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61.
62.
用十二胺-N乙酸-N亚甲基膦酸(DAPA)改性氧化锆制备了一种新的锆基质色谱固定相(DAPAZ),研究发现,DAPA在氧化锆表面有两种结合方式:红外光谱中1611cm^-1处的特征吸收表明羧基主要与胺基形成偶极离子,以羧酸根离子形式存在,大部分的DAPA分子通过膦酸基团与氧化锆结合;而与钼酸的显色反应则表明有少量DAPA以羧居与氧化锆结合,另外,对固定相的屏蔽效应、碱性条件(pH9.5)下的稳定性等色谱性能的研究也证实这两种吸附方式同时存在,但以膦酸基结合为主。 相似文献
63.
[5-(芳亚甲基氨基)-1,3,4-噻二唑-2-基]硫乙酰芳胺的合成及 生物活性研究 总被引:2,自引:0,他引:2
在K2CO3存在下利用聚乙二醇-400 (PEG-400)作相转移催化剂, 于固-液相转移催化条件下, 通过5-芳亚甲基氨 基-2-巯基-1,3,4-噻二唑与氯乙酰芳胺的硫烷基化反应, 合成了16个未见文献报道的[5-(芳亚甲基氨基)-1,3,4-噻二唑-2-基]硫乙酰芳胺衍生物. 经元素分析, FT-IR,1H NMR和13C NMR确证了其结构. 生物活性实验结果表明, 部分化合物对小麦幼苗的生长具有明显的植物生长调节活性, 并对枯草杆菌具有一定的抑制活性. 相似文献
64.
Abstract Management and conservation of exploited populations have been a central issue in theoretical and empirical studies. In this work, it is shown that threshold policies can induce cyclic behavior in an otherwise exploited stable population as a consequence of the combination of harvest pressure and excessively protective threshold densities. Moreover, the dynamical outcomes generated by these extremely protective policies may vary according to the initial densities. These results may be of significant concern in conservation as well as in management of exploited population. 相似文献
65.
P. A. S. JORGE P. CALDAS J. C. G. ESTEVES DA SILVA C. C. ROSA A. G. OLIVA J. L. SANTOS 《Fiber and Integrated Optics》2013,32(3-4):201-225
Abstract A scheme for the simultaneous determination of temperature and analyte concentration for application in luminescence-based chemical sensors is proposed. This scheme is applied to an optical oxygen sensor, which is based on the quenching of the fluorescence of a ruthenium complex. Temperature measurement is performed using the excitation radiation and an absorption long-pass filter. Preliminary results are presented that show the viability of an oxygen measurement that is independent of temperature and optical power level. The possibility of self-referenced temperature measurements with semiconductor nanoparticles is also investigated. In order to optimize the sensor design, several different optical fiber probe geometries for oxygen sensing are tested and compared, including different methods of coupling radiation into the optical fiber system. Polyvinyl alcohol (PVA) and polyacrylamide membranes are tested as supports for sensor immobilization in fiber-optical pH sensing devices in aqueous solution. Some results are presented that show the feasibility of using fiber-optical pH indicators for remote monitoring. 相似文献
66.
RUTE DA FONSECA MARIA CRISTINA MENZIANI ANDRÉ MELO MARIA JOÃO RAMOS 《Molecular physics》2013,111(17):2731-2741
Cytochrome P450 (CYP) is a family of enzymes responsible for organism detoxification. However, some of the members of the CYP1A subfamily also catalyse the activation of heterocyclic amines (HAs), present in cooked meat, to carcinogenic compounds which have been shown to increase the risk of breast, colorectal and lung cancer. In humans, CYP1A2 is the enzyme with the most significant action in HA metabolism but in rodents CYP1A1 is also important in this biotransformation. Understanding the metabolic action of these enzymes is essential to predict the factors that enable the formation of the carcinogenic products. We have built two models of CYP1A2, one for the human enzyme and one for the rat homologue. The templates chosen include the only X-ray structure published to date for a mammal CYP, a quimeric C2A5 from rabbit, as well as CYPs belonging to Bacillus megaterium (CYPBm-3), Pseudomonas putida (CYPcam), Pseudomonas sp. (CYPterp), and Saccharopolyspora erythraea (CYPeryf). Two HAs, MeIQ (2-amino-3,4-dimethylimidazo[4,5-?]quinoline) and MeIQx (2-amino-3,8-dimethylimidazo[4,5-?]quinoxaline), known substrates of human and rat CYPIA2, were docked in the active site of the models, providing information regarding the different catalytic rates associated with the metabolisms in both enzymes. This is important for analysing the behaviour of animal models concerning the testing of anticancer drugs. 相似文献
67.
