromagnet/antiferromagnet) exchange-biased systems are studied. The...     

Crystallographic Parameters of Special Grain Boundaries in Multicrystalline Silicon

Crystallography Reports - The orientation of grains and the special boundaries formed by them in multicrystalline silicon has been studied by electron backscattered diffraction. It is found that...     

Fractional derivative method for describing solitons on the surface of deep water

Theoretical and Mathematical Physics - The fractional derivative method is used to take wave dispersion into account in the wave equation when describing the propagation of gravitational soliton...     

Biosynthesis of zinc oxide nanoparticles using Euphorbia milii leaf constituents: Characterization and improved photocatalytic degradation of methylene blue dye under natural sunlight

A facile biosynthesis route was followed to prepare zinc oxide nanoparticles (ZnO NPs) using Euphorbia milii (E. milii) leaf constituents. The SEM images exhibited presence of spherical ZnO NPs and the corresponding TEM images disclosed monodisperse nature of the ZnO NPs with diameter ranges between 12 and 20 nm. The Brunauer–Emmett–Teller (BET) analysis revealed that the ZnO NPs have specific surface area of 20.46 m²/g with pore diameter of 2 nm–10 nm and pore volume of 0.908 cm³/g. The EDAX spectrum exemplified the existence of Zn and O elements and non-appearance of impurities that confirmed pristine nature of the ZnO NPs. The XRD pattern indicated crystalline peaks corresponding to hexagonal wurtzite structured ZnO with an average crystallite size of 16.11 nm. The FTIR spectrum displayed strong absorption bands at 512 and 534 cm^?1 related to ZnO. The photocatalytic action of ZnO NPs exhibited noteworthy degradation of methylene blue dye under natural sunlight illumination. The maximum degradation efficiency achieved was 98.17% at an illumination period of 50 min. The reusability study proved considerable photostability of the ZnO NPs during photocatalytic experiments. These findings suggest that the E. milii leaf constituents can be utilized as suitable biological source to synthesis ZnO NPs for photocatalytic applications.     

Reply to comment on “Limitation of uranium and thorium traces in charnockite matrix‐PIXE analyses at 3 MeV with Si (Li) detector”

Journal of Radioanalytical and Nuclear Chemistry -     

Transition-Metal Catalysis of Triene 6π Electrocyclization: The π-Complexation Strategy Realized

Triene 6π electrocyclization, wherein a conjugated triene undergoes a concerted stereospecific cycloisomerization to a cyclohexadiene, is a reaction of great historical and practical significance. In order to circumvent limitations imposed by the normally harsh reaction conditions, chemists have long sought to develop catalytic variants based upon the activating power of metal–alkene coordination. Herein, we demonstrate the first successful implementation of such a strategy by utilizing [(C₅H₅)Ru(NCMe)₃]PF₆ as a precatalyst for the disrotatory 6π electrocyclization of highly substituted trienes that are resistant to thermal cyclization. Mechanistic and computational studies implicate hexahapto transition-metal coordination as responsible for lowering the energetic barrier to ring closure. This work establishes a foundation for the development of new catalysts for stereoselective electrocyclizations.