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91.
Joan A. Vaccaro 《Foundations of Physics》2011,41(10):1569-1596
An increasing number of experiments at the Belle, BNL, CERN, DAΦNE and SLAC accelerators are confirming the violation of time
reversal invariance (T). The violation signifies a fundamental asymmetry between the past and future and calls for a major
shift in the way we think about time. Here we show that processes which violate T symmetry induce destructive interference
between different paths that the universe can take through time. The interference eliminates all paths except for two that
represent continuously forwards and continuously backwards time evolution. Evidence from the accelerator experiments indicates
which path the universe is effectively following. This work may provide fresh insight into the long-standing problem of modeling
the dynamics of T violation processes. It suggests that T violation has previously unknown, large-scale physical effects and
that these effects underlie the origin of the unidirectionality of time. It may have implications for the Wheeler-DeWitt equation
of canonical quantum gravity. Finally it provides a view of the quantum nature of time itself. 相似文献
92.
Joan Boulanger Olivier Balima 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(7):1222-1228
We present the first reconstruction algorithm for refractive index imaging, which is based on the radiative transfer equation (RTE). An objective function is iteratively minimized to find a solution to the problem of inversion of the refractive index field. The function describes the discrepancies of the emerging light measurements on the surface of the sample to be probed with predicted data from the corresponding numerical model. The unknown refractive index field is updated within each reconstruction iteration according to a search direction on the index distribution given by the adjoint model to the RTE. In this paper, emphasis is placed on the theoretical aspects. Preliminary tests are demonstrated on generic phantoms. 相似文献
93.
Sergey V. Gonchenko Ivan I. Ovsyannikov Joan C. Tatjer 《Regular and Chaotic Dynamics》2014,19(4):495-505
It was established in [1] that bifurcations of three-dimensional diffeomorphisms with a homoclinic tangency to a saddle-focus fixed point with the Jacobian equal to 1 can lead to Lorenz-like strange attractors. In the present paper we prove an analogous result for three-dimensional diffeomorphisms with a homoclinic tangency to a saddle fixed point with the Jacobian equal to 1, provided the quadratic homoclinic tangency under consideration is nonsimple. 相似文献
94.
Lan-Ying Qin Andrew G. Cole Marc-Raleigh Brescia Joan J. Zhang James R. Wareing Juerg Zimmermann John J. Baldwin 《Tetrahedron letters》2010,51(34):4486-4489
A facile synthesis of novel 2-amino-6-arylmethyl-7-carboxamido-7,8-dihydropyrimido[5,4-f][1,4]thiazepin-5-ones is described. The synthesis was developed on solid phase and was applied to provide a series of analogs in good yield. The key reactions are acylation of a cysteine derivative with 2,4-dichloropyrimidine-5-carbonyl chloride followed by cyclization to generate a 6-arylmethyl-7-carboxamido-2-chloro-7,8-dihydropyrimido[5,4-f][1,4]thiazepin-5-one, which is further derivatized with an amine to give the desired 2-amino-6-arylmethyl-7-carboxamido-7,8-dihydropyrimido[5,4-f][1,4]thiazepin-5-one. 相似文献
95.
Carmen Coll Elena Aznar Ramón Martínez‐Máñez Prof. M. Dolores Marcos Dr. Félix Sancenón Dr. Juan Soto Dr. Pedro Amorós Joan Cano Dr. Eliseo Ruiz Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(33):10048-10061
We report the preparation of a MCM‐41 mesoporous material that contains the dye [Ru(bipy)3]Cl2 (bipy=bipyridine) inside the mesopores and functionalised with suitable binding groups at the entrance of the pores. Solids S1 – S3 were obtained by the reaction of the mesoporous material with N‐methyl‐N′‐propyltrimethoxysilylimidazolium chloride, N‐phenyl‐N′‐[3‐(trimethoxysilyl)propyl]thiourea, or N‐phenyl‐N′‐[3‐(trimethoxysilyl)propyl]urea, respectively. A study of the dye delivery of these systems in buffered water (pH 7.0, 2‐[4‐(2‐hydroxyethyl)piperazin‐1‐yl]ethanesulfonic acid (HEPES), 10?3 mol dm?3) in the presence of a family of carboxylate ions was carried out. In the interaction of the anions with the surface of the solids, the response depends on the characteristics of the binding groups (i.e., imidazolium, urea and thiourea) at the pore outlets and their specific interaction with the corresponding anion. The interaction of long‐chain carboxylate ions with the binding sites at the surface of the solids resulted in a remarkable inhibition of the delivery of the dye. This inhibition was observed clearly for the dodecanoate anion, whereas the octanoate, decanoate, cholate, deoxycholate, glycodeoxycholate and taurocholate anions induced a certain pore blockage that varied according to the solid studied. The interaction of smaller anions, such as acetate, butanoate, hexanoate and octanoate, with the solids had no effect on the dye release process. The possible use of the gating system for the chromo‐fluorogenic detection of anionic surfactants through selective dye delivery inhibition was also explored. Molecular dynamic simulations that use force‐field methods have been made to theoretically study the capping carboxylate mechanism. The calculations are in agreement with the experimental results, thus allowing a representation of the dye delivery inhibition in the presence of long‐chain carboxylate ions. 相似文献
96.
97.
98.
We construct, assuming Jensen's principle ?, a one-dimensional locally connected hereditarily separable continuum without convergent sequences. 相似文献
99.
Sergio Peris Bartosz Tylkowski Joan Carles Ronda Ricard Garcia‐Valls José Antonio Reina Marta Giamberini 《Journal of polymer science. Part A, Polymer chemistry》2009,47(20):5426-5436
Two new polyethers, bearing azobenzene moiety in the side chain, were synthesized in excellent yields by means of anionic polymerization of 4‐glycidyloxyazobenzene and 4‐cyano‐4′‐glycidyloxyazobenzene (leading to azo‐P1 and azo‐P2 polymers, respectively) with the system polyiminophosphazene base t‐Bu‐P4/3,5‐di‐tert‐butylphenol as initiator. The polymers were characterized with respect to their molecular weights, structure, and calorimetric features. The polyether bearing cyanoazobenzene group in the side chain was found to exhibit nematic phase up to 200 °C. E–Z isomerization of both polymers in tetrahydrofuran solution, after irradiating with UV light at 364 nm for 15 min, was investigated by means of UV–visible absorption spectroscopy. In the case of glycidylic monomers as well as the resulting polymers, E–Z isomerization was also investigated by means of 1H NMR, by direct irradiation in the NMR probe in deuterated 1,1,2,2‐tetrachloroethane solution. By this technique, in the case of 4‐cyano‐4′‐glycidyloxyazobenzene, it was found that irradiation led to a photostationary state corresponding to an amount of Z isomer equal to 25%. For azo‐P1 polymer, Z–E or “reverse” isomerization was investigated at 60, 70, or 80 °C directly in the NMR probe; as expected, the process followed a first‐order rate law. The kinetic constants as well as the activation energy for the process were determined in this temperature range. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5426–5436, 2009 相似文献
100.
In this paper we prove that the equational class generated by bounded BCK‐algebras is the variety generated by the class of finite simple bounded BCK‐algebras. To obtain these results we prove that every simple algebra in the equational class generated by bounded BCK‐algebras is also a relatively simple bounded BCK‐algebra. Moreover, we show that every simple bounded BCK‐algebra can be embedded into a simple integral commutative bounded residuated lattice. We extend our main results to some richer subreducts of the class of integral commutative bounded residuated lattices and to the involutive case. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献