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81.
The design and synthesis of amphiphilic nano- to micro-sized polymeric particles with core–shell nanostructures have attracted more and more attention because of their wide applicability in modern material science and their technological importance in the areas of colloid and interface science. Many synthetic strategies have been developed for the preparation of amphiphilic core–shell particles that consist of hydrophobic polymer cores and hydrophilic polymeric shells. In this review, we focus on emulsion-based approaches and properties of particles produced. These methods are: (1) grafting to functionalized particle that produces a corona-like particle, (2) grafting from reactive seed particle that produces a brush-like particle, (3) copolymerization of reactive macro-monomer with hydrophobic monomer that produces a corona-like particle, (4) emulsion polymerization in the presence of block or comb-like copolymer containing controlled free-radical moiety that produces a multi-layered particle, and (5) redox-initiated graft polymerization of vinyl monomer from a water-soluble polymer containing amino groups that produces a hairy-like particle. Potential applications of some of these particles in drug and gene deliveries, enzyme immobilization, colloidal nanocatalyst, chemical sensing, smart coating, and thermal laser imaging will be discussed. 相似文献
82.
Tsz Kin Tam Marcos Pita Mikhail Motornov Ihor Tokarev Sergiy Minko Evgeny Katz 《Electroanalysis》2010,22(1):35-40
The modified electrode functionalized with a mixed‐polymer brush composed of poly(2‐vinylpyridine) and polyacrylic acid tethered to the surface demonstrated switchable interfacial properties discriminating negatively and positively charged redox species. The switchable electrochemical process was characterized by differential pulse voltammetry and Faradaic impedance spectroscopy. The electrochemical system was discussed as a model of an electrochemical multiplexer with two chemical redox inputs, the pH input operating as the selecting signal and one electronic output signal readable by the impedance spectroscopy in the form of the interfacial resistance. The modified electrode represents a novel component for integration with biocatalytic and biocomputing systems aiming at biochemically and electronically controlled actuators. 相似文献
83.
Shih-sen Chang H.W. Joseph Lee Chi Kin Chan 《Nonlinear Analysis: Theory, Methods & Applications》2009
In this paper, we introduce a new iterative scheme for finding a common element of the set of solutions of an equilibrium problem, the set of common fixed point for a family of infinitely nonexpansive mappings and the set of solutions of the variational inequality for α-inverse-strongly monotone mappings in a Hilbert space. Under suitable conditions, some strong convergence theorems for approximating a common element of the above three sets are obtained. As applications, at the end of the paper we utilize our results to study the optimization problem and some convergence problem for strictly pseudocontractive mappings. The results presented in the paper extend and improve some recent results of Yao and Yao [Y.Y. Yao, J.C. Yao, On modified iterative method for nonexpansive mappings and monotone mappings, Appl. Math. Comput. 186 (2) (2007) 1551–1558], Plubtieng and Punpaeng [S. Plubtieng, R. Punpaeng, A new iterative method for equilibrium problems and fixed point problems of nonlinear mappings and monotone mappings, Appl. Math. Comput. (2007) doi:10.1016/j.amc.2007.07.075], S. Takahashi and W. Takahashi [S. Takahashi, W. Takahashi, Viscosity approximation methods for Equilibrium problems and fixed point problems in Hilbert spaces, J. Math. Anal. Appl. 331 (2006) 506–515], Su, Shang and Qin [Y.F. Su, M.J. Shang, X.L. Qin, An iterative method of solution for equilibrium and optimization problems, Nonlinear Anal. (2007) doi:10.1016/j.na.2007.08.045] and Chang, Cho and Kim [S.S. Chang, Y.J. Cho, J.K. Kim, Approximation methods of solutions for equilibrium problem in Hilbert spaces, Dynam. Systems Appl. (in print)]. 相似文献
84.
Man KY Wong HL Chan WK Djurisić AB Beach E Rozeveld S 《Langmuir : the ACS journal of surfaces and colloids》2006,22(7):3368-3375
Multilayer polymer films composed of a ruthenium terpyridine complex containing poly(p-phenylenevinylene) (Ru-PPV) and sulfonated polyaniline (SPAN) were prepared by a layer-by-layer electrostatic self-assembly deposition. The deposition process was carried out from SPAN solution in water and Ru-PPV in dimethylformamide (DMF). Optical-quality multilayer thin films were obtained. The film growth process was monitored by quartz crystal microbalance, and the surface morphology of the films was studied by atomic force microscopy. It was found that the properties of the multilayer films were dependent on deposition conditions such as the pH of the SPAN solution, the presence of salt in the polymer solutions, and the post-film-forming thermal annealing process. Cross-section transmission electron microscopic images suggested that there was no stratified structure formed in the multilayer films. Photovoltaic cells were fabricated by sandwiching the multilayer films between indium-tin-oxide and aluminum electrodes. The device performances were examined by illumination with AM 1.5 simulated solar light. The power conversion efficiencies of these devices were on the order of 10(-3)%. The maximum incident photon-to-electron conversion efficiency (IPCE) of the devices was found to be approximately 2% at 510 nm, which is consistent with the absorption maximum of the ruthenium complex. This indicates that the photosensitization process is due to the electronic excitation of the ruthenium complex. 相似文献
85.
Man Kin Tse Gopinathan Anilkumar Feyissa Gadissa Gelalcha 《Journal of organometallic chemistry》2006,691(21):4419-4433
Various Ru(L1)(L2) (1) complexes (L1 = 2,2′-bipyridines, 2,2′:6′,2″-terpyridines, 6-(4S)-4-phenyl-4,5-dihydro-oxazol-2-yl-2,2′-bipyridinyl or 2,2′-bipyridinyl-6-carboxylate; L2 = pyridine-2,6-dicarboxylate, pyridine-2-carboxylate or 2,2′-bipyridinyl-6-carboxylate) have been synthesized (or in situ generated) and tested on epoxidation of olefins utilizing 30% aqueous H2O2. The complexes containing pyridine-2,6-dicarboxylate show extraordinarily high catalytic activity. Based on the stereoselective performance of chiral ruthenium complexes containing non-racemic 2,2′-bipyridines including 6-[(4S)-4-phenyl-4,5-dihydro-oxazol-2-yl]-[2,2′]bipyridinyl new insights on the reaction intermediates and reaction pathway of the ruthenium-catalyzed enantioselective epoxidation are proposed. In addition, a simplified protocol for epoxidation of olefins using urea hydrogen peroxide complex as oxidizing agent has been developed. 相似文献
86.
Sunintaboon P Ho KM Li P Cheng SZ Harris FW 《Journal of the American Chemical Society》2006,128(7):2168-2169
A new, simplified route to amphiphilic core-shell nanotubes, microfibers, and microrods has been developed that does not involve the traditional utilization of well-defined block copolymers. Thus, amphiphilic graft copolymers (PEI-g-PMMA) are prepared by an aqueous free radical polymerization that self-assemble in situ to form uniform core-shell nanoparticles. The hydrophobic homopolymer (PMMA) that is also formed is incorporated in the cores. Slight cross-linking of the shells followed by extraction of the homopolymer results in hollow nanoparticles that coalesce to form nanotubes. When the shells are not cross-linked, the hollow particles coalesce to form microrods and microfibers. The sizes and shapes of the micromaterials can be controlled by varying the experimental conditions. 相似文献
87.
Lam KL Ishitsuka Y Cheng Y Chien K Waring AJ Lehrer RI Lee KY 《The journal of physical chemistry. B》2006,110(42):21282-21286
While pore formation has been suggested as an important step in the membrane disruption process induced by antimicrobial peptides, membrane pore formation has never been directly visualized. We report on the dynamics of membrane disruption by antimicrobial peptide protegrin-1 (PG-1) on dimyristoyl-sn-glycero-phosphocholine-supported bilayer patches obtained via atomic force microscopy. The action of PG-1 is found to be concentration-dependent. At low PG-1 concentrations (1 < [PG-1] < 4 microg/mL), the peptide destabilizes the edge of the membrane to form fingerlike structures. At higher concentrations, PG-1 induces the formation of a sievelike nanoporous structure in the membrane. The highest degree of disruption is attained at concentrations >or=20 microg/mL, at which PG-1 disrupts the entire membrane, transforming it into stripelike structures with a well-defined and uniform stripe width. This first direct visualization of these membrane structural transformations helps elucidate the PG-1-induced membrane disruption mechanism. 相似文献
88.
Chris S. K. Mak Qing Yun Leung Chi Ho Li Wai Kin Chan 《Journal of polymer science. Part A, Polymer chemistry》2010,48(11):2311-2319
Low‐bandgap rhenium(I) complex with absorption onset at 795 nm in solution was tethered onto π‐conjugated polymer. The conjugated copolymer provides solution processability of the metallopolymer, and the pendant allows the low energy‐absorbing Re(I) complex units to be evenly distributed on the thin film. The copolymer tethered with low‐bandgap rhenium complex was synthesized by Suzuki cross‐coupling reaction. The metal‐free polymer ( poly‐1 ) tethered with functionalized intramolecular charge transfer dye, 2‐phenyl‐3‐pyridin‐2‐yl‐5,7‐di‐2‐thienylthieno[3,4‐b]pyrazine, exhibited high molecular weight, good film‐forming properties, and excellent solution processability. The pendants of the conjugated polymer possess donor–acceptor characters and broaden the absorption band. These pendants can function as bidentate ligands for metal chelation. The solubilizing groups on the monomers provide good solubility to the polymer even with high content of metal chelation. Upon the complexation with rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting metallopolymer was further extended toward the near‐infrared region. Photovoltaic performances based on this metallopolymer have been studied. The design approach of these metallopolymers provides synthetic feasibility for coordinating wide range of metal ions on the pendant, and the resulting low‐bandgap polymer can be a potential candidate for light harvesting material in solar cell applications. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2311–2319, 2010 相似文献
89.
The determination of membrane-substrate profile for adherent vesicle using confocal reflectance interference contrast microscopy (C-RICM) has pushed for the need of advanced mechanics model for interpreting adhesion mechanisms. In this work, a model for vesicles or cells adhesion is established, the governing equation is derived from the variation of the potential energy at the cohesive zone. A closed-form solution is found for vesicle spontaneously adheres to a substrate when its shear modulus, micro vanishes. Based on the model and C-RICM experiments the magnitude of the adhesion force is calculated for a lipid vesicle adheres to a glass substrate. 相似文献
90.
Feng Shi Man Kin Tse Matthias Beller 《Journal of molecular catalysis. A, Chemical》2007,270(1-2):68-75
The selective oxidation of naphthalene and its derivatives to give naphthoquinones has been investigated in detail. The reaction can be carried out effectively in the presence of a catalytic amount of Ru complexes (0.2 mol%) and phase transfer catalysts (PTC) using H2O2 as the terminal oxidant and water as the solvent. The effect of different ruthenium complexes, phase transfer catalysts, and the concentration of hydrogen peroxide were studied. Compared to previous procedures for this type of reactions, acidic solvents and high concentration of hydrogen peroxide are not necessary, which makes the reaction more environmentally friendly. 相似文献