The experimental results of single event burnout induced by heavy ions and 252Cf fission fragments in power MOSFET devices have been investigated. It is concluded that the characteristics of single event burnout induced by 252Cf fission fragments is consistent to that in heavy ions. The power MOSFET in the "turn-off" state is more susceptible to single event burnout than it is in the "turn-on" state. The thresholds of the drain-source voltage for single event burnout induced by 173 MeV bromine ions and 252Cf fission fragments are close to each other, and the burnout cross section is sensitive to variation of the drain-source voltage above the threshold of single event burnout. In addition, the current waveforms of single event burnouts induced by different sources are similar. Different power MOSFET devices may have different probabilities for the occurrence of single event burnout. 相似文献
68.
The experimental results of single event burnout induced by heavy ions and 252Cf fission fragments in power MOSFET devices have been investigated. It is concluded that the characteristics of single event burnout induced by 252Cf fission fragments is consistent to that in heavy ions. The power MOSFET in the "turn-off" state is more susceptible to single event burnout than it is in the "turn-on" state. The thresholds of the drain-source voltage for single event burnout induced by 173 MeV bromine ions and ^252Cf fission fragments are close to each other, and the burnout cross section is sensitive to variation of the drain-source voltage above the threshold of single event burnout. In addition, the current waveforms of single event burnouts induced by different sources are similar. Different power MOSFET devices may have different probabilities for the occurrence of single event burnout. 相似文献
69.
针对声矢量传感器姿态变化难以准确测量导致目标测向精度低的现状,设计一种微型MEMS姿态传感器,并将其封装在声矢量传感器内部,实现基于MEMS姿态传感器的声矢量传感器设计。首先根据声矢量传感器姿态测量与校正原理,采用四元数姿态解算方法及扩展卡尔曼滤波器设计MEMS姿态传感器,并对其进行姿态精度测试;然后基于MEMS姿态传感器进行声矢量传感器样机设计、制作、参数测试;最后对样机进行了海上实验,结果表明,通过姿态校正后声矢量传感器目标方位估计精度与GPS推算方位精度一致,验证了利用MEMS姿态传感器设计声矢量传感器的可行性。 相似文献
70.
QuEChERS-液相色谱-串联质谱法测定植物性食品中30种氨基甲酸酯类农药残留 总被引:3,自引:0,他引:3
基于欧洲标准化委员会标准方法(EN 15662)对食品基质的分类,选择6种代表性植物性食品作为基质,系统优化了QuEChERS样品前处理方法;在此基础上,建立了30种氨基甲酸酯类农药的液相色谱-串联质谱分析方法。实验结果表明,除涕灭威砜的线性范围为2~100 μg/kg,其他29种氨基甲酸酯类农药的线性范围均为1~100 μg/kg;6种样品基质在3个添加水平(5、20、100 μg/kg)下的回收率为56.13%~127.6%,相对标准偏差为0.47%~16%;以信噪比(S/N)≥10计,30种农药的定量限(LOQ)为0.041~1.9 μg/kg。本文方法灵敏、有效,适用于植物性食品基质中30种氨基甲酸酯类农药残留的测定。 相似文献