Synthesis, electrochemical, and gas sensitivity performance of polyaniline/MoO3 hybrid materials

Hybrid material of polyaniline with molybdenum trioxide (MoO ₃ ) xerogel obtained by ion exchange of (NH ₄ ) ₆ Mo ₇ O ₂₄ ·4H ₂ O was synthesized via polymerization of the monomer by ammonium peroxydisulfate/HCl oxidant system. The properties of MoO ₃ and hybrid material were investigated through thermogravimetry, X-ray diffraction, scanning electron microscopy, charge–discharge test, cyclic voltammetry, electrochemical impedance spectroscopy, and gas sensing experiments. Results show that hybrid material exhibits higher capacity, more excellent cycling reversibility, and better sensitivity to ethanol gas than MoO ₃ xerogel.     

Effect of isothermal annealing on degree of crystallinity and mechanical properties of poly(l‐lactide‐co‐glycolide)

We investigated the effect of isothermal annealing on the degree of crystallinity and mechanical properties of a random copolymer‐poly(l‐lactide‐co ‐glycolide) (PLLGA)‐with monomer molar ratios of 85/15 (PLLGA85/15) by performing polarizing optical microscopy, differential scanning calorimetry, and X‐ray diffraction, and studying the tensile properties. Isothermal annealing of PLLGA at 130 °C was conducted to improve the degree of crystallinity of the copolymer; the maximum degree of crystallinity (44.5%) was achieved after 60 min of annealing. The crystal size/perfection was observed to increase with annealing time. The highest tensile strength of 65.8 MPa was achieved after 80 min of annealing. However, the degree of crystallinity and tensile strength can only reach to certain extent. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Sparse asymptotic minimum variance based bearing estimation algorithm for a single vector hydrophone

For underwater target detection using a single vector hydrophone, sparse asymptotic minimum variance(SAMV) method is used to estimate the target bearing. The SAMV discretizes the entire scanning space and the target bearing is located at the position of the discrete direction. The SAMV algorithm utilizes the sparsity of the spatial signal to improve the estimation performance of the target bearing. Background noise level(BNL) of the bearing estimation of SAMV algorithm is lower than those of the conventional beam forming(CBF)method and minimum variance distortionless response(MVDR) method for different signal noise ratios(SNRs). When the SNR is higher than 0 d B, the direction-finding error of this algorithm is less than 2°. Moreover, the SAMV algorithm has a better dimensional orientation resolution capability. The experimental results show that the SAMV algorithm gives a bearing and time recording map with a lower BNL, which effectively verifies the effectiveness of SAMV algorithm in terms of underwater target detection.     

Existence and multiplicity results for singular quasilinear elliptic equation on unbounded domain

In this paper, we are interested in the existence and multiplicity results of solutions for the singular quasilinear elliptic problem with concave–convex nonlinearities (0.1) where is an unbounded exterior domain with smooth boundary ?Ω, 1 < p < N,0 ≤ a < (N ? p) ∕ p,λ > 0,1 < s < p < r < q = pN ∕ (N ? pd),d = a + 1 ? b,a ≤ b < a + 1. By the variational methods, we prove that problem 0.1 admits a sequence of solutions u_k under the appropriate assumptions on the weight functions H(x) and H(x). For the critical case, s = q,h(x) = | x | ^{? bq}, we obtain that problem 0.1 has at least a nonnegative solution with p < r < q and a sequence of solutions u_k with 1 < r < p < q and J(u_k) → 0 as k → ∞ , where J(u) is the energy functional associated to problem 0.1 . Copyright © 2013 John Wiley & Sons, Ltd.     

一类中立型泛函微分方程的周期解

利用K-集压缩算子拓扑度抽象连续定理,得到一类带分布时滞的中立型泛函微分方程存在周期解的充分条件.     

220例婴幼儿、学龄前儿童头发微量元素含量浅析

任意取城镇６个月－７岁男女儿童２２０例，取其枕意味着不测定Ｚｎ、Ｆｅ、Ｃａ、Ｐｂ的含量，分年龄，怀别统计其正常值，非正常值发生率。结果发现，缺锌，中发生率与年龄有关，缺Ｃａ、高Ｃａ发生率与年龄，性别有关。     

离子交换色谱法分离测定磷霉素的研究

分别采用全多孔型硅胶基键合强阴离子交换柱与氨丙基键合硅胶柱，在低波长 ２００ ｎｍ 处检测，分离测定了磷霉素 探讨了流动相条件，如ｐ Ｈ 值、离子强度等对磷霉素保留及分离选择性的影响，优化分离条件，建立了一种测定磷霉素的高效液相色谱新方法方法简便、快速     

辉光等离子体辅助化学气相沉积低温合成金刚石薄膜的研究

采用辉光放电等离子体增强化学气相沉积 (GP CVD)技术在低温条件下合成了高品质的亚微米金刚石薄膜 ,并通过对合成过程的实时发射光谱诊断确定了 [CH4 H2 ]系统参与金刚石合成反应的主要荷能粒子。对合成过程的研究表明 :采用这种技术能使电子增强热丝化学气相沉积 (EACVD)合成高品质金刚石薄膜的温度从 85 0℃降至 (340± 5 )℃ ;薄膜低温合成中的主要荷能粒子为CH3 、CH ,CH+ 、H 等 ,其中过饱和原子氢保证了高品质金刚石薄膜的合成 ;根据光诊断和探针测量的结果推断近表面辉光放电可在基片表面形成电偶极层 ,该偶极层是进行超常态反应的必要环境 ,并在低温合成中起重要作用     

与正规性相关的各种子群之间的关系

本讨论了正规子群，拟正规子群，s-拟正规子群，半正规子群，c-正规子群，次正规子群，共轭置换子群，半置换子群，s-半置换子群这九种子群之间的关系。