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111.
M. V. Pryadeina A. B. Denisova Ya. V. Burgart V. I. Saloutin 《Russian Journal of Organic Chemistry》2008,44(12):1811-1815
Ethyl 2-ethoxymethylidene-3-oxo-3-polyfluoroalkylpropionates reacted in a regioselective fashion with thiazolylhydrazines to give the corresponding ethyl 1-thiazolyl-5-fluoroalkyl-1H-pyrazole-4-carboxylates. The product structure was determined on the basis of NMR and X-ray diffraction data. 相似文献
112.
Interaction of perfluoropentene-2 with ethylenediamine, diethylenetriamine, and triethylenetetramine forms previously unknown fluorine-containing azaheterocycles in yields of 25–74%. The structure of the compounds obtained has been confirmed by1H and19F NMR methods and mass spectrometry.Department of Fine Organic Synthesis, Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, 620219 Ekaterinburg. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2170–2174, September, 1992. 相似文献
113.
Ionov D. S. Ionova I. V. Lobova N. A. Kononevich Yu. N. Belova A. S. Burgart D. A. Sazhnikov V. A. Muzafarov A. M. Alfimov M. V. 《High Energy Chemistry》2021,55(5):368-374
High Energy Chemistry - The basic photophysical characteristics and the hydrolytic stability and photostability of dibenzoylmethanatoboron complexes containing various substituents at the boron... 相似文献
114.
D. N. Bazhin E. V. Shchegol’kov Yu. S. Kudyakova K. V. Scherbakov Ya. V. Burgart V. I. Saloutin 《Russian Journal of General Chemistry》2012,82(1):116-121
The structure of key intermediates in the synthesis of fluoroquinolone antibiotics: diethyl (2,3,4,5-tetrafluorobenzoyl)malonate
and ethyl (2Z)-3-hydroxy-(2,3,4,5-tetrafluorophenyl)prop-2-enoate was for first time studied using X-ray diffraction (XRD) and 1H, 19F NMR spectroscopy. In solution both the esters were shown to exist as a mixture of enol and ketone tautomeric forms with
predominance of the latter. According to the XRD analysis, ethyl (2Z)-3-hydroxy-(2,3,4,5-tetrafluorophenyl)prop-2-enoate in the solid state exists entirely in the enol form. 相似文献
115.
E. V. Shchegol’kov E. V. Sadchikova Ya. V. Burgart V. I. Saloutin 《Russian Journal of Organic Chemistry》2009,45(4):572-580
Azo coupling of fluorinated 1,3-diketones with 4-ethoxycarbonyl-1H-imidazole-5-diazonium chloride led to the formation of 4-hydroxy-4-polyfluoroalkyl-1,4-dihydroimidazo[5,1-c][1,2,4]triazines. According to the 1H and 19F NMR data, these compounds in solution give rise to ring-chain tautomerism via opening of the C4-N5 bond, which is especially characteristic of dihydroimidazotriazines with a polyfluoroalkyl substituent longer than trifluoromethyl group. 相似文献
116.
I. T. Bazyl' S. P. Kisil' S. N. Frolov Ya. V. Burgart V. I. Saloutin 《Russian Chemical Bulletin》1999,48(8):1537-1541
The reactions of ethyl 5,6,7,8-tetrafluoro-2-methylchromone-3-carboxylate with mercaptoacetic acid and 1,2-ethanedithiol afforded
C(7)-substitution products. The above-mentioned chromone reacted with 2-mercaptoethanol to yield 7-mono- or 5,7,8-trisubstituted
products depending on the reaction conditions. The reaction of 3-acetimidoyl-5,6,7,8-tetrafluoro-4-hydroxycoumarin with 2-mercaptoethanol
afforded a 5,7,8-trisubstituted produect. The acyl-lactone rearrangement of mono- and trisubstituted chromones yielded the
corresponding coumarins.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1557–1561, August, 1999. 相似文献