Oxygen- versus carbon-coordination of the alpha-stabilized phosphorus ylide Ph<Subscript>3</Subscript>P=C(H)R in palladacycles bearing secondary amines

The ortho-metalated complex [Pd(x){κ ² (C,N)-[C₆H₄CH₂NRR′ (Y)}] (2a–4a and 2b–3b) was prepared by refluxing in benzene equimolecular amounts of Pd(OAc)₂ and secondary benzylamine [a, EtNHCH₂Ph; b, t-BuNHCH₂Ph followed by addition of excess NaCl. The reaction of the complexes [Pd(x){κ ² (C,N)-[C₆H₄CH₂NRR′ (Y)}] (2a–4a and 2b–3b) with a stoichiometric amount of Ph₃P=C(H)COC₆H₄-4-Z (Z = Br, Ph) (ZBPPY) (1:1 molar ratio), in THF at low temperature, gives the cationic derivatives [Pd(OC(Z-4-C₆H₄C=CHPPh₃){κ ² (C,N)-[C₆H₄CH₂NRR′(Y)}] (5a–9a, 4b–6b, and 4b′–6b′), in which the ylide ligand is O-coordinated to the Pd(II) center and trans to the ortho-metalated C(6)H(4) group, in an “end-on carbonyl”. Ortho-metallation, ylide O-coordination, and C-coordination in complexes (5a–9a, 4b–6b, and 4b′–6b′) were characterized by elemental analysis as well as various spectroscopic techniques.     

Sunlight absorbing potential of carbon nanoball water and ethylene glycol-based nanofluids

Solar thermal collectors are applicable in the water heating or space conditioning systems in which surface-based absorption of incident solar flux cause high heat losses. Therefore, an enhancement in the efficiency of solar harvesting devices is a basic challenge which requires great effort. Adding nanoparticles to the working fluid in direct absorption solar collector, which has been recently proposed, leads to improvement in the working fluid thermal and optical properties such as thermal conductivity and absorption coefficient. This results certainly in collector efficiency enhancement. In this paper, the characteristics of nanofluids consisting carbon nanoball in water- and ethylene glycol-based suspensions in consideration of their use as sunlight absorber fluid in a DASC are investigated. It was found that by using of 300 ppm carbon nanoballs, the extinction coefficient of pure water and ethylene glycol is increased by about 3.9 cm^?1 and 3.4 cm^?1 in average, respectively. With these significantly promising optical properties, a direct absorption solar collector using carbon nanoball-based nanofluids can achieve relatively higher efficiencies, compared with a conventional solar collector.     

To obtain approximate probability density functions for a class of axially moving viscoelastic plates under external and parametric white noise excitation

The probability density function plays an essential role to investigate the behaviors of stochastic linear or nonlinear systems. This function can be evaluated by several approaches but due to its analytical theme, the Fokker–Planck–Kolmlgorov (FPK) approach is preferable. FPK equation is a nonlinear PDE gives the probability density function for a stochastic linear or nonlinear system. Many researches have been done in literature tried to specify the conditions, in which the FPK equation gives an exact solution. Although, the exact probability density function can be achieved by solving the FPK equation even for some nonlinear systems, many types of systems cannot satisfy the conditions for exact solution. In this article, the axially moving viscoelastic plates under both external and parametric white noise excitation as one of the newest and applicable research areas are studied. Due to strong nonlinearities recognized in the governing equation of the system, the exact probability density function cannot be obtained, however, via an approximate method; some precise approximate solutions for different but comprehensive case studies are evaluated, validated, and discussed.     

Infrared spectroscopic and chemometric approach for identifying binding medium in Sukias mansion’s wall paintings

Abstract

This paper addresses the application of infrared spectroscopy in combination with chemometrics to identify wall painting’s binding medium while employing pattern recognition techniques to process FTIR data-set of complex samples. In this regard, based on the historical documents and previous researches, firstly 56 standard samples were prepared to represent strata of Persian wall paintings in the Safavid period in addition to real historic samples from the case study; Sukias mansion. Then, each sample was analysed by the means of FTIR and chemometrics. Finally, SIMCA was applied to the whole region of studied IR spectra which predicted egg yolk as the binding medium of Sukias mansion samples.     

A novel protocol for catalyst-free synthesis of fused six-member rings to triazole and pyrazole

Molecular Diversity - Herein, an effectual, quick and novel method is described for the synthesis of new triazolo[1,5-a]pyrimidine, triazolo[5,1-b][1,3] thiazine and pyrazolo[1,5-a]pyrimidine...     

Modeling and Optimizing of Effective Factors on Kinetic Spectrophotometric Determination of Vitamin B12

Journal of Applied Spectroscopy - A new, accurate, sensitive, and reliable kinetic spectrophotometric method for the determination of vitamin B12 in biological samples and pharmaceutical...     

A New Bound on the Total Domination Subdivision Number

A set S of vertices of a graph G = (V, E) without isolated vertex is a total dominating set if every vertex of V(G) is adjacent to some vertex in S. The total domination number γ _t (G) is the minimum cardinality of a total dominating set of G. The total domination subdivision number is the minimum number of edges that must be subdivided (each edge in G can be subdivided at most once) in order to increase the total domination number. In this paper we prove that for every simple connected graph G of order n ≥ 3,

On the Roman domination number of a graph

A Roman dominating function of a graph G is a labeling f:V(G)?{0,1,2} such that every vertex with label 0 has a neighbor with label 2. The Roman domination number γ_R(G) of G is the minimum of ∑_v∈V(G)f(v) over such functions. A Roman dominating function of G of weight γ_R(G) is called a γ_R(G)-function. A Roman dominating function f:V?{0,1,2} can be represented by the ordered partition (V₀,V₁,V₂) of V, where V_i={v∈V∣f(v)=i}. Cockayne et al. [E.J. Cockayne, P.A. Dreyer, S.M. Hedetniemi, S.T. Hedetniemi, On Roman domination in graphs, Discrete Math. 278 (2004) 11-22] posed the following question: What can we say about the minimum and maximum values of |V₀|,|V₁|,|V₂| for a γ_R-function f=(V₀,V₁,V₂) of a graph G? In this paper we first show that for any connected graph G of order n≥3, , where γ(G) is the domination number of G. Also we prove that for any γ_R-function f=(V₀,V₁,V₂) of a connected graph G of order n≥3, , and .     

Preload effect on nonlinear dynamic behavior of a rigid rotor supported by noncircular gas-lubricated journal bearing systems

This paper presents the effect of preload, as one of the design parameters, on nonlinear dynamic behavior of a rigid rotor supported by gas-lubricated noncircular journal bearings. A finite element method has been employed to solve the Reynolds equation in static and dynamical states and the dynamical equations are solved using the Runge–Kutta method. To analyze the behavior of the rotor center in horizontal and vertical directions under different operating conditions, dynamic trajectory, power spectra, Poincare maps, and bifurcation diagrams are used. Results of this study reveal how the complex dynamic behavior of two types of noncircular bearing systems comprising periodic, KT-periodic, and quasi-periodic responses of the rotor center varies with changes in preload value.