Two-dimensional high-resolution NMR spectra in matched B(0) and B(1) field gradients

In a recent publication we presented a method to obtain highly resolved NMR spectra in the presence of an inhomogeneous B(0) field with the help of a matched RF gradient. If RF gradient pulses are combined with "ideal" 90 degrees pulses to form inhomogeneous z rotation pulses, the line broadening caused by the B(0) gradient can be refocused, while the full chemical shift information is maintained. This approach is of potential use for NMR spectroscopy in an inhomogeneous magnetic field produced by an "ex-situ" surface spectrometer. In this contribution, we extend this method toward two-dimensional spectroscopy with high resolution in one or both dimensions. Line narrowing in the indirect dimension can be achieved by two types of nutation echoes, thus leading to depth-sensitive NMR spectra with full chemical shift information. If the nutation echo in the indirect dimension is combined with a stroboscopic acquisition using inhomogeneous z-rotation pulses, highly resolved two-dimensional correlation spectra can be obtained in matched field gradients. Finally, we demonstrate that an INEPT coherence transfer from proton to carbon spins is possible in inhomogeneous B(0) fields. Thus, it is possible to obtain one-dimensional (13)C NMR spectra with increased sensitivity and two-dimensional HETCOR spectra in the presence of B(0) gradients of 0.4 mT/cm. These schemes may be of some value for ex-situ NMR analysis of materials and biological systems.     

Diode-pumped passively mode-locked Nd:YAG laser with 10-W average power in a diffraction-limited beam

We present a passively mode-locked Nd:YAG laser with 10.7-W average output power in a diffraction-limited beam. Stable self-starting mode locking with a pulse duration of 16 ps and a pulse energy of 120 nJ is obtained with a semiconductor saturable-absorber mirror. The laser is directly side pumped with two 20-W diode bars. Single-pass frequency doubling in an external 5-mm-thick KTP crystal yields 3.2-W average power at 532 nm.     

Resolvent Tests for Similarity to a Normal Operator

The main result of this paper is the resolvent similarity criterionwhich says that linear growth of the resolvent towards the spectrumis sufficient for a Hilbert space contraction with finite rankdefect operators and spectrum not covering the unit disc tobe similar to a normal operator. Similar results are provedfor operators having a spectral set bounded by a Dini-smoothJordan curve; in particular, a dissipative operator with finiterank imaginary part is similar to a normal operator if and onlyif its resolvent grows linearly towards the spectrum. Relevantresults on the insufficiency of linear resolvent growth notaccompanied by smallness of defect operators are presented.Also it is proved that there is no restriction on the spectrum,other than finiteness, which together with linear resolventgrowth implies similarity to a normal operator. The constructionof corresponding examples depends on a characterization of well-knownAhlfors curves as curves of linear length growth with respectto linear fractional transformations. 1991 Mathematics SubjectClassification: 11D25, 11G05, 14G05.     

Surface integral and Gauss-Ostrogradskij theorem from the viewpoint of applications

Making use of a surface integral defined without use of the partition of unity, trace theorems and the Gauss-Ostrogradskij theorem are proved in the case of three-dimensional domains with a Lipschitz-continuous boundary for functions belonging to the Sobolev spaces H ^1,p () (1 p < ). The paper is a generalization of the previous author's paper which is devoted to the line integral.     

Generic convergence of infinite products of positive linear operators

We present several results concerning the asymptotic behavior of (random) infinite products of generic sequences of positive linear operators on an ordered Banach space. In addition to a weak ergodic theorem we also obtain convergence to an operator of the formf(·) wheref is a continuous linear functional and is a common fixed point.     

A Characterization of Projective Spaces by a Set of Planes

This note deals with the following question: How many planes of a linear space (P, $\mathfrak{L}$ ) must be known as projective planes to ensure that (P, $\mathfrak{L}$ ) is a projective space? The following answer is given: If for any subset M of a linear space (P, $\mathfrak{L}$ ) the restriction (M, $\mathfrak{L}$ )(M)) is locally complete, and if for every plane E of (M, $\mathfrak{L}$ (M)) the plane $\bar E$ generated by E is a projective plane, then (P, $\mathfrak{L}$ ) is a projective space (cf. 5.6). Or more generally: If for any subset M of P the restriction (M, $\mathfrak{L}$ (M)) is locally complete, and if for any two distinct coplanar lines G1, G2 ∈ $\mathfrak{L}$ (M) the lines $\bar G_1 ,\bar G_2 \varepsilon \mathfrak{L}$ generated by G1, G2 have a nonempty intersection and $\overline {G_1 \cup {\text{ }}G_2 }$ satisfies the exchange condition, then (P, $\mathfrak{L}$ ) is a generalized projective space.     

Relativistic calculations using Monte Carlo methods: one-electron systems

Variance minimization and Monte Carlo integration are used to evaluate the four-component Dirac equation for a number of one-electron atomic and diatomic systems. This combination produces accurate energies, is relatively simple to implement, and exhibits few of the problems associated with traditional techniques.     

Free modules over hjelmslev rings in which not every maximal linearly independent subset is a basis

First it will be shown that every left-noetherian AH-ring is left-artinian. For an AH-ring R every finite linearly independent subset of a free left R-module V can be completed to a basis of V. But a maximal linearly independent subset of a free left R-module V need not be a basis of V. For an H-ring R, every maximal linearly independent subset of a free left R-module V is a basis of V if and only if the H-ring R is left-noetherian or V is finitely generated.