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11.
Formation of p-type ZnO film on InP substrate by phosphor doping 总被引:3,自引:0,他引:3
Kyu-Hyun Bang Deuk-Kyu Hwang Min-Chul Park Young-Don Ko Ilgu Yun Jae-Min Myoung 《Applied Surface Science》2003,210(3-4):177-182
ZnO thin film was initially deposited on InP substrate by radio frequency (rf) magnetron sputtering and the diffusion process was performed using the closed ampoule technique where Zn3P2 was used as the dopant source. To verify the junction formation of ZnO thin films, the electrical properties were measured, and the effects of Zn3P2 diffusion on ZnO thin films were investigated. It is observed that the electrical property of the film is changed from n-type to p-type by dopant diffusion effect. Based on the results, it is confirmed that ZnO thin films can be a potential candidate for ultraviolet (UV) optical devices. 相似文献
12.
Al2O3 incorporated HfO2 films grown by atomic layer deposition (ALD) were investigated by high-resolution X-ray photoelectron spectroscopy (HRXPS). The core level energy state of a 15 Å thick film showed a shift to higher binding energy, as the result of a silicate formation and Al2O3 incorporation. The incorporation of Al2O3 into the HfO2 film had no effect on silicate formation at the interface between the film and Si, while the ionic bonding characteristics and hybridization effects were enhanced compared to a pure HfO2 film. The dissociation of the film in an ultrahigh vacuum (UHV) is effectively suppressed compared to a pure HfO2 film, indicating an enhanced thermal stability of Hf-Al-O. Any dissociated Al2O3 on the film surface was completely removed into the vacuum by vacuum annealing treatment over 850 °C, while HfO2 contributed to Hf silicide formation on the film surface. 相似文献
13.
For the methylsilsesquioxane film whose optical birefringence is almost zero, it was recently reported that its vertical thermal expansion coefficient (CTE) was approximately one order of magnitude larger than the lateral CTE. Though the birefringence is not an absolute predictor of anisotropic behavior, the discrepancy in both the CTEs was so remarkable that it was essential to investigate whether the anisotropy was intrinsic property or not. If the effect of Poisson's ratio is considered in the calculation of the vertical CTE and when elastic modulus measured by surface acoustic wave spectroscopy is used in the assessment of the lateral CTE, both the CTEs are coincident with each other. Therefore, it can be concluded that the discrepancy in the CTEs can be attributed to a higher in‐plane polymer chain orientation but it can also arise from the misleadingly assumed modulus and Poisson's ratio. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3109–3120, 2006 相似文献
14.
15.
Ha Yong Lee Se Hun Jung Soo Yong Lee Young Ho You Kyung Hyun Ko 《Applied Surface Science》2005,252(5):1891-1898
Al-Al2O3 composite coatings with different Al2O3 particle shapes were prepared on Si and Al substrate by cold spray. The powder compositions of metal (Al) and ceramic (Al2O3) having different sizes and agglomerations were varied into ratios of 10:1 wt% and 1:1 wt%. Al2O3 particles were successfully incorporated into the soft metal matrix of Al. It was found that crater formation between the coatings and substrate, which is typical characteristic signature of cold spray could be affected by initial starting Al2O3 particles. In addition, when the large hard particles of fused Al2O3 were employed, the deep and big craters were generated at the interface between coatings and hard substrates. In the case of pure soft metal coating such as Al on hard substrate, it is very hard to get proper adhesion due to lack of crater formation. Therefore, the composite coating would have certain advantages. 相似文献
16.
Kenji Handa 《Journal of statistical physics》1996,83(3-4):555-571
Entropy production per site in a (nonreversible) spin-flip process is studied. We give it a useful expression, from which a property stronger than affinity of the entropy production per site follows. Furthermore, quasi-invariance of nonequilibrium measures in the spin-flip processes is discussed via entropy production. 相似文献
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18.
Toshihide Baba Satoru Hikita Haruhisa Handa Yoshio Ono 《Research on Chemical Intermediates》1998,24(5):495-505
Europium supported on alumina (Eu/Al2O3) was prepared by impregnation from an ammoniacal solution of the metal. The catalytic activity of Eu/Al2O3 for the isomerization of 2,3-dimethylbut-1-ene to 2,3-dimethylbut-2-ene was examined. Eu/Al2O3 showed the highest catalytic activity for the isomerization when heated under a vacuum at 523 K, the yield of 2,3-dimethylbut-2-ene
in 20 min being 81.6% at 314 K. IR spectrum shows the presence of two kinds of Eu amides. The change of the IR spectra and
the catalytic activities with evacuation temperature suggest that only one of the two Eu amides is catalytically active for
this base-catalyzed isomerization. 相似文献
19.
JiŘí Kvapil Josef Kvapil Bohumil Perner Michal Košelja Helena Jelínková 《Czechoslovak Journal of Physics》1990,40(11):1283-1287
The methods of growing YAG:Nd crystals with a flat interface and YAP:Nd crystals with a sharp conical interface are described. The form of the interface was controlled by the He and H2O content in the reducing atmosphere composed mainly of Ar and H2 as well as by axial temperature gradient above the melt level. The crystals of 120–180 mm in length were machined to the high-quality slabs. 相似文献
20.
The present paper summarizes detailed investigations of Nd3+ fluorescence spectra in YAP:Nd laser crystal in the broad spectral range of 370–1100 nm at liquid nitrogen temperature. Especially, Nd3+ near UV and visible fluorescence spectra were studied for the first time in this crystal. The Nd3+ near UV and visible fluorescence spectra of this crystal consist of many narrow lines (up to 50). The Nd3+ near UV and visible fluorescence lines arise mainly from4D3/2 and2P3/2 Nd3+ terms (transitions from4D3/2,2P3/2 to lower lying Nd3+ levels are responsible for their appearance). At room temperature the fluorescence spectra consist of broad bands with narrow lines (mainly4D3/24F3/2,4F5/2 and2H9/2 transitions). 相似文献