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371.
Noora Salonen Antti Nyyss?l? Kalle Salonen Ossi Turunen 《Applied biochemistry and biotechnology》2012,168(2):392-405
Bifidobacterium longum NRRL B-41409 l-arabinose isomerase (l-AI) was cloned and overexpressed in Lactococcus lactis using a phosphate-depletion-inducible expression system. The purified B. longum l-AI was characterized using d-galactose and l-arabinose as the substrates. The enzyme was active and stable at acidic pH with an optimum at pH 6.0?C6.5. The enzyme showed the highest activity at 55?°C during a 20-min incubation at pH 6.5. The K m value was 120?mM for l-arabinose and 590?mM for d-galactose. The V max was 42?U mg?1 with l-arabinose and 7.7?U mg?1 with d-galactose as the substrates. The enzyme had very low requirement for metal ions for catalytic activity, but it was stabilized by divalent metal ions (Mg2+, Mn2+). The enzyme bound the metal ions so tightly that they could not be fully removed from the active site by EDTA treatment. Using purified B. longum l-AI as the catalyst at 35?°C, equilibrium yields of 36?% d-tagatose and 11?% l-ribulose with 1.67?M d-galactose and l-arabinose, respectively, as the substrates were reached. 相似文献
372.
In this paper, a unified framework for a posteriori error estimation for the Stokes problem is developed. It is based on $[H^1_0(\Omega )]^d$ -conforming velocity reconstruction and $\underline{\varvec{H}}(\mathrm{div},\Omega )$ -conforming, locally conservative flux (stress) reconstruction. It?gives guaranteed, fully computable global upper bounds as well as local lower bounds on the energy error. In order to apply this framework to a given numerical method, two simple conditions need to be checked. We show how to do this for various conforming and conforming stabilized finite element methods, the discontinuous Galerkin method, the Crouzeix–Raviart nonconforming finite element method, the mixed finite element method, and a general class of finite volume methods. The tools developed and used include a new simple equilibration on dual meshes and the solution of local Poisson-type Neumann problems by the mixed finite element method. Numerical experiments illustrate the theoretical developments. 相似文献
373.
We show that the famous maximum angle condition in the finite element analysis is not necessary to achieve the optimal convergence
rate when simplicial finite elements are used to solve elliptic problems. This condition is only sufficient. In fact, finite
element approximations may converge even though some dihedral angles of simplicial elements tend to π. 相似文献
374.
Crystallization studies of C-methyl pyrogallarene with potassium, rubidium and caesium bromides or chlorides resulted in a hydrogen bonded molecular cage in which the alkali metal cations are eta6 coordinated to aromatic rings via strong cation-pi interactions. 相似文献
375.
Rosenholm JM Penninkangas A Lindén M 《Chemical communications (Cambridge, England)》2006,(37):3909-3911
A simple method for surface functionalization of large-pore mesoporous silica by hyperbranching polymerization resulting in a high loading of amine groups is presented. 相似文献
376.
Antti Hannukainen Sergey Korotov Tomáš Vejchodský 《Journal of Computational and Applied Mathematics》2009
In this paper we analyse the discrete maximum principle (DMP) for a stationary diffusion-reaction problem solved by means of prismatic finite elements. We derive geometric conditions on the shape parameters of the prismatic partitions which guarantee validity of the DMP. The presented numerical tests show the sharpness of the obtained conditions. 相似文献
377.
Tim Graubner Prof. Dr. Antti J. Karttunen Prof. Dr. Florian Kraus 《Chemphyschem》2023,24(9):e202200903
Quantum chemical methods were used to study the molecular structure and anharmonic IR spectra of the experimentally known closed-shell molecular hexafluorides MF6 (M=S, Se, Te, Xe, Mo, W, U). First, the molecular structures and harmonic frequencies were investigated using Density Functional Theory (DFT) with all-electron basis sets and explicitly considering the influence of spin-orbit coupling. Second, anharmonic frequencies and IR intensities were calculated with the CCSD(T) coupled cluster method and compared, where available, with IR spectra recorded by us. These comparisons showed satisfactory results. The anharmonic IR spectra provide means for identifying experimentally too little studied or unknown MF6 molecules with M=Cr, Po, Rn. To the best of our knowledge, we predict the NdF6 molecule for the first time and show it to be a true local minimum on the potential energy surface. We used intrinsic bond orbital (IBO) analyses to characterize the bonding situation in comparison with the UF6 molecule. 相似文献
378.
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
379.
Tassilo M. F. Restle Lavinia Scherf Jasmin V. Dums Alexander G. Mutschke Robert J. Spranger Holger Kirchhain Antti J. Karttunen Leo van Wüllen Thomas F. Fässler 《Angewandte Chemie (International ed. in English)》2023,62(10):e202213962
All-solid-state batteries are promising candidates for safe energy-storage systems due to non-flammable solid electrolytes and the possibility to use metallic lithium as an anode. Thus, there is a challenge to design new solid electrolytes and to understand the principles of ion conduction on an atomic scale. We report on a new concept for compounds with high lithium ion mobility based on a rigid open-framework boron structure. The host–guest structure Li6B18(Li3N) comprises large hexagonal pores filled with Li7N] strands that represent a perfect cutout from the structure of α-Li3N. Variable-temperature 7Li NMR spectroscopy reveals a very high Li mobility in the template phase with a remarkably low activation energy below 19 kJ mol−1 and thus much lower than pristine Li3N. The formation of the solid solution of Li6B18(Li3N) and Li6B18(Li2O) over the complete compositional range allows the tuning of lithium defects in the template structure that is not possible for pristine Li3N and Li2O. 相似文献