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Pei Li Jiang Hong Liu Ting Kwok Wong Hak Ping Yiu Jun Gau 《Journal of polymer science. Part A, Polymer chemistry》1997,35(16):3585-3593
Surface-functionalized cationic poly(methylstyrene) (PMS) latex particles containing aldehyde and carboxylic acid groups were successfully achieved via an emulsion polymerization of 3(4)-methylstyrene in the presence of cetyltrimethylammonium bromide, followed by an in-situ oxidation catalyzed by copper chloride and tert-butyl hydroperoxide (t-BuOOH). Factors such as the type of metal catalyst, oxidant, and their concentration strongly affected the rate of oxidation. Step addition of t-BuOOH resulted in both a higher degree of oxidation and a more uniform distribution of particle size of the functionalized PMS as compared to the batch addition method. The effect of organic solvent was found to be insignificant, and the oxidation could still proceed in its absence. The particle sizes increased significantly during the oxidation but could be controlled by using crosslinked PMS latexes. Finally, the versatility of this oxidation process was demonstrated by oxidation of the polymer with a solid loading as high as 28%. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35 : 3585–3593, 1997 相似文献
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Birane Fall AbdelAziz Jalil Michael Gau Sumanth Chereddy Michael J. Zdilla Stephanie L. Wunder Parameswara Rao Chinnam 《Ionics》2018,24(2):343-349
A soft solid crystal composed of isoquinoline (IQ) and LiCl was prepared based on the concept of Pearson’s hard-soft acid-base (HSAB) theory. Single-crystal X-ray diffraction best described the isoquinoline3?(LiCl)2 as consisting of molecular Li4Cl4(isoquinoline)6 units, where the LiCl cluster is an array of edge-fused Li2Cl2 rhombs. Electrochemical impedance measurements on pressed pellets showed that conductivity occurs mainly through the bulk via a hopping mechanism, with a calculated activation energy of Ea = 67 kJ/mol. The high value of the activation energy was due to Li4Cl4 clusters that were well separated by intervening IQ ligands in the crystal structure, requiring large hops for ions to migrate through the lattice. 相似文献
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Phytochemical examination on the leaves of Ilex cornuta Lindl. (Aquifoliaceae) resulted in the isolation and identification of lupeol (I), 3β-hydroxylup-20(29)-en-30-al (II), oleanolic acid (III), and β-sitosterol-β-D-glucoside (IV). 相似文献
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