Synthesis of Ultrahigh‐Molecular‐Weight Ethylene‐1‐Hexene Copolymers with High Hexene Content via Living Polymerization with Fluorinated Bis(phenoxy–imine) Titanium(IV)

The fluorinated FI–Ti catalyst bis[N‐(3‐propylsalicylidene)‐pentafluoroanilinato] titanium(IV) dichloride (PFI) combined with dried methylaluminoxane (dMAO) is investigated for ethylene/1‐hexene copolymerization at 50 °C under atmospheric pressure. The reaction shows good livingness and has a high activity at high [H]/[E] molar ratios up to 14. Ultrahigh molecular weight (>1.4 × 10⁶ g mol⁻¹) copolymers with high 1‐hexene content (>25 mol%) are prepared. Kinetic parameters of the copolymerization with PFI are determined. The first‐order Markov statistics applies and the product of the reactivity ratios r₁r₂ is close to 1, giving random unit distributions.

     

An Organotin(IV) Carboxylate Based on Amide Carboxylic Acid: Synthesis,Crystal Structure,and Characterizations

An organotin carboxylate based on amide carboxylic acid (Ph₃Sn)(L)·C₇H₈ (complex 1 ) (HL = 3‐(1,3‐dioxo‐1H,3H‐benzo[de]isoquinolin‐2‐yl)propanoic acid) has been synthesized and characterized by elemental analyses (IR, ¹H, ¹³C, and ¹¹⁹Sn NMR), UV–visible spectroscopies, and X‐ray crystallography diffraction analysis. Complex 1 is a monomeric triphenyltin carboxylate. Ligand HL in complex 1 adopts unidentate coordination mode. Intermolecular hydrogen bonds and C H···π interactions help complex 1 to build fascinating one‐dimensional and two‐dimensional structures, which are discussed in detail.     

Effect of pore size on the performance of composite adsorbent

Three kinds of commercial silica gels with pore size of 2–3, 4–7 and 8–10 nm respectively are used for preparing composite adsorbents by soaking them into the aqueous solution of calcium chloride. The test result indicates that both the water uptake and adsorption rate of composite adsorbents prepared from 4–7 and 8–10 nm silica gels improve greatly compared to pure silica gels, but they do not for 2–3 nm silica gels. The silica gel with pore size of 2–3 nm is not suitable for preparing the composite adsorbent by impregnation method due to the pore blockage because of the small pore size. The SCP and COP of the adsorption chiller with sample SA50 are 128.3 Wkg^?1 and 0.27 respectively at the hot source temperature of 90 °C, which are largely superior to that of SA0. Hence using the composite adsorbent instead of the pure silica gel can reduce the size of the adsorption chiller.     

Preparation of very long and open aligned carbon nanotubes

Very long and open aligned carbon nanotubes that reach about 2 mm long, an order of magnitude longer than previously reached, have been prepared by chemical vapor deposition over silica dioxide substrates on the surface, where iron/silica nano-composite particles are evenly positioned. The nanotubes are naturally opened at the bottom ends. The growth mechanism of the very long and openended nanotubes is also discussed.     

Comparison of different technologies for alginate beads production

This paper describes the results of the round robin experiment “Bead production technologies” carried out during the COST 840 action “Bioencapsulation Innovation and Technologies” within the 5th Framework Program of the European Community. In this round robin experiment, calcium alginate hydrogel beads with the diameter of (800 ± 100) μm were produced by the most common bead production technologies using 0.5–4 mass % sodium alginate solutions as starting material. Dynamic viscosity of the alginate solutions ranged from less than 50 mPa s up to more than 10000 mPa s. With the coaxial air-flow and electrostatic enhanced dropping technologies as well as with the JetCutter technology in the soft-landing mode, beads were produced from all alginate solutions, whereas the vibration technology was not capable to process the high-viscosity 3 % and 4 % alginate solutions. Spherical beads were generated by the electrostatic and the JetCutter technologies. Slightly deformed beads were obtained from high-viscosity alginate solutions using the coaxial airflow and from the 0.5 % and 2 % alginate solutions using the vibration technology. The rate of bead production using the JetCutter was about 10 times higher than with the vibration technology and more than 10000 times higher than with the coaxial air-flow and electrostatic technology. In memory of our colleague Stefan Rosinski     

Annealing and amorphous silicon passivation of porous silicon with blue light emission

The photoluminescence (PL) of the annealed and amorphous silicon passivated porous silicon with blue emission has been investigated. The N-type and P-type porous silicon fabricated by electrochemical etching was annealed in the temperature range of 700-900 °C, and was coated with amorphous silicon formed in a plasma-enhanced chemical vapor deposition (PECVD) process. After annealing, the variation of PL intensity of N-type porous silicon was different from that of P-type porous silicon, depending on their structure. It was also found that during annealing at 900 °C, the coated amorphous silicon crystallized into polycrystalline silicon, which passivated the irradiative centers on the surface of porous silicon so as to increase the intensity of the blue emission.     

CP asymmetries in decays of the D^{0}-\bar{D}^{0} system revisited

CP violation in neutral D meson decays to the CP eigenstates and non-CP eigenstates is studied systematically within the framework of the Cabibbo-Kobayashi-Maskawa model. The nonleptonic two-body decay processes and the decay processes with semileptonic tagging are discussed in detail and the upper bounds of the direct and indirect CP violation in these decay processes are obtained. A method to measure the mixing parameter [(e)\tilde]\tilde{\epsilon} and to separate the direct and indirect CP violation in the decay processes with semileptonic tagging are also discussed.     

5.3 W deep-blue light generation by intra-cavity frequency doubling of Nd:GdVO4

We report the efficient compacted deep-blue laser at 456 nm generation by intra-cavity frequency doubling of a continuous-wave (cw) laser operation of a diode-pumped Nd:GdVO₄ laser on the ⁴ F _3/2→⁴ I _9/2 transition at 912 nm. The different long LiB₃O₅ (LBO) crystals, cut for critical type I phase matching at room temperature, are used for second harmonic generation (shg) of the laser. At an incident pump power of 30 W, up to 5.3 W of cw output power at 456 nm is achieved with 15-mm-long LBO (3.8 W with 10 mm-long LBO). The conversion efficiency is 17.7% from pump diode input to second harmonic wave output.PACS 42.70.Hj; 42.55.Xi; 42.65.Ky     

Study of the relationship between porous ratio and effective index in nanoporous film

In this paper, a theory model called 'composite media in parallel' is proposed to explain the connection between the porous ratio and effective index of the nanoporous film. This model comes from theory of composite media's effective dielectric constant in solid material field. From this model, a function relationship between the porous ratio and effective index of the nanoporous film is obtained. And the Finite Difference Time Domain (FDTD) method is used to construct the model of nanoporous film, simulate the propagation of lightwave in the film and calculate some effective indices according to different ratios of pore. Compared with Maxwell Garnett theory model and Bruggeman theory model, it is found that the function curve based on the composite media in parallel model is most consistent with the results simulated by FDTD method.     

保矩阵{1}逆的线性映射

设R是特征为2的主理想整环,Mn(R)表示R上n×n矩阵代数,在本文中我们给出了保Mn(R)中矩阵{1}逆的线性映射的一个刻划.