全文获取类型
收费全文 | 983篇 |
免费 | 36篇 |
国内免费 | 27篇 |
专业分类
化学 | 532篇 |
晶体学 | 10篇 |
力学 | 23篇 |
数学 | 107篇 |
物理学 | 374篇 |
出版年
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 6篇 |
2016年 | 14篇 |
2015年 | 9篇 |
2014年 | 16篇 |
2013年 | 74篇 |
2012年 | 42篇 |
2011年 | 49篇 |
2010年 | 27篇 |
2009年 | 18篇 |
2008年 | 51篇 |
2007年 | 35篇 |
2006年 | 46篇 |
2005年 | 41篇 |
2004年 | 45篇 |
2003年 | 41篇 |
2002年 | 51篇 |
2001年 | 34篇 |
2000年 | 35篇 |
1999年 | 11篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 16篇 |
1994年 | 12篇 |
1993年 | 15篇 |
1992年 | 24篇 |
1991年 | 14篇 |
1990年 | 10篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 16篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 16篇 |
1983年 | 12篇 |
1982年 | 24篇 |
1981年 | 9篇 |
1980年 | 10篇 |
1979年 | 9篇 |
1978年 | 18篇 |
1977年 | 9篇 |
1976年 | 14篇 |
1975年 | 10篇 |
1974年 | 4篇 |
1973年 | 9篇 |
1972年 | 6篇 |
排序方式: 共有1046条查询结果,搜索用时 13 毫秒
51.
52.
Tandem mass spectrometry is used to monitor the contamination of banknotes by cocaine. By introducing a series of banknotes into an instrument a distribution of contamination can be obtained. The distribution of samples arising from defendants where the banknotes have been in close proximity to cocaine should differ from the distribution from the general background population. Peak picking and integration is used to produce a series of intensity readings for a batch of banknotes. By visually inspecting these distribution, and applying a variety of chemometric methods (principal components analysis, cluster analysis and class modelling via Mahalanobis distance) it is possible to discriminate effectively between the two classes of distribution (7157 background notes and 4826 case notes alleged to be from drug dealers). By calculating the Mahalonobis distance over 100 bootstrap iterations, background samples were correctly classified 96.48% of the time, while case samples were correctly classified 89.37% of the time. 相似文献
53.
54.
Zhenning Gu Feng Liang Zheyi Chen Anil Sadana Carter Kittrell W.E. Billups Robert H. Hauge Richard E. Smalley 《Chemical physics letters》2005,410(4-6):467-470
The charge transfer induced lithiation of single-wall carbon nanotubes (SWNTs) was investigated by in situ monitoring by Raman spectroscopy as lithium was added incrementally to a dispersion of SWNTs in liquid ammonia. Charge transfer from liquid ammonia solvated lithium to the SWNTs led to intercalation of lithium into the SWNT ropes, as well as to the semi-covalent lithiation of the SWNTs. Raman spectra of the SWNTs recorded as lithium was added showed a 30 wavenumber downshift of the G band (1594 cm−1) with the concomitant appearance of a new peak at 1350 cm−1 that was assigned as the signature of the lithiated SWNTs. Addition of 1-iodododecane to the lithiated SWNTs resulted in the covalent attachment of dodecyl groups. The intercalation of lithium throughout the SWNT ropes led to complete dodecylation of all individual SWNTs. 相似文献
55.
Bernd Hartke Douglas A. Gibson Emily A. Carter 《International journal of quantum chemistry》1993,45(1):59-70
This is the first application of a rigorous, established multiple time-step method to ab initio molecular dynamics. The resulting algorithm is conceptually simple and easy to implement, but very effective. It translates the large mass differences present in ab initio molecular dynamics into substantial savings in computer time while retaining high accuracy. This transforms ab initio molecular dynamics from a desirable but prohibitively expensive possibility into a viable method, at least for short-time phenomena in small systems or for otherwise inaccessibly complicated potential energy surfaces. © 1993 John Wiley & Sons, Inc. 相似文献
56.
[reaction: see text] The synthesis of the C9-C26 portion of amphidinolide B1 is described. A Fleming allylation followed by elimination was employed for the construction of the C13-C15 diene portion. Sharpless asymmetric dihydroxylation was utilized for regioselective functionalization of a styrene-derived alkene, in the presence of the C13-C15 diene functionality. A highly diastereoselective aldol reaction was developed to establish the C18 stereochemistry. 相似文献
57.
Effects of surfactants on the photosensitized production of tyrosine radicals studied by photo-CIDNP
Lopez JJ Carter MA Tsentalovich YP Morozova OB Yurkovskaya AV Hore PJ 《Photochemistry and photobiology》2002,75(1):6-10
The influence of the surfactants sodium dodecyl sulphate, cetyltrimethyl-ammonium bromide and triton X-100 on the photochemically induced dynamic nuclear polarization (CIDNP) of N-acetyl tyrosine has been investigated. Three photosensitizers were used to generate polarization: thionin, eosin Y and flavin mononucleotide. 600 MHz 1H photo-CIDNP experiments, supported by laser flash photolysis transient absorption measurements, indicate that the neutral triton surfactant has no influence on the nuclear polarization, but that the other two, charged, amphiphiles affect the photochemistry in a variety of ways, depending on the surfactant concentration and the identity of the sensitizer. 相似文献
58.
Nee MJ Osterwalder A Neumark DM Kaposta C Cibrián Uhalte C Xie T Kaledin A Bowman JM Carter S Asmis KR 《The Journal of chemical physics》2004,121(15):7259-7268
Gas phase vibrational spectra of BrHI- and BrDI- have been measured from 6 to 17 microm (590-1666 cm(-1)) using tunable infrared radiation from the free electron laser for infrared experiments in order to characterize the strong hydrogen bond in these species. BrHI-.Ar and BrDI-.Ar complexes were produced and mass selected, and the depletion of their signal due to vibrational predissociation was monitored as a function of photon energy. Additionally, BrHI- and BrDI- were dissociated into HBr (DBr) and I- via resonant infrared multiphoton dissociation. The spectra show numerous transitions, which had not been observed by previous matrix studies. New ab initio calculations of the potential-energy surface and the dipole moment are presented and are used in variational ro-vibrational calculations to assign the spectral features. These calculations highlight the importance of basis set in the simulation of heavy atoms such as iodine. Further, they demonstrate extensive mode mixing between the bend and the H-atom stretch modes in BrHI- and BrDI- due to Fermi resonances. These interactions result in major deviations from simple harmonic estimates of the vibrational energies. As a result of this new analysis, previous matrix-isolation spectra assignments are reevaluated. 相似文献
59.
60.