Fe3O4/g-C3N4磁性固相萃取湖水中的3种苯甲酰脲杀虫剂

建立了Fe3O4/g-C3N4磁性固相萃取,结合高效液相色谱-可变波长紫外检测,用于测定湖水中3种苯甲酰脲杀虫剂的新方法.实验考察了溶液pH、离子强度、吸附剂用量、吸附时间、洗脱溶剂种类和体积对3种目标物回收率的影响.在最优实验条件下,氟铃脲和虱螨脲在0.50～500 ng/mL(r≥0.9997)、氟啶脲在0.20～...     

一类催化抑制系统反应扩散方程的奇摄动(英文)

研究了一类奇摄动非线性催化抑制系统反应扩散方程.在适当的条件下,首先求出了原问题的外部解,然后利用伸长变量、多重尺度和幂级数展开理论构造出解的形式渐近展开式最后利用微分不等式理论讨论了问题解的一致有效性和渐近性态.     

大尺度三维几何尺寸立体视觉测量系统实现

基于立体视觉的大尺度三维几何尺寸测量技术是对外形不规则的大型物体进行几何量测量的有效方法。与传统的视觉测量技术不同,大尺度视觉测量的精度随测量距离的增加而迅速下降,同时大尺度空间下照明条件难以控制,也使得测量变得不稳定。因此如何在大测量尺度的前提下提高测量精度成为这一领域的研究难点。从立体视觉测量系统的原理出发,分析了影响系统精度的各种因素,将相位一致性变换与极线约束条件引入结构光光条中心提取之中,显著提高了图像分析的精度。研制了测量系统的样机并给出了实验结果,现场测试表明该系统可以有效地保证大尺度条件下的测量精度。     

含分数阶Bingham模型的阻尼减振系统时滞半主动控制

针对基于磁流变液阻尼器的半主动控制系统中存在的时滞问题, 采用了一种将可控的时滞变量引入半主动控制切换条件的控制策略, 研究了考虑时滞的天棚阻尼控制切换条件对半主动阻尼减振系统的影响, 分析了含有分数阶Bingham模型的线性刚度系统在基础激励下的振动特性. 利用平均法得到了系统在含时滞半主动控制策略下主共振响应的近似解析解, 根据Lyapunov理论分析了系统的稳定性. 通过数值解验证了近似解析解的准确性, 二者具有较好的一致性. 利用近似解析解分析了固定激励频率下时滞对系统幅频响应特性的影响, 以及主共振峰值响应和共振频率随时滞变化的特性规律. 结果表明, 含时滞的半主动控制系统存在一个小时滞区间, 使得系统的振幅在主共振峰对应的频率附近低于不考虑时滞时系统的振幅, 且存在最优时滞使得系统的振幅大幅度降低; 而大时滞的引入会加剧系统的振动, 导致系统的颤振. 确定了基于分数阶Bingham模型的线性刚度系统在天棚阻尼半主动控制下的时滞选取原则, 为振动系统半主动阻尼控制中的时滞选取提供了参考.      

Negative thermal expansion: Mechanisms and materials

Negative thermal expansion (NTE) of materials is an intriguing phenomenon challenging the concept of traditional lattice dynamics and of importance for a variety of applications. Progresses in this field develop markedly and update continuously our knowledge on the NTE behavior of materials. In this article, we review the most recent understandings on the underlying mechanisms (anharmonic phonon vibration, magnetovolume effect, ferroelectrorestriction and charge transfer) of thermal shrinkage and the development of NTE materials under each mechanism from both the theoretical and experimental aspects. Besides the low frequency optical phonons which are usually accepted as the origins of NTE in framework structures, NTE driven by acoustic phonons and the interplay between anisotropic elasticity and phonons are stressed. Based on the data documented, some problems affecting applications of NTE materials are discussed and strategies for discovering and design novel framework structured NET materials are also presented.     

The Singularly Perturbed Boundary Value Problems for Semilinear Elliptic Equation

The singularly perturbed boundary value problems for the semilinear elliptic equation are considered. Under suitable conditions and by using the fixed point theorem, the existence, uniqueness and asymptotic behavior of solution for the boundary value problems are studied.     

一类半线性椭圆型方程奇摄动Robin边值问题

The singularly perturbed Robin boundary value problems for the semilinear elliptic equation are considered. Under suitable conditions and by using the fixed point theorem the existence ,uniqueness and asymptotic behavior of solution for the boundary value problems are studied.     

The singularly perturbed problem for combustion reaction diffusion

1. IntroductionThe anchor discussed a class of problems for the nonlinear ordinary differential equations(of. [1-3]) and the reaction dimsion equations (of. [4-7]).Now we consider a model of the combustion reaction decision problem as follows:where y is a density of combustion flame, s denotes the rate of diffusion effect for reactionspeed, whiCh is a small positive parameter, t is a position of combustion, functions y - t andy t are the positions of the matter for fuel and chide respectivel…     

π-π interactions in the self-assembly of melamine and barbituric acid derivatives

Self-assembly of a pair of complementary molecular components, 5-(4-dodecyloxyben-zylidene)-(1H,3H)-2, 4,6-pyrimidinetrione (PB₁₂)and 4-amino-2,6-didodecylamino-1, 3, 5-triazine (M₁₂) was studied by cyclic voltammogram, surface photovoltage spectroscopy, fluorescence spectroscopy, FTIR and X-ray diffraction. It is found that after mixing equimolar amount of PB₁₂ and M₁₂ at room temperature, not only triply complementary hydrogen bonds are formed between PB₁₂and M₁₂ but also further self-assembly of the supermolecules based on network of hydrogen bonds occurs via π-π interactions. During the self-assembly of the supermolecules, π -π interactions are induced by delocalized interactions between the HOMO of M₁₂ and the LUMO of PB₁₂, resulting in the formation of a supramolecular nanotube with a layered structure bearing a d value of 0.41 nm and PB₁₂ and M₁₂are arranged alternatively between adjacent supermolecules.     

奇摄动燃烧反应扩散问题

本文讨论了一类奇摄动燃烧反应扩用Ｒｏｂｉｎ问题,利用微分不等式理论,证明了问题解的存在性等式并得到了解的斩近估计。