排序方式: 共有58条查询结果,搜索用时 296 毫秒
11.
CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献
12.
John W.Grove 《数学物理学报(B辑英文版)》2010,30(2):563-594
This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described. 相似文献
13.
Dainis Dakternieks Andrew Duthie Douglas R. Smyth Clynton P. D. Stapleton Edward R. T. Tiekink 《应用有机金属化学》2004,18(1):53-54
The tin atom in the title compound is in a distorted pentagonal bipyramidal geometry defined by two sets of nitrogen and oxygen donors derived from the carboxylate ligands, two carbon atoms from the cyclohexyl substituents and an oxygen atom from the coordinated water molecule; C? Sn? C 170.85(15)°. Extensive hydrogen bonding occurs in the lattice. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
14.
15.
The title compound was prepared by base hydrolysis of (p‐MeOC6H4)2SeCl2 in water and isolated as the crystalline monohydrate, (p‐MeOC6H4)2SeO·H2O, in which the water molecule is associated via hydrogen‐bonding. Water‐free (p‐MeOC6H4)2SeO was obtained crystalline after drying and recrystallisation from toluene. Both crystal phases were investigated by single crystal X‐ray diffraction. Preliminary DFT calculations at the B3LYP/LANL2DZdp level of theory suggest that the hydrogen bonded complexes R2SeO·H2O (R = H, Me, Ph) are by 2.79, 3.36 and 11.10 kcal mol?1 more stable than the corresponding elusive diorganoselenium dihydroxides R2Se(OH)2. The hydrogen bond energies of R2SeO·H2O (R = H, Me, Ph) are 5.98, 7.18 and 5.89 kcal mol?1. 相似文献
16.
17.
Ratnamma Pasar Pallavi MS Harischandra Naik R Devaraj M Nandini P Bheemanna M Badariprasad P R Paramasivam M 《Journal of separation science》2022,45(11):1831-1838
This study presents the method development, validation, and simultaneous determination of dimethoate and its metabolite omethoate in curry leaf. Samples were extracted following modified quick, easy, cheap, effective, rugged, and safe extraction protocol and analyzed using liquid chromatography-tandem mass spectrometry. The limit of quantification in the matrix was 0.005 μg g−1 for dimethoate and omethoate. Extraction using acetonitrile recorded the average recoveries in the range of 82.25 to 112.97% for dimethoate and 85.57 to 107.22% for omethoate at 0.005, 0.025 and 0.050 μg g−1 fortification levels and relative standard deviation less than 5%. Similarly, the relative standard deviation values for intraday (Repeatability) and interday (Reproducibility) tests were less than 15%. Dissipation kinetics of dimethoate 30% emulsifiable concentrate at 200 and 400 g a.i h−1 recorded initial deposits of 5.20 and 10.05 μg g−1 and 0.33 and 0.48 μg g−1 for dimethoate and omethoate, respectively, and half-life of 3.07 and 3.34 days. The estimated hazard index value found more than one at a day after dimethoate application. It is not safe for consumer health to use curry leaves in the initial days after application. 相似文献
18.
19.
An ‘S’ conformation, stabilized by intramolecular C? H···π interactions, is found in centrosymmetric p‐(Cl2PhSnCH2CH2)2C6H4. The dinuclear species features distorted tetrahedral tin centres, with the greatest distortion manifested in the C? Sn? C angle of 134.32(16) °. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
20.
Monique Biesemans Andrew Duthie Klaus Jurkschat Ingrid Verbruggen Rudolph Willem Bernhard Zobel 《应用有机金属化学》2003,17(5):298-304
The reaction of the 2,2‐bis(organodichlorostannyl)propane [(Me3Si)2CH(Cl2)Sn]2CMe2 (A) with the corresponding organotin oxide {[(Me3Si)2CH(O)Sn]2CMe2}2 (B) does not provide the corresponding normally expected tetraorganodistannoxane {[(Me3Si)2CH(Cl)SnCMe2Sn(Cl)CH(SiMe3)2]O}n but a complex reaction mixture. One major product, namely the 2,4,6,8‐tetraorgano‐2,6‐dichloro‐1,5,9‐trioxa‐2,4,6,8‐tetrastannabicyclo[3.3.1]nonane derivative [(Me3Si)2CHSnCMe2Sn(Cl)CH(SiMe3)2]2O3 (C) was identified in situ by 2D 1H? 119Sn and 1H? 13C heteronuclear multiple quantum coherence and heteronuclear multiple bond correlation NMR spectroscopy as well as electrospray mass spectrometry. Compound C is proposed to be in equilibrium with an ionic species C′, the cation of which has an adamantane‐type structure. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献