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41.
Phase Diagrams of Alkali Bromide - Lanthanoid(III) Bromide Mixtures The phase diagrams of the systems KBr? PrBr3 (NdBr3, SmBr3, GdBr3, DyBr3, ErBr3, YbBr3), RbBr? NdBr3 (SmBr3, GdBr3, DyBr3, ErBr3, YbBr3) and CsBr? PrBr3 (NdBr3, SmBr3, GdBr3, ErBr3, YbBr3) were determined by differential thermal analysis and differential scanning calorimetry. The compound M3LnBr6, whose stability increases with increasing size of the alkali cation resp. decreasing of the Ln3+ ion, was found in all investigated systems. Additionaly congruently melting compounds of the type MLn2Br7 were found in the system from PrBr3 to DyBr3 which are, however, peritectic in systems with smaller alkali cations. Another peritectic compound has the composition M2LnBr5, in case that the quotient rMe+rX?/rLn3+ exceeds 3 this composition shifts to M3Ln2Br9. The compounds M3LnBr6 have a transition with a transition temperature, which is concentration dependent. This May indicate that at the composition ?M3LnBr6”? in fact two compounds exist with slightly different composition, of which one is stable at higher the other at lower temperatures. 相似文献
42.
Miltner A Richnow HH Kopinke FD Kästner M 《Isotopes in environmental and health studies》2005,41(2):135-140
In general, soils without the vegetation growing on them are regarded as sources of CO2. However, there are indications that CO2 is also fixed by soil microorganisms. Although this process is not significant from a quantitative point of view, it may change the isotopic composition of soil organic matter. Therefore, we conducted an incubation study with soil and 13C-labeled CO2 to investigate this process. We found that the label was transferred from CO2 into organic compounds in soil. At the end of a 61-day incubation period, 1.3 micromol C g(-1) soil, corresponding to approximately 0.08% of the soil organic carbon, had been fixed. CO2 may, therefore, be an additional source of soil organic carbon. Compound-specific analysis of amino sugars, amino acids, and fatty acids indicated that the label is incorporated into microbial, mainly bacterial, biomass. All groups of microorganisms were involved in the assimilation of CO2, but the relatively high enrichment of mono-unsaturated and mid-chain branched fatty acids indicates that gram negative bacteria and actinomycetes may be slightly more important in this process than other groups of microorganisms. 相似文献
43.
[reaction: see text] The use of the p-toluenesulfonyl (Ts) and tosylvinyl (Tsv) groups as nitrogen masking groups imparted high regioselectivity in Diels-Alder reactions directed toward members of the oroidin-derived marine alkaloid family. The electron-withdrawing Tsv group was utilized as an electronically adjustable nitrogen-protecting group as subsequent hydrogenation provided the more electron-rich tosylethyl (Tse) group. This electronic adjustment strategy avoided a protecting group exchange and provided the required electronics for the key chlorination/ring-contraction sequence. 相似文献
44.
Background
In hippocampal neurons, nuclear calcium signaling is important for learning- and neuronal survival-associated gene expression. However, it is unknown whether calcium signals generated by neuronal activity at the cell membrane and propagated to the soma can unrestrictedly cross the nuclear envelope to invade the nucleus. The nuclear envelope, which allows ion transit via the nuclear pore complex, may represent a barrier for calcium and has been suggested to insulate the nucleus from activity-induced cytoplasmic calcium transients in some cell types. 相似文献45.
Parvin Zare Maria Mahrova Emilia Tojo Anja Stojanovic Wolfgang H. Binder 《Journal of polymer science. Part A, Polymer chemistry》2013,51(1):190-202
A facile synthetic route for the preparation of dicationic ethylene glycol based‐ionic liquids (ILs) via the azide/alkyne “click” reaction is presented. The copper(I) catalyzed, microwave‐assisted azide/alkyne “click” reaction between diazido‐ethylene glycols and the corresponding alkyne containing IL‐head group enables a simple preparation of different sets of poly(ethylene glycol)‐based ILs. Beside tetra‐ and hexa(ethylene glycol)‐based ILs, also oligomeric (Mn = 400 g/mol) and polymeric ILs (Mn up to 1550 g/mol) could be prepared in good yield and with full conversion of the ionic head group. The prepared ILs were extensively characterized via NMR spectroscopy and ESI‐time‐of‐flight (TOF) mass spectroscopy, revealing the formation of multiply charged ions in the negative mode. Thermal stability proved to be exceptionally high (up to 300 °C) together with low glass‐transition temperatures. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
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47.
Nicole Bäuerle Anja Blatter Alfred Müller 《Mathematical Methods of Operations Research》2008,67(1):161-186
In this paper we investigate dependence properties and comparison results for multidimensional Lévy processes. In particular
we address the questions, whether or not dependence properties and orderings of the copulas of the distributions of a Lévy
process can be characterized by corresponding properties of the Lévy copula, a concept which has been introduced recently
in Cont and Tankov (Financial modelling with jump processes. Chapman & Hall/CRC, Boca Raton, 2004) and Kallsen and Tankov
(J Multivariate Anal 97:1551–1572, 2006). It turns out that association, positive orthant dependence and positive supermodular dependence of Lévy processes can be characterized in terms of the Lévy measure as well as in terms of the Lévy copula. As
far as comparisons of Lévy processes are concerned we consider the supermodular and the concordance order and characterize
them by orders of the Lévy measures and by orders of the Lévy copulas, respectively. An example is given that the Lévy copula
does not determine dependence concepts like multivariate total positivity of order 2 or conditionally increasing in sequence. Besides these general results we specialize our findings for subfamilies of Lévy processes. The last section contains some
applications in finance and insurance like comparison statements for ruin times, ruin probabilities and option prices which
extends the current literature.
Anja Blatter was supported by the Deutsche Forschungsgemeinschaft (DFG). 相似文献
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50.
Anna Luise Grab Dirk Hose Patrick Horn Elisabetta Ada Cavalcanti-Adam Anja Seckinger Martin Müller 《Particle & Particle Systems Characterization》2021,38(3):2000263
In the malignant plasma cell disease multiple myeloma (MM), bone lesions and resulting fractures caused by MM cell (MMC) accumulation represent a major cause of morbidity and mortality. Despite recent advantages in systemic treatment, residual MMCs remain, especially in bone lesions. Therefore an interfacial delivery system for local treatment of MM and induced bone disease based on polyelectrolyte complex nanoparticles (PEC NP) loaded with bone morphogenetic protein 6 (BMP-6) inducing de-novo bone formation and MMC apoptosis is presented herein. BMP-6 loaded PEC NP are fabricated by defined mixing bio-related cationic and anionic polysaccharides and BMP-6 according to molar ratio of BMP-6/PEC-NP of 1/3. BMP-6/PEC NP bound to a model substrate releases 10% BMP-6 sustainably within two weeks as accessed by infrared spectroscopy. BMP-6 loaded PEC NP adheres to cell membranes of MMCs and MSCs and activated phosphorylation of Smad 1/5. Osteogenic differentiation (ALP-concentration) is enhanced in MSCs (p < 0.05). All patient samples (10/10) of MMCs show significant induction of apoptosis (median 84%, p < 0.05). Finally, BMP-6/PEC NP are successfully integrated in a commercial hyaluronic acid based hydrogel material revealing MMC death as principal proof for the local treatment of MM induced bone lesions. 相似文献