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991.
From flash photolysis data of benzil and 2,2′-dichlorobenzil, the role of conformeric triplets in the formation of hydrogen
adduct radicals has been discussed. The planar relaxed triplet absorbing at 470 nm is less efficient in forming a hydrogen
adduct radical as compared to its puckered conformeric partner. Among the hydrogen donors, triethyl amine and isopropanol,
the former is more efficient in converting puckered triplets and less efficient in the case of planar conformers. Absorptions
of radicals and radical anions of 2,2′-dichlorobenzil appear at 355 nm and 460 nm respectively. These are blue-shifted as
compared to those of the parent compound benzil appearing at 370 nm and 540 nm, respectively. This blue-shift has been discussed
in terms of steric hindrance due to ortho-substitution. 相似文献
992.
993.
This paper presents a generalized Adadorov theory for anisotropic thin—walled beams. The theory takes account of the shear strain of the middle surface, which exerts a significant influence on the anisotropic thin-walled beams. A new approach is established to solve the governing equations, which have the same form for both open and closed section beams. The numerical examples show that the effects of the shear strain cannot be neglected for this class of beams.This work was part of research project supported by the National Natural Science Foundation of China 相似文献
994.
995.
本文利用不连续罚函数方法将带有不等式约束的全局优化问题的求解转化为 讨论一非线性方程的求根问题,从而得到若干个全局最优性条件. 相似文献
996.
von-Neumann正则环与左SF-环 总被引:6,自引:0,他引:6
环R称为左SF-环,如果每个单左R-模是平坦的.众所周知,Von-Neumann正则环是SF-环,但SF-环是否是正则环至今仍是公开问题,本文主要研究左SF-环是正则环的条件,证明了:如果R是左SF-环且R的每个极大左(右)理想是广义弱理想,那么R是强正则环.并且推广了Rege[3]中的相应结果. 相似文献
997.
Aiming at a simultaneous extension of Khintchine(X,X,m,T)(X,\mathcal{X},\mu,T)
and a set
A ? XA\in\mathcal{X}
of positive measure, the set of integers n such that
A T^2nA T^knA)(A)^k+1-\mu(A{\cap} T^{n}A{\cap} T^{2n}A{\cap} \ldots{\cap} T^{kn}A)>\mu(A)^{k+1}-\epsilon
is syndetic. The size of this set, surprisingly enough, depends on the length (k+1) of the arithmetic progression under consideration. In an ergodic system, for k=2 and k=3, this set is syndetic, while for kòf(x)f(Tnx)f(T2nx)? f(Tknx) dm(x)\int{f(x)f(T^{n}x)f(T^{2n}x){\ldots} f(T^{kn}x) \,d\mu(x)}
, where k and n are positive integers and f is a bounded measurable function. We also derive combinatorial consequences of these results, for example showing that for a set of integers E with upper Banach density d*(E)>0 and for all
{n ? \mathbbZ\colon d*(E?(E+n)?(E+2n)?(E+3n)) > d*(E)4-e}\big\{n\in\mathbb{Z}{\colon} d^*\big(E\cap(E+n)\cap(E+2n)\cap(E+3n)\big) > d^*(E)^4-\epsilon\big\} 相似文献
998.
A. Tseronis D. Tsilimantos N. Uzunoglu 《International Journal of Infrared and Millimeter Waves》2005,26(2):279-295
Radiation phenomena observed in a wedge shape ended dielectric slab waveguide are analyzed using mode matching technique. The case of transverse electric polarization (TE) being parallel to dielectric slab waveguide is assumed. In order to describe the fields in the wedge region, a stack of dielectric plates is assumed and in each layer the fields are expanded in terms of the mixed spectrum of guided and radiated modes. A similar expansion is used in the constant thickness slab waveguide while in free space medium a continuous-radiation mode expansion is used. Then a mode matching approach is applied, incorporating the orthogonality properties of mixed spectrum modes, in order to compute the wave fields inside the dielectric slab waveguide and wedge medium. Mode matching is achieved by discretizing the continuous radiation mode spectrum leading into a numerically stable solution provided a sufficient large number of points are used to convert integrals into finite summations. Numerical computations are carried out for various wedge geometries and shapes including linear and exponential profiles. 相似文献
999.
1000.
B. G. Orr C. Orme M. D. Johnson K. -T. Leung P. Smilauer D. Vvedensky 《Journal of Crystal Growth》1995,150(1-4):128-135
Atomic force and scanning tunneling microscopy studies have been performed on GaAs(001) films grown by molecular beam epitaxy. Multilayered mounds are seen to evolve when the growth conditions favor island nucleation. As the epilayer thickness is increased, these features grow in all dimensions but the angle of inclination remains approximately constant at 1°. The mounding does not occur on surfaces grown in step-flow. We propose that the multi-layered features are due to an unstable growth mode which relies on island nucleation and the presence of a step edge barrier. 相似文献