全文获取类型
收费全文 | 72篇 |
免费 | 8篇 |
专业分类
化学 | 41篇 |
力学 | 1篇 |
数学 | 14篇 |
物理学 | 24篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 2篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 2篇 |
2009年 | 7篇 |
2008年 | 3篇 |
2007年 | 7篇 |
2006年 | 4篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有80条查询结果,搜索用时 15 毫秒
61.
62.
63.
Effect of ions on a dipalmitoyl phosphatidylcholine bilayer. a molecular dynamics simulation study 总被引:1,自引:0,他引:1
The effect of physiological concentrations of different chlorides on the structure of a dipalmitoyl phosphatidylcholine (DPPC) bilayer has been investigated through atomistic molecular dynamics simulations. These calculations provide support to the concept that Li+, Na+, Ca2+, Mg2+, Sr2+, Ba2+, and Ac3+, but not K+, bind to the lipid-head oxygens. Ion binding exhibits an influence on lipid order, area per lipid, orientation of the lipid head dipole, the charge distribution in the system, and therefore the electrostatic potential across the head-group region of the bilayer. These structural effects are sensitive to the specific characteristics of each cation, i.e., radius, charge, and coordination properties. These results provide evidence aimed at shedding some light into the apparent contradictions among different studies reported recently regarding the ordering effect of ions on zwitterionic phosphatidylcholine lipid bilayers. 相似文献
64.
Pruneda JM Sánchez-Portal D Arnau A Juaristi JI Artacho E 《Physical review letters》2007,99(23):235501
Using time-dependent density-functional theory we calculate from first principles the rate of energy transfer from a moving proton or antiproton to the electrons of an insulating material, LiF. The behavior of the electronic stopping power versus projectile velocity displays an effective threshold velocity of approximately 0.2 a.u. for the proton, consistent with recent experimental observations, and also for the antiproton. The calculated proton/antiproton stopping-power ratio is approximately 2.4 at velocities slightly above the threshold (v approximately 0.4 a.u.), as compared to the experimental value of 2.1. The projectile energy loss mechanism is observed to be extremely local. 相似文献
65.
Alexandra Schroter Carla Arnau del Valle María J. Marín Thomas Hirsch 《Angewandte Chemie (International ed. in English)》2023,62(36):e202305165
The surface chemistry of nanoparticles is a key step on the pathway from particle design towards applications in biologically relevant environments. Here, a bilayer-based strategy for the surface modification of hydrophobic nanoparticles is introduced that leads to excellent colloidal stability in aqueous environments and good protection against disintegration, while permitting surface functionalization via simple carbodiimide chemistry. We have demonstrated the excellent potential of this strategy using upconversion nanoparticles (UCNPs), initially coated with oleate and therefore dispersible only in organic solvents. The hydrophobic oleate capping is maintained and a bilayer is formed upon addition of excess oleate. The bilayer approach renders protection towards luminescence loss by water quenching, while the incorporation of additional molecules containing amino functions yields colloidal stability and facilitates the introduction of functionality. The biological relevance of the approach was confirmed with the use of two model dyes, a photosensitizer and a nitric oxide (NO) probe that, when attached to the surface of the UCNPs, retained their functionality to produce singlet oxygen and detect intracellular NO, respectively. We present a simple and fast strategy to protect and functionalize inorganic nanoparticles in biological media, which is important for controlled surface engineering of nanosized materials for theranostic applications. 相似文献
66.
Laura Hernández-López Alba Cortés-Martínez Dr. Teodor Parella Dr. Arnau Carné-Sánchez Prof. Daniel Maspoch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(31):e202200357
Water pollution threatens human and environmental health worldwide. Thus, there is a pressing need for new approaches to water purification. Herein, we report a novel supramolecular strategy based on the use of a metal-organic polyhedron (MOP) as a capture agent to remove nitrogenous organic micropollutants from water, even at very low concentrations (ppm), based exclusively on coordination chemistry at the external surface of the MOP. Specifically, we exploit the exohedral coordination positions of RhII-MOP to coordinatively sequester pollutants bearing N-donor atoms in aqueous solution, and then harness their exposed surface carboxyl groups to control their aqueous solubility through acid/base reactions. We validated this approach for removal of benzotriazole, benzothiazole, isoquinoline, and 1-napthylamine from water. 相似文献
67.
68.
This paper describes in detail a novel formulation of the method of characteristics for its application to solve one-dimensional compressible unsteady non-homentropic flow advected along porous wall channels. In particular, the method is implemented into a wall-flow monolith Diesel particulate filter model whose purpose is the pressure drop prediction. The flow inside the monolith channels is considered to be one-dimensional and the flow through the porous wall treated as a source term agree with the Darcy’s law. The flow dynamic behaviour at internal nodes of the channels is solved by means of shock capturing methods, whereas the end nodes, or boundary conditions, are solved applying the method of characteristics. The derived solution in this study of the Riemann variables and the entropy level includes the variation along the space–time plane due to cross-section area changes, friction and heat transfer as traditionally stated, but also takes into account the key influence on every line of the flow leaving or entering to the channels through the porous walls. 相似文献
69.
70.
Given a compact symmetric space, M, we obtain the mean exit time function from a principal orbit, for a Brownian particle starting and moving in a generalized ball whose boundary is the principal orbit. We also obtain the mean exit time flmction of a tube of radius r around special totally geodesic submanifolds P of M. Finally we give a comparison result for the mean exit time function of tubes around submanifolds in Riemannian manifolds, using these totally geodesic submanifolds in compact symmetric spaces as a model. 相似文献