全文获取类型
收费全文 | 518篇 |
免费 | 13篇 |
国内免费 | 3篇 |
专业分类
化学 | 356篇 |
晶体学 | 6篇 |
力学 | 11篇 |
数学 | 122篇 |
物理学 | 39篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 27篇 |
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 8篇 |
2016年 | 23篇 |
2015年 | 8篇 |
2014年 | 16篇 |
2013年 | 30篇 |
2012年 | 25篇 |
2011年 | 33篇 |
2010年 | 18篇 |
2009年 | 24篇 |
2008年 | 28篇 |
2007年 | 26篇 |
2006年 | 15篇 |
2005年 | 38篇 |
2004年 | 22篇 |
2003年 | 19篇 |
2002年 | 19篇 |
2001年 | 6篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
排序方式: 共有534条查询结果,搜索用时 78 毫秒
21.
Dr. Michael L. Lejkowski Dr. Ronald Lindner Dr. Takeharu Kageyama Dr. Gabriella É. Bódizs Dipl.‐Chem. Philipp N. Plessow Dr. Imke B. Müller Dr. Ansgar Schäfer Dr. Frank Rominger Prof. Dr. Peter Hofmann Dr. Cornelia Futter Dr. Stephan A. Schunk Dr. Michael Limbach 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(44):14017-14025
For more than three decades the catalytic synthesis of acrylates from the cheap and abundantly available C1 building block carbon dioxide and alkenes has been an unsolved problem in catalysis research, both in academia and industry. Herein, we describe a homogeneous catalyst based on nickel that permits the catalytic synthesis of the industrially highly relevant acrylate sodium acrylate from CO2, ethylene, and a base, as demonstrated, at this stage, by a turnover number of greater than 10 with respect to the metal. 相似文献
22.
Gabriella Tarantello 《Milan Journal of Mathematics》2016,84(2):269-298
In this note we discuss the solvability of Liouville-type systems in presence of singular sources, which arise from the study of non-abelian Chern Simons vortices in Gauge Field Theory and their asymptotic behaviour (for limiting values of the physical parameters). This investigation has contributed towards the understanding of singular PDE ’s in Mean Field form, in connection to surfaces with conical singularities, sharp Moser–Trudinger and log(HLS)-inequalities, bubbling phenomena and point-wise profile estimates in terms of Harnack type inequalities. We shall emphasise mostly the physical impact of the rigorous mathematical results established and mention several of the remaining open problems. 相似文献
23.
24.
Viviana De Luca Paolo Digiamberardino Giovanna Di Pasquale Salvatore Graziani Antonino Pollicino Elena Umana Maria Gabriella Xibilia 《Journal of Polymer Science.Polymer Physics》2013,51(9):699-734
Smart systems adapt to the surrounding environments in a number of ways. They are capable to scavenge energy from available sources, sense and elaborate external stimuli and adequately react. Electro Active Polymers are playing a main role in the realization of smart systems for applications if fields such as bio inspired and autonomous robotics, medicine, and aerospace. This paper focus on the possibility to use Ionic Polymer Metal Composites as a class of materials relevant to the realization of post silicon smart systems. The three main aspects of this new technology, i.e., fabrication methods, modeling, and applications are described with emphasis to most recent results. Attention is given to main challenges and shortcomings to be solved for technology, modelling, and control of IPMC based devices that need to be solved before this new technology can be fully exploited in real world applications. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013 相似文献
25.
26.
Paulo R. Olivato Mirta G. Mondino Giuseppe Distefano Maurizio Dal Colle Gabriella Bombieri Antonio Del Pra 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):443-444
ABSTRACT. The analysis of the carbonyl I.R. band and the U.V. phoelectron spectroscopic data along with the ab-initio calculations and X-ray diffraction of α-(methylsulfinyl)- and α-(phenylsulfinyl)-acetophenones indicated the predominance of the cis rotamers over the qauche ones. 相似文献
27.
Bianca Flavia Bonini Luca Bernardi Mauro Comes-Franchini Gabriella Dessole Mariafrancesca Fochi Alfredo Ricci 《Phosphorus, sulfur, and silicon and the related elements》2013,188(5-6):1273-1277
Abstract Enantiomerically pure 2-hydroxyalkyl, 2-aminoalkyl and 2-iminoalkyl ferrocenyl p-tolylsulfides are easily prepared in good yields and with complete diastereocontrol from (S)-(2-p-tolylthio)ferrocencarboxyaldehyde. 2-Iminoalkyl ferrocenyl derivatives can be used as ligands in asymmetric catalysis and as starting materials for asymmetric Staudinger reaction. 相似文献
28.
Edit Csapó Dániel Sebők Julia Makrai Babić Filip Šupljika Gabriella Bohus Imre Dékány 《Journal of Dispersion Science and Technology》2014,35(6):815-825
Gold nanoparticles reduced by sodium citrate (d ~ 10 nm) and purchased gold colloid particles (d ~ 500 nm) were examined and compared. The properties of both gold particles and their biofunctionalized derivatives with L-cysteine and L-glutathione were studied in the presence of sodium nitrate. The structural investigations indicated an aggregated inner structure. The isoelectric points of pure gold, citrate reduced gold, and functionalized gold were measured and compared. The low isoelectric point of pure gold/water interface was explained by considering the distribution and accumulation of H+ and OH? ions within the interfacial water layer, being more pronounced for OH? ions. 相似文献
29.
Francesca Sisto Simone Carradori Paolo Guglielmi Mattia Spano Daniela Secci Arianna Granese Anatoly P. Sobolev Rossella Grande Cristina Campestre Maria Carmela Di Marcantonio Gabriella Mincione 《Molecules (Basel, Switzerland)》2021,26(7)
Following a similar approach on carvacrol-based derivatives, we investigated the synthesis and the microbiological screening against eight strains of H. pylori, and the cytotoxic activity against human gastric adenocarcinoma (AGS) cells of a new series of ether compounds based on the structure of thymol. Structural analysis comprehended elemental analysis and 1H/13C/19F NMR spectra. The analysis of structure–activity relationships within this molecular library of 38 structurally-related compounds reported that some chemical modifications of the OH group of thymol led to broad-spectrum growth inhibition on all isolates. Preferred substitutions were benzyl groups compared to alkyl chains, and the specific presence of functional groups at para position of the benzyl moiety such as 4-CN and 4-Ph endowed the most anti-H. pylori activity toward all the strains with minimum inhibitory concentration (MIC) values up to 4 µg/mL. Poly-substitution on the benzyl ring was not essential. Moreover, several compounds characterized by the lowest minimum inhibitory concentration/minimum bactericidal concentration (MIC/MBC) values against H. pylori were also tested in order to verify a cytotoxic effect against AGS cells with respect to 5-fluorouracil and carvacrol. Three derivatives can be considered as new lead compounds alternative to current therapy to manage H. pylori infection, preventing the occurrence of severe gastric diseases. The present work confirms the possibility to use natural compounds as templates for the medicinal semi-synthesis. 相似文献
30.