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Ali Osman Ayaş Mustafa Akyol Selda Kılıç Çetin Melike Kaya İlker Dinçer Ahmet Ekicibil 《哲学杂志》2013,93(9):671-682
AbstractIn this work, we have studied on double-layered perovskite (Ruddlesden–Popper) manganite structure in Pr1.75Sr1.25Mn2O7 synthesised by sol–gel method. The crystal structure of the double-layered perovskite is found as tetragonal from the X-ray diffraction analysis with I4/mmm space group. A high Curie temperature, TC = 305 K is observed from the temperature dependence of magnetisation measurement. The isothermal magnetisation curves showed that magnetic phase transition is second order due to the positive slope of the Arrott plots. Maximum magnetic entropy change (ΔSM) and adiabatic temperature change (ΔTad) values are calculated as 3.99 J kg?1 K?1 and 2.1 K under external magnetic field of 70 kOe, respectively. Since our double-layered perovskite manganite sample has desired TC value and relatively high ΔSM, it can be a potential candidate as a magnetocaloric material for room temperature magnetic cooling systems. 相似文献
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Selda Kabatas Paola Agüi‐Gonzalez Kim‐Ann Saal Sebastian Jhne Felipe Opazo Silvio O. Rizzoli Nhu T. N. Phan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(11):3476-3481
Boron has been employed in materials science as a marker for imaging specific structures by electron energy loss spectroscopy (EELS) or secondary ion mass spectrometry (SIMS). It has a strong potential in biological analyses as well; however, the specific coupling of a sufficient number of boron atoms to a biological structure has proven challenging. Herein, we synthesize tags containing closo‐1,2‐dicarbadodecaborane, coupled to soluble peptides, which were integrated in specific proteins by click chemistry in mammalian cells and were also coupled to nanobodies for use in immunocytochemistry experiments. The tags were fully functional in biological samples, as demonstrated by nanoSIMS imaging of cell cultures. The boron signal revealed the protein of interest, while other SIMS channels were used for imaging different positive ions, such as the cellular metal ions. This allows, for the first time, the simultaneous imaging of such ions with a protein of interest and will enable new biological applications in the SIMS field. 相似文献
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We consider a weighted difference scheme approximating the heat equation with the nonlocal boundary conditions . We show that in this case the system of eigenfunctions of the main difference operator is not a basis but can be supplemented with associated functions to form a basis. Using the method of expansions in the basis of eigenfunctions and associated functions, we find a necessary and sufficient condition for stability with respect to the initial data in some energy norm. We show that this stability condition cannot be weakened by choosing a different norm. The above-mentioned energy norm is shown to be equivalent to the grid L 2-norm.
相似文献
$$u(0,t) = 0, \frac{{\partial u}}{{\partial x}}(0,t) + \frac{{\partial u}}{{\partial x}}(1,t) = 0$$
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In this study, we shall suggest analytical expressions for two-center nuclear attraction integrals over STO’s with a one-center
charge distribution by using Fourier transform method. The derivation is based on partial-fraction decompositions and Taylor
expansions of rational functions. Analytical expressions obtained by this method are expressed in terms of Gegenbauer, and
binomial coefficients and linear combinations of STO’s. Finally, it is relatively easy to express the Fourier integral representations
of two-center nuclear attraction integrals with a one-center charge distribution mentioned above as finite and infinite of
series of STO’s and irregular solid harmonics which may be considered to be limiting cases of STO’s. 相似文献
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Kazaryan P. S. Kharitonova E. P. Makaev S. V. Gulin A. A. Kondratenko M. S. 《Doklady Physical Chemistry》2021,497(1):28-33
Doklady Physical Chemistry - The study addresses the relationship between the omniphobic properties of coatings based on polymer matrices doped with liquid lubricants (Slippery Liquid-Infused... 相似文献
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S. B. Gulin Yu S. Gorelov I. G. Sidorov V. Yu Proskurnin 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(2):855-860
A modified method has been developed for measuring the 234Th concentration in seawater, which is based upon the use of MnO2-impregnated disk mini adsorbers with radial flow connected in-line and the direct beta counting of 234Th and/or its daughter 234mPa. This allows determining the 234Th concentration in a relatively small volume of seawater (20–50 L) with the possibility to check the extraction efficiency in every individual sample. The field testing, which was carried out at different areas of Sevastopol Bay during different seasons, has shown applicability of the proposed method to evaluate particle fluxes in marine environments within a wide range of concentrations of suspended matter. 相似文献