水热合成超分子网络化合物[Mn(phen)_2I_2] (phen=邻菲咯啉)及晶体结构

采用水热法设计并合成了一个新颖的超分子网络化合物[Mn(phen)_2I_2],并对其进行了元素分析,红外光谱分析和X-射线单晶衍射分析.结果表明:该化合物属三斜晶系, P_1~-空间群,晶胞参数为:a=0.92705(19) nm,b=1.0370(2) nm,c=1.2775(3) nm,α=77.32(3) °,β=81.26 (3) °,γ=70.30(3) °,V=1.1240(4) nm~3,Z= 2.该化合物通过四种C-H...I氢键相互作用与两种π-π堆积相互作用把各个独立的结构单元连接成了超分子网络化合物.     

斜坡应力分布的系统测试与反演分析

采用简易、快速、经济的洞壁应力恢复法对某工程边坡勘探平硐洞壁应力场作了系统测试, 并采用FLAC^2D软件对测试成果作了斜坡初始应力的反演分析。结果表明, 斜坡应力场随深度变化具有明显分带性, 应力量值随硐深曲线具有典型的驼峰式特征, 与理论分析结果相符, 表明该方法能较好地应用于斜坡应力场的系统测试和研究。成果对认识斜坡岩体的变形破裂及卸荷特征等具有重要意义。     

A Novel Deterministic Quantum Communication Scheme Using Stabilizer Quantum Code

Exploiting the encoding process of the stabilizer quantum code [[n, k, d]], a deterministic quantum communication scheme, in which n - 1 photons are distributed forward and backward in two-way channel, is proposed to transmit the secret messages with unconditional security. The present scheme can be implemented to distribute the secret quantum （or classical） messages with great capacity in imperfect quantum channel since the utilized code encodes k-qubit messages for each scheme run.     

Groupoids,Discrete Mechanics,and Discrete Variation

After introducing some of the basic definitions and results from the theory of groupoid and Lie algebroid, we investigate the discrete Lagrangian mechanics from the viewpoint of groupoid theory and give the connection between groupoids variation and the methods of the first and second discrete variational principles.     

Cooperative Effects of Noise and Coupling on Stochastic Dynamics of a Membrane-Bulk Coupling Model

Based on a membrane-bulk coupling cell model proposed by Gomez-Marin et al. [ Phys. Rev. Lett. 98 （2007） 168303], the cooperative effects of noise and coupling on the stochastic dynamical behavior are investigated. For parameters in a certain region, the oscillation can be induced by the cooperative effect of noise and coupling. Whether considering the coupling or not, corresponding coherence resonance phenomena are observed. Furthermore, the effects of two coupling parameters, cell size L and coupling intensity k, on the noise-induced oscillation of membranes are studied. Contrary effects of noise are found in and out of the deterministic oscillatory regions.     

Mei Symmetry and Mei Conserved Quantity for a Non-holonomic Systemof Non-Chetaev's Type with Unilateral Constraints in Nielsen Style

Mei symmetry and Mei conserved quantity for a non-holonomic system of non-Chetaev's type with unilateral constraints in the Nielsen style are studied. The differential equations of motion for the system above are established. The definition and the criteria of Mei symmetry, conditions, and expressions of Mei conserved quantity deduced directly from the Mei symmetry are given. An example is given to illustrate the application of the results.     

基于统计最优和波叠加的联合局部近场声全息

提出了一种基于统计最优近场声全息和波叠加法的联合局部近场声全息技术。首先利用两次统计最优近场声全息的声源定位结果来指导配置等效源,其后利用波叠加法进行局部声场重构。该技术适合于中低频声场的局部重建,计算快速,重建精度高;可以在测量数据有缺失的情况下重建声场。进行了脉动球声源模型的数值仿真,并在半消声室内对电机噪声源进行了实验,仿真实验都准确地重构了声源所辐射的外部声场。该技术可以重建任意类球形声源辐射的声场。      

Study on the radial jet velocity distribution of two closely spaced opposed jets

The experimental and theoretical researches on the radial jet of two opposed jets have been carried out in this paper. The radial velocities of opposed jets with various exit velocities, nozzle diameters and nozzle separations were measured experimentally by a hot-wire anemometer (HWA). The results show that, the normalized radial velocities are self-similar across various radial sections at r ? 1.5D and the radial velocity profiles can be described by a Gaussian distribution function. The half-width increases linearly with increasing radial distance at r ? 1.5D, and spreading rates of radial jet are about 0.121. The normalized radial velocity at impingement plane increases firstly, and then decreases with the increasing normalized radial distance. The normalized radial velocity is independent on nozzle diameter, nozzle separation and exit velocity. The maximum radial velocity at impingement plane is proportional to the exit velocity, and it is inversely proportional to the 0.551th power of the normalized nozzle separation. The position of the maximum radial velocity increases with the nozzle separation at L/D < 1, and keeps invariant at L/D ? 1.     

翡翠贻贝珍珠层的XRD和FTIR光谱特征

对翡翠贻贝贝壳的珍珠层、棱柱层进行了XRD和FTIR光谱检测,对文石的ν₁,ν₂及ν₄三个内振动模式的频率进行了分析。文石的ν₁和ν₄带在所有的样品中不存在频率位移现象,与洞穴文石的相关谱带的频率一致;ν₂带频率却存在较大差异,珍珠层、棱柱层的ν₂带存在频率位移,初步推测生物合成文石与热效应有关,内部储存有过剩的能量,可作为研究生物矿化机理的实验依据。     

立方氮化硼单晶紫外吸收光谱的研究

对于在高温、高压下合成的人工立方氮化硼(cBN)片状单晶进行了紫外吸收光谱和第一性原理的能带结构研究。实验中采用了UV WINLAB光谱分析仪,数据分析由MOLECULAR SPECTROSCOPY软件进行拟合运算,通过特殊的石英夹具对样品的测试表明cBN的紫外吸收波长限为198 nm,带隙为6.26 eV。结合第一性原理计算的cBN的能带结构和电子态密度的计算,可以证实导致紫外光吸收的过程是价带电子吸收光子到导带的间接跃迁。文章实验结果与目前报道的cBN能带结构中禁带宽度的吻合较好,表明cBN具有良好的紫外特性,是一种具有发展前景的紫外光电和高温半导体器件材料。