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81.
Jing Zhang Dan Shan Shaolin Mu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5573-5582
A copolymer, poly(aniline‐co‐o‐aminophenol), was prepared chemically by using ammonium peroxydisulfate as an oxidant. The monomer concentration ratio of o‐aminophenol to aniline strongly influences the copolymerization rate and properties of the copolymer. The optimum composition of a mixture for the chemical copolymerization consisted of 0.3 M aniline, 0.021 M o‐aminophenol, 0.42 M ammonium peroxydisulfate, and 2 M H2SO4. The result of cyclic voltammograms in a potential region of ?0.20 to 0.80 V (vs.SCE) indicates that the electrochemical activity of the copolymer prepared under the optimum condition is similar to that of polyaniline in more acid solutions. However, the copolymer still holds the good electrochemical activity until pH 11.0. Therefore, the pH dependence of the electrochemical property of the copolymer is improved, compared with poly(aniline‐co‐o‐aminophenol) prepared electrochemically, and is much better than that of polyaniline. The spectra of IR and 1H NMR confirm that o‐aminophenol units are included in the copolymer chain, which play a key role in extending the usable pH region of the copolymer. The visible spectra of the copolymers show that a high concentration ratio of o‐aminophenol to aniline in a mixture inhibits the chain growth. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5573–5582, 2007 相似文献
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LUO You-Hua GE Zi-Ming 《理论物理通讯》2006,46(12)
In noncommutative space, we examine the problem of a noninteracting and harmonically trapped BoseEinstein condensate, and derive a simple analytic expression for the effect of spatial noncommutativity on energy spectrum of the condensate. It indicates that the ground-state energy incorporating the spatial noncommutativity is reduced to a lower level, which depends upon the noncommutativity parameter θ. The gap between the noncommutative space and commutative one for the ground-state level of the condensate should be a signal of spatial noncommutativity. 相似文献
84.
Thermal Rate Constants of the N(^4S)+O2(X^3∑g^-) → NO(X^2Ⅱ) +O(^3P) Reaction on the ^2A′ Potential Energy Surface 下载免费PDF全文
A quasiclassical trajectory study with the sixth-order explicit symplectic algorithm for the N(^4S)+O2(X^3∑g^-) → NO(X^2Ⅱ) +O(^3P) reaction has been reported by employing a new ground potential energy surface. We have discussed the influence of the relative translational energy, the vibrational and rotational levels of O2 molecules on the total reaction cross section. Thermal rate constants at temperatures 300, 600, and 1000 K determined in this work for the reaction are 4.4 × 10^7, 1.8 × 10^10, and 3.1 × 10^11 cm^3mol^-1s^-1, respectively. It is found that they are in better agreement with the experimental data than previous theoretical values. 相似文献
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87.
Effects of Substrate Temperature on Helium Content and Microstructure of Nanocrystalline Titanium Films 下载免费PDF全文
Helium-charged nanocrystalline titanium films have been deposited by HeAr magnetron co-sputtering. The effects of substrate temperature on the helium content and microstructure of the nanocrystalline titanium films have been studied. The results indicate that helium atoms with a high concentration are evenly incorporated in the deposited titanium films. When the substrate temperature increases from 60℃ to 350℃ while the other deposition'parameters are fixed, the helium content decreases gradually from 38.6 at.% to 9.2at.%, which proves that nanocrystalline Ti films have a great helium storage capacity. The 20 angle of the Bragg peak of (002) crystal planes of the He-charged Ti film shifts to a lower angle and that of (100) crystal plane is unchanged as compared with that of the pure Ti film, which indicates that the lattice parameter c increases and a keeps at the primitive value. The grain refining and helium damage result in the diffraction peak broadening. 相似文献
88.
采用聚丙烯胺溶胶-凝胶法制备了类钙钛矿La1-xNDxSrCoO4(x=0.1~0.9)复合氧化物催化剂,考察了其对CO和C3H8的催化氧化活性,并运用XRD、IR和TPR等手段对催化剂进行了表征.结果表明,所制备的样品均具有K2NiF4型结构,适量Nd2O3的加入增加了LaSrCoO4的催化活性,使LaSrCoO4催化剂粒度变小、晶格畸变率变大及与氧的结合能力减弱,从而有利于CO和C3H8氧化活性的提高. 相似文献
89.
90.
Jing Cheng 《量子光学学报》2006,12(B08):71-72
The effect of finite control beam on the transverse spatial profile of the slow light propagation in an electromagnetically induced transparency medium is studied. From the second-order wave equation and linear response of an EIT medium to the signal field, we find it is possible to produce an effective waveguide for the signal field. The existence and properties of a set of localized, stationary transverse modes are demonstrated. Especially, by carefully manipulating the profile of the control beam, we can realize single-mode propagation for the signal field, which may be important for potential applications. 相似文献