Antiproton stopping at low energies: confirmation of velocity-proportional stopping power

The stopping power for antiprotons in various solid targets has been measured in the low-energy range of 1-100 keV. In agreement with most models, in particular free-electron gas models, the stopping power is found to be proportional to the projectile velocity below the stopping-power maximum. Although a stopping power proportional to velocity has also been observed for protons, the interpretation of such measurements is difficult due to the presence of charge exchange processes. Hence, the present measurements constitute the first unambiguous support for a velocity-proportional stopping power due to target excitations by a pointlike projectile.     

Catalytic Enantioselective Addition of Nitro Compounds to Imines-A Simple Approach for the Synthesis of Optically Active beta-Nitro-alpha-Amino Esters

No AbstractSupporting information for this article is available on the WWW under http://www.angewandte.com or from the author.     

Determination of mixed-mode stress intensity factors, fracture toughness, and crack turning angle for anisotropic foam material

A numerical and experimental investigation for determining mixed-mode stress intensity factors, fracture toughness, and crack turning angle for BX-265 foam insulation material, used by NASA to insulate the external tank (ET) for the space shuttle, is presented. BX-265 foam is a type of spray-on foam insulation (SOFI), similar to the material used to insulate attics in residential construction. This cellular material is a good insulator and is very lightweight. Breakup of segments of this foam insulation on the shuttle ET impacting the shuttle thermal protection tiles during liftoff is believed to have caused the space shuttle Columbia failure during re-entry. NASA engineers are interested in understanding the processes that govern the breakup/fracture of this material from the shuttle ET. The foam is anisotropic in nature and the required stress and fracture mechanics analysis must include the effects of the direction dependence on material properties. Material testing at NASA Marshall Space Flight Center (MSFC) has indicated that the foam can be modeled as a transversely isotropic material. As a first step toward understanding the fracture mechanics of this material, we present a general theoretical and numerical framework for computing stress intensity factors (SIFs), under mixed-mode loading conditions, taking into account the material anisotropy. We present SIFs for middle tension – M(T) – test specimens, using 3D finite element stress analysis (ANSYS) and FRANC3D fracture analysis software. SIF values are presented for a range of foam material orientations. Mode I fracture toughness of the material is determined based on the SIF value at failure load. We also present crack turning angles for anisotropic foam material under mixed-mode loading. The results represent a quantitative basis for evaluating the strength and fracture properties of anisotropic foam insulation material.     

The ion-atom differential single-scattering cross section in the region of weak screening measured on solid targets

An accurate method for measuring the single-scattering cross section of ions on solid targets is described and used for 14–31 MeV ⁸¹Br ions scattered through 3–12° on gold targets. The results agree with the theory of Lindhard, Nielsen and Scharff except for the lowest t ^½ values, where a small deviation is observed. Comparing the present data with earlier published measurements of 0.3–2 MeV H, He, and Li ions scattered on selenium and gold, we conclude that the theoretically predicted scaling laws are fulfilled in the region of weak screening of the Coulomb interaction.     

Adsorption of ammonia on multilayer iron phthalocyanine

The adsorption of ammonia on multilayers of well-ordered, flat-lying iron phthalocyanine (FePc) molecules on a Au(111) support was investigated by x-ray photoelectron spectroscopy. We find that the electron-donating ammonia molecules coordinate to the metal centers of iron phthlalocyanine. The coordination of ammonia induces changes of the electronic structure of the iron phthalocyanine layer, which, in particular, lead to a modification of the FePc valence electron spin.     

Tuning the activity of Pt(111) for oxygen electroreduction by subsurface alloying

To enable the development of low temperature fuel cells, significant improvements are required to the efficiency of the Pt electrocatalysts at the cathode, where oxygen reduction takes place. Herein, we study the effect of subsurface solute metals on the reactivity of Pt, using a Cu/Pt(111) near-surface alloy. Our investigations incorporate electrochemical measurements, ultrahigh vacuum experiments, and density functional theory. Changes to the OH binding energy, ΔE(OH), were monitored in situ and adjusted continuously through the subsurface Cu coverage. The incorporation of submonolayer quantities of Cu into Pt(111) resulted in an 8-fold improvement in oxygen reduction activity. The most optimal catalyst for oxygen reduction has an ΔE(OH) ≈ 0.1 eV weaker than that of pure Pt, validating earlier theoretical predictions.     

Electrostatic ultra-low-energy antiproton recycling ring

There is a strong need to push forward developments in the storage and control of ultra-low-energy antiproton beams to enable important scientific research. To this end, a small electrostatic ring, and associated electrostatic acceleration section, is being designed and developed by the QUASAR group. The ring will be placed on the MUSASHI beamline at the CERN-AD. It will serve as a prototype for the future ultra-low energy storage ring (USR), to be integrated at the facility for low-energy antiproton and ion research (FLAIR) and will enable various components of the USR to be tested and optimised. A reaction microscope will be integrated in the ring to enable partial ionisation cross section measurements to be made. This small recycler ring will be unique due to its combination of size, electrostatic nature and energy and type of circulating particles (ca 3?C30 keV antiprotons). A short electrostatic accelerating section is also being developed, which will be placed between the beamline and the ring to accelerate the antiprotons from the trap extraction energy (typically 250 eV) to the final required (re-circulating) energy. The AD recycler project will be described, including ring design, accelerating injection section and the inclusion of a reaction microscope and the experiments it will enable.     

Two-phase flow in porous media: dynamical phase transition

We study numerically the behavior of two-phase flow in porous media via the parameters capillary number and viscosity ratio, under steady-state conditions and various levels of saturation. We construct a phase diagram, where the phases are defined according to whether one or both fluids move. We establish a semi-empirical theory for the location of the phase boundaries. The steady-state conditions are obtained by implementing biperiodic boundary conditions.