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991.
The combustion characteristics of freely falling droplets, individually generated by the merging of colliding methanol and alkane droplets, were investigated and compared with those for pure methanol and alkanes. The merging of the nominally immiscible methanol and alkanes was manifested in an apparently adhesive, but unmixed, manner in all test conditions. An air bubble was found to be trapped at the colliding interfaces where they were “adhered,” with the trapping favored for head-on or near head-on collision orientations. The trapped air bubble ostensibly induced heterogeneous nucleation of the methanol, being facilitated by the relatively low limit of superheat of methanol. Consequently, the droplet exploded almost immediately upon ignition, leading to an extremely short overall lifetime. For collision orientations that were more off-centered, bubble trapping and thereby heterogeneous nucleation were not favored. However, delayed, albeit strong, microexplosion occurred through homogeneous nucleation of methanol at the contacting interface. The global burning rate was therefore again augmented. In general, microexplosion was facilitated for high-boiling-point alkanes such as hexadecane and tetradecane. The co-vaporization of methanol and alkane from their respective hemispherical segments constituting the adhered droplet also led to flame colors that were more bluish than yellowish, indicating the reduction of soot from alkane burning in the presence of methanol vapor. In light of the difficulty of forming stable methanol/oil emulsions, the potential of separate injection of oil and methanol in opposed jet arrangement, in direct-injection engines to facilitate collision, is suggested. 相似文献
992.
FuLinYAN AiXiaWANG ZhongJianJIA LeiHE 《中国化学快报》2003,14(12):1253-1254
A new isopropenyl benzofuran-type tetramer was isolated from the roots of ligularia stenocephala and its structure was established by spectroscopic methods. 相似文献
993.
Beam expanders being used presently have complex structure and none is perfect. A novel beam expander is proposed first. The beam expander can magnify (or decrease) the diameter of incident laser beam according to the theory of total internal reflection–refraction (TIR-R) principle. The characteristic of the beam expander was studied by using ray-tracing method and computer simulation. The beam expander can propagate a parallel laser beam along the propagation axis and would not change the propagation direction of the beam. For a nonparallel beam the Lagrange invariant (the product of diameter and divergence angle) is not constant. This beam expander would be an effective device in some applications. 相似文献
994.
Tetrabutylammonium or potassium salts of organometalllic derivatives of lacunary polyanion (RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn) have been prepared and structurally characterized by elemental analysis,IR,UV-Vis,^1H NMR and^183 W NMR spectroscopies.The title complexes exhibit antitumor activity in vitro. 相似文献
995.
辉光等离子体辅助化学气相沉积低温合成金刚石薄膜的研究 总被引:5,自引:0,他引:5
采用辉光放电等离子体增强化学气相沉积 (GP CVD)技术在低温条件下合成了高品质的亚微米金刚石薄膜 ,并通过对合成过程的实时发射光谱诊断确定了 [CH4 H2 ]系统参与金刚石合成反应的主要荷能粒子。对合成过程的研究表明 :采用这种技术能使电子增强热丝化学气相沉积 (EACVD)合成高品质金刚石薄膜的温度从 85 0℃降至 (340± 5 )℃ ;薄膜低温合成中的主要荷能粒子为CH3 、CH ,CH+ 、H 等 ,其中过饱和原子氢保证了高品质金刚石薄膜的合成 ;根据光诊断和探针测量的结果推断近表面辉光放电可在基片表面形成电偶极层 ,该偶极层是进行超常态反应的必要环境 ,并在低温合成中起重要作用 相似文献
996.
基于Takens的相空间延迟坐标重构,研究了用于混沌信号预测的三阶Volterra滤波器的一种乘积耦合近似实现结构,并应用于典型的低维混沌时间序列和具有高维混沌特性的EEG信号的预测.数值研究表明:这种滤波器结构对于低维混沌时间序列的预测精度可以比二阶Volterra滤波器提高103倍,而且能够较好地对一些具有高维混沌特性的EEG信号进行预测
关键词:
混沌
非线性自适应预测
三阶Volterra滤波器
electroencephalography信号 相似文献
997.
本文研究了n奎乙醇的合成方法.由于采用较高效率的相转移催化剂和乙醇一水作重结晶溶剂,得到高纯度,高产率的喳乙醇. 相似文献
998.
本文在实验室条件下对赤峰的两种褐煤进行了煤热解气化实验研究,考察了气化室温度和流化状态等实验条件变化对煤气产率,组分的影响,得到了具体条件下的煤气化综合过程实验数据。 相似文献
999.
Structure, electrical and chemical properties of zirconium nitride films deposited by dc reactive magnetron sputtering 总被引:1,自引:0,他引:1
D. Wu Z. Zhang D. Fu W. Fan H. Guo 《Applied Physics A: Materials Science & Processing》1997,64(6):593-595
2 and Ar ambient. X-ray diffraction indicated that growth of ZrN with a preferred (111) orientation over Si(100) was achieved.
The resistivity of the films varies from 200 μΩcm to 15 μΩcm depending on the N2 content in the working gas. The square resistance of the films deposited on 96% Al2O3 ceramic wafers is stable below 300 °C.
Received: 17 June 1996/Accepted: 9 December 1996 相似文献
1000.
Absolute rate constants for the additions of syn- and anti-2-thienylchlorocarbenes to various alkenes have been measured. The reactivity, selectivity, and structures of these species were characterized experimentally and computationally. 相似文献