A UNIFORMLY CONVERGENT DIFFERENCE SCHEME FOR THE SINGULAR PERTURBATION PROBLEM OF A HIGH ORDER ELLIPTIC DIFFERENTIAL EQUATION

ＡＵＮＩＦＯＲＭＬＹＣＯＮＶＥＲＧＥＮＴＤＩＦＦＥＲＥＮＣＥＳＣＨＥＭＥＦＯＲＴＨＥＳＩＮＧＵＬＡＲＰＥＲＴＵＲＢＡＴＩＯＮＰＲＯＢＬＥＭＯＦＡＨＩＧＨＯＲＤＥＲＥＬＬＩＰＴＩＣＤＩＦＦＥＲＥＮＴＩＡＬＥＱＵＡＴＩＯＮ（刘国庆）（苏煜城）ＡＵＮＩＦＯ...     

压电激励圆形曲梁的静态响应及位移控制

研究压电激励圆形曲梁的静态位移响应及位移控制的参数特性。将压电夹层圆形曲梁等效为单层结构,基于一维小曲率曲梁理论,建立其控制方程。在集中弯矩和径向集中力以及电载荷作用下,分析了带压电激励器的圆形悬臂曲梁的静态响应。与有限元结果比较表明:本文的理论模型能够模拟压电激励的小曲率圆形曲梁的静态响应。压电夹层圆形曲梁在任意位置的径向集中力载荷作用下,控制其自由端径向位移响应为零,求得控制电压的解析表达,数值分析表明:随着集中力载荷的位置变化和梁长的变化,最优控制电压将出现峰值和反号。     

TiO_2/Ag_2NCN复合光催化剂的制备与可见光催化性能

利用银盐与单氰胺水溶液的沉淀反应,通过共混不同质量分数的纳米TiO2粒子制备了TiO2/Ag2NCN复合光催化剂.使用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、傅里叶变换红外(FTIR)光谱仪和紫外-可见(UV-Vis)吸收光谱仪对复合光催化剂的结构进行了表征.结果表明,锐钛矿相TiO2纳米颗粒沉积在Ag2NCN表面形成异质结构,二者间以弱的物理作用力相结合.TiO2的掺杂使得复合颗粒的UV-Vis吸收光谱发生红移,带隙变窄.以亚甲基蓝(MB)为光催化降解对象,研究了TiO2/Ag2NCN复合颗粒的可见光催化活性.结果表明,与单一Ag2NCN相比,复合颗粒表现出增强的光催化性能.对TiO2/Ag2NCN复合颗粒的光催化反应动力学过程及光催化机理进行了探讨.     

Combination of Solid‐Phase Micro‐Extraction and Direct Analysis in Real Time‐Fourier Transform Ion Cyclotron Resonance Mass Spectrometry for Sensitive and Rapid Analysis of 15 Phthalate Plasticizers in Beverages

A method for rapid identification and quantification of phthalate plasticizers in beverages was developed. A number of 15 phthalate plasticizers which covered all the phthalates concerned in the US Consumer Product Safety Improvement Act (CPSIA), European Union legislations and Chinese national standards (GB) were analyzed. By a combined solid‐phase micro‐extraction (SPME) and direct analysis in real time mass spectrometry (DART‐MS) approach, phthalates at sub‐ng·mL^?1 levels can be qualitatively and quantitatively analyzed in a short time. The use of ultrahigh‐resolving power and the accurate mass measurement capacity naturally provided by Fourier transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS) minimizes the matrix interferences and thus enables the evaluation of phthalates in a complex matrix without extensive sample handlings or preparations. The limits of quantification (LOQs) were estimated to be at 0.3–5.0 ng·mL^?1, lower than the Maximum Residue Limit (MRL) regulated by the European Union legislations (2007/19/EC) in foods, beverages, food packaging and toys (0.3–30 ng·mL^?1). This rapid and easy‐to‐use SPME‐DART‐FT‐ICR‐MS method provided a relatively high‐throughput and powerful analytical approach for quick testing and screening phthalates in beverages and water samples to ensure food safety.     

贵金属负载的棒状ZnO复合光催化剂的制备及其提升的光催化性能

以水热制备的ZnO纳米棒为基底,通过乙二醇液相还原法负载不同贵金属颗粒(Pt、Pd、Ru)构筑贵金属负载的ZnO纳米棒复合光催化剂。实验结果表明在制备条件相同时,Pt/ZnO样品中Pt颗粒尺寸较小,分布均匀;Pd/ZnO样品中Pd颗粒尺寸较大且团聚严重;Ru/ZnO样品则几乎没有Ru颗粒负载。在紫外光照射下降解亚甲基蓝的反应中,Pt/ZnO表现出最高的光催化性能,Pd/ZnO样品次之,而Ru/ZnO则表现出与ZnO纳米棒相似的光催化活性;表明小尺寸和大小均匀的贵金属颗粒对ZnO纳米棒的催化性能有着显著的提升作用。对Pt/ZnO来说,当Pt载量为3.2%时Pt/ZnO催化剂的光催化活性最高。     

摩擦接触问题数学规划法的收敛性和算法的改进

对摩擦接触问题的数学规划法进行了收敛性分析，并对算法提出一种改进，对“较小”摩擦系数问题改进算法严格保证收敛。在“较大”摩擦系数情形，问题提法本身有可能发生解不唯一和不存在现象。     

接触问题的非线性互补－接触柔度法

基于势能互补原理，不引入额外松弛变量，对库仑摩擦定律未做预先线性化近似，提出了三维弹性摩擦接触问题的非线性互补－接触柔度法，收敛性和收敛速率得到了严格理论保证。数值实验结果表明方法可靠、有效、低存储量、高精度     

GENERAL SOLUTION OF PLANE PROBLEM OF PIEZOELECTRIC MEDIA EXPRESSED BY "HARMONIC FUNCTIONS

I.IntroductionBecauseofthecouplingcharacteristicbetweenthemechanicaldeformationandthee1ectricaleffect,piezoelectricmaterialshavebeenwidelyusedintransducersandsmartstructures.Moreandmoreattentionshavebeenpaidonsuchmaterials,andgreatadvanceshavebeenmadeinva…     

INTERACTION-MEDIATED GROWTH OF CARBON NANOTUBES ON ACICULAR SILICA-COATED α-Fe CATALYST BY CHEMICAL VAPOR DEPOSITION

Multi-walled carbon nanotubes (MWNTs) with 20 nm outer diameter were prepared by chemical vapor deposition of ethylene using ultrafine surface-modified acicular α-Fe catalyst particles.The growth mechanism of MWNTs on the larger catalyst particles are attributed to the interaction between the Fe nanoparticles with the surface-modified silica layer.This interaction-mediated growth mechanism is illustrated by studying the electronic,atomic and crystal properties of surface-modified catalysts and MWNTs products by characterization with X-ray diffraction (XRD),transmission electron microscopy (TEM),high resolution transmission electron microscopy (HRTEM),thermal gravimetric analysis (TGA) and Raman spectra